3-[5-(tert-butyldimethylsiloxy)-2-naphthyl]-4,4-diisopropyl-3-methoxy-1,2-dioxetane | 187962-03-4

• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• 英文名称: 3-[5-(tert-butyldimethylsiloxy)-2-naphthyl]-4,4-diisopropyl-3-methoxy-1,2-dioxetane
• 英文别名: Tert-butyl-[6-[3-methoxy-4,4-di(propan-2-yl)dioxetan-3-yl]naphthalen-1-yl]oxy-dimethylsilane
• CAS: 187962-03-4
• 化学式: C₂₅H₃₈O₄Si
• 分子量: 430.66
• InChiKey: OBLYGGIJIVMCIG-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  7.04
• 重原子数：
  30
• 可旋转键数：
  7
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.6
• 拓扑面积：
  36.9
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  3-[5-(tert-butyldimethylsiloxy)-2-naphthyl]-4,4-diisopropyl-3-methoxy-1,2-dioxetane 在 四丁基氟化铵 作用下， 以 二甲基亚砜 为溶剂， 生成 2,4-二甲基-3-戊酮 、
  参考文献：
  名称：

  Synthesis of 3,3-diisopropyl-4-methoxy-4-(siloxy-2-naphthyl)-1,2-dioxetanes and their F−-induced chemiluminescent decomposition

  摘要：

  Six isomeric 3,3-diisopropyl-4-methoxy-4-(siloxy-2-napthyl)-1,2-dioxetanes (3) were synthesized and their F--induced chemiluminescencent decomposition were examined in DMSO. The 'odd/even' relationship in (CL)-C-Phi holds for all the dioxetanes (3). On the other band, the 'odd/even' relationship in emission half-lives t(1/2) is observed for dioxetanes (3e-3f) with a trigger on the ring B but not for dioxetanes (3a and 3b) with a trigger on the ring A. (C) 1999 Elsevier Science Ltd. All rights reserved.

  DOI：

  10.1016/s0040-4020(99)00336-1
• 作为产物：
  描述：

  5-甲氧基-1,2,3,4-四氢-2-萘甲酸甲酯 在 咪唑 、 lithium aluminium tetrahydride 、 titanium(III) chloride 、 氧气 、 tetraphenylporphyrin 、 sodium hydride 、 三乙胺 、 乙硫醇 作用下， 以 四氢呋喃 、 二氯甲烷 、 N,N-二甲基甲酰胺 为溶剂， 反应 4.0h， 生成 3-[5-(tert-butyldimethylsiloxy)-2-naphthyl]-4,4-diisopropyl-3-methoxy-1,2-dioxetane
  参考文献：
  名称：

  Synthesis of 3,3-diisopropyl-4-methoxy-4-(siloxy-2-naphthyl)-1,2-dioxetanes and their F−-induced chemiluminescent decomposition

  摘要：

  Six isomeric 3,3-diisopropyl-4-methoxy-4-(siloxy-2-napthyl)-1,2-dioxetanes (3) were synthesized and their F--induced chemiluminescencent decomposition were examined in DMSO. The 'odd/even' relationship in (CL)-C-Phi holds for all the dioxetanes (3). On the other band, the 'odd/even' relationship in emission half-lives t(1/2) is observed for dioxetanes (3e-3f) with a trigger on the ring B but not for dioxetanes (3a and 3b) with a trigger on the ring A. (C) 1999 Elsevier Science Ltd. All rights reserved.

  DOI：

  10.1016/s0040-4020(99)00336-1

文献信息

• Synthesis and chemiluminescence of 3,3-diisopropyl-4-methoxy-4-(2-naphthyl)-1,2-dioxetanes
  作者：Masakatsu Matsumoto、Nobuko Watanabe、Hisako Kobayashi、Mitsunori Azami、Hiroshi Ikawa

  DOI：10.1016/s0040-4039(96)02312-x

  日期：1997.1

  Six isomeric 3,3-diisopropyl-4-methoxy-4-(2-naphthyl)dioxetanes (4) were synthesized and their F--induced chemiluminescences were examined in DMSO. Dioxetane 4b is a new type of chemiluminescent substrate which affords intense flash light. The other isomeric naphthyldioxetanes (4c-4f) exhibit chemiluminescent properties in agreement with the 'odd/even' relationship.