2,7-dibromo-9-(4-hexylphenyl)-9H-fluorene | 1159853-05-0

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 2,7-dibromo-9-(4-hexylphenyl)-9H-fluorene
• CAS: 1159853-05-0
• 化学式: C₂₅H₂₄Br₂
• 分子量: 484.274
• InChiKey: NHNUDJADVQYAFY-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  9.3
• 重原子数：
  27
• 可旋转键数：
  6
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.28
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  2,7-dibromo-9-(4-hexylphenyl)-9H-fluorene 在 氯化亚砜 、 18-冠醚-6 、 苄基三乙基氯化铵 、 potassium carbonate 、 sodium hydroxide 作用下， 以 乙醇 、 水 、 N,N-二甲基甲酰胺 、 甲苯 、 乙腈 为溶剂， 反应 21.75h， 生成
  参考文献：
  名称：

  METAL COMPOSITES AND COMPOUND USEFUL FOR PREPARATION THEREOF

  摘要：

  具有以下式(P-a)所表示的组分单元的聚合物化合物，其分子量为5×10^2至1×10^7：（其中Ar2表示一个芳香基团，可以有取代基；R2表示直接键或有机基团，可选地只有氧原子作为杂原子；E表示杂原子；R3表示一价碳氢基团或氢原子；mt和nt分别表示独立的大于或等于1的整数；lt表示1到3的整数。多个R3、E和lt中的每一个可以相同也可以不同。当存在多个mt时，它们可以相同也可以不同。当括号中附有mt和nt的多个基团存在时，它们可以相同也可以不同。）

  公开号：

  US20130018155A1

文献信息

• POLYMER COMPOUND CONTAINING NITROGEN-CONTAINING HETEROCYCLIC STRUCTURE, AND COMPOSITION, SOLUTION, THIN FILM AND POLYMER LIGHT-EMITTING ELEMENT EACH CONTAINING SAME
  申请人：Ishii Yusuke

  公开号：US20110210322A1

  公开（公告）日：2011-09-01

  A polymer compound having a repeating unit represented by formula (1-0): wherein in formula (1-0), ring A 01 and ring A 02 are the same or different and each represents an aromatic hydrocarbon ring that is optionally substituted; and X 10 and X 20 are the same or different and each represents a hydrogen atom or a substituent, provided that at least one of X 10 and X 20 is a group represented by formula (2-0): wherein in formula (2-0), Z 10 , Z 20 and Z 30 are the same or different and each represents —N═ or —CH═, provided that at least two of Z 10 , Z 20 and Z 30 are —N═; L 0 represents an arylene group or a single bond; and Ar 10 and Ar 20 are the same or different and each represents an aryl group, provided that the total carbon number of the groups represented by Ar 10 , Ar 20 and L 0 is 24 or more.

  具有由公式（1-0）表示的重复单元的聚合物化合物：其中，在公式（1-0）中，环A01和环A02相同或不同，每个环都表示可以选择取代的芳香族碳氢环；X10和X20相同或不同，每个都表示氢原子或取代基，但至少其中一个是由公式（2-0）表示的基团：其中，在公式（2-0）中，Z10、Z20和Z30相同或不同，每个都表示—N═或—CH═，但至少有两个是—N═；L0表示芳撑基团或单键；Ar10和Ar20相同或不同，每个都表示芳基团，但由Ar10、Ar20和L0表示的基团的总碳数为24或更多。
• POLYMERIC COMPOUND CONTAINING METAL COMPLEX RESIDUE AND ELEMENT COMPRISING SAME
  申请人：Akino Nobuhiko

  公开号：US20110124808A1

  公开（公告）日：2011-05-26

  A polymeric compound containing a residue of a metal complex represented by formula (1) [wherein M represents a metal atom selected from ruthenium, rhodium, palladium, osmium, iridium and platinum; R 1 , R 2 , R 3 , R 4 , R 5 , R 6 and R 8 independently represent a hydrogen atom, a halogen atom, an alkyl group, or the like; m represents an integer of 1 to 3; n represents an integer of 0 to 2; Z 1 , Z 2 , Z 3 , Z 4 and Z 5 independently represent a carbon atom or a nitrogen atom, provided that at least two member of Z 1 , Z 2 , Z 3 , Z 4 and Z 5 represent a nitrogen atom, and when any one member of Z 1 , Z 2 , Z 3 , Z 4 and Z 5 represents a carbon atom, a hydrogen atom bound to the carbon atom may be substituted by a substituent; a moiety represented by formula (2) represents a bidentate monoanionic ligand; and Rx and Ry are atoms bound to the metal atom M and independently represent a carbon atom, an oxygen atom or a nitrogen atom] and a bivalent group.

  一种聚合物化合物，其中包含由公式（1）表示的金属配合物残基 [其中M代表从钌、铑、钯、锇、铱和铂中选择的金属原子；R1、R2、R3、R4、R5、R6和R8分别独立地表示氢原子、卤素原子、烷基或类似物；m表示1到3的整数；n表示0到2的整数；Z1、Z2、Z3、Z4和Z5独立地表示碳原子或氮原子，但至少有两个成员是氮原子，当Z1、Z2、Z3、Z4和Z5中的任何一个成员表示碳原子时，与碳原子结合的氢原子可以被取代；由公式（2）表示的基团表示一个双齿单负离子配体；Rx和Ry是与金属原子M结合的原子，独立地表示碳原子、氧原子或氮原子]和一个二价基团。
• COMPOUND CONTAINING 1,3-DIENE STRUCTURE AND METHOD FOR PRODUCING SAME
  申请人：Nakatani Tomoya

  公开号：US20110127517A1

  公开（公告）日：2011-06-02

  Disclosed is a compound containing a divalent group represented by formula (I). (In formula (I), Ar 1 represents an arylene group, a divalent heterocyclic group or a divalent aromatic amine group; J 1 represents a phenylene group; J 2 represents an alkylene group; X represents an oxygen atom or a sulfur atom; j represents 0 or 1, k represents an integer of 0-3, and l represents 0 or 1, while satisfying 1≦j+k+l≦5; m represents 1 or 2; R 1 represents a hydrogen atom, an alkyl group, an alkoxy group, an alkylthio group, an aryl group, an aryloxy group, an arylthio group, an arylalkyl group, an arylalkoxy group, an arylalkylthio group, an arylalkenyl group, an arylalkynyl group, an amino group, a substituted amino group, a silyl group, a substituted silyl group, a halogen atom, an acyl group, an acyloxy group, an imine residue, a carbamoyl group, an acid imide group, a monovalent heterocyclic group, a carboxyl group, a substituted carboxyl group, a cyano group or a nitro group; the plurality of R 1 's may be the same as or different from each other; and when there are a plurality of J 1 's, J 2 's, X's, j's, k's or l's, the J 1 's, J 2 's, X's, j's, k's or l's may be the same as or different from each other, respectively.)
• US8999523B2
  申请人：——

  公开号：US8999523B2

  公开（公告）日：2015-04-07
• METAL COMPOSITES AND COMPOUND USEFUL FOR PREPARATION THEREOF
  申请人：Tanaka Kenta

  公开号：US20130018155A1

  公开（公告）日：2013-01-17

  A polymer compound having a constituent unit represented by the following formula (P-a) and having a molecular weight of 5×10 2 to 1×10 7 : (wherein Ar 2 represents an aromatic group optionally having a substituent, R 2 represents a direct bond or an organic group optionally having only an oxygen atom as a hetero atom, E represents a hetero atom, R 3 represents a monovalent hydrocarbon group or a hydrogen atom, m t and n t represent each independently an integer of 1 or more, and l t represents an integer of 1 to 3. Each of a plurality of R 3 s, Es and l t s may be mutually the same or different. When there exist a plurality of m t s, these may be mutually the same or different. When there exist a plurality of groups in parentheses appended with m t and n t , these may be mutually the same or different.).

  具有以下式(P-a)所表示的组分单元的聚合物化合物，其分子量为5×10^2至1×10^7：（其中Ar2表示一个芳香基团，可以有取代基；R2表示直接键或有机基团，可选地只有氧原子作为杂原子；E表示杂原子；R3表示一价碳氢基团或氢原子；mt和nt分别表示独立的大于或等于1的整数；lt表示1到3的整数。多个R3、E和lt中的每一个可以相同也可以不同。当存在多个mt时，它们可以相同也可以不同。当括号中附有mt和nt的多个基团存在时，它们可以相同也可以不同。）