N,N'-bis(pentafluorobenzoyl)hydrazide | 16065-70-6

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: N,N'-bis(pentafluorobenzoyl)hydrazide
• 英文别名: 2,3,4,5,6-pentafluoro-N'-(2,3,4,5,6-pentafluorobenzoyl)benzohydrazide
• CAS: 16065-70-6
• 化学式: C₁₄H₂F₁₀N₂O₂
• 分子量: 420.166
• InChiKey: UKJJCJYJYWBWKG-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.4
• 重原子数：
  28
• 可旋转键数：
  2
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  58.2
• 氢给体数：
  2
• 氢受体数：
  12

反应信息

• 作为反应物：
  描述：

  N,N'-bis(pentafluorobenzoyl)hydrazide 在 tetraphosphorus decasulfide 作用下， 生成 2,5-二(2,3,4,5,6-五氟苯基)-1,3,4-噻二唑
  参考文献：
  名称：

  Prudchenko,A.T. et al., Journal of general chemistry of the USSR, 1967, vol. 37, p. 2082 - 2084

  摘要：

  DOI：
• 作为产物：
  描述：

  五氟苯甲酰氯 在 一水合肼 作用下， 以 四氢呋喃 为溶剂， 反应 2.0h， 以82%的产率得到N,N'-bis(pentafluorobenzoyl)hydrazide
  参考文献：
  名称：

  新型2,5-二取代的1,3,4-恶二唑的合成及杀虫活性

  摘要：

  通过简便，温和的方法合成了九种新颖的对称和不对称的2,5-二取代的1,3,4-恶二唑。同时，发现在多卤素取代的芳酰基肼中，氟易于被肼取代。初步的生物测定测试表明，两种化合物（D5和D6）对粘虫（Leucania separata Walker ）表现出显着的杀虫活性（LC 50 = 116.02和70.93 mg l -1）。使用药物发现工作台（DDW）（Cerius 2），研究了结构与活性之间的关系。

  DOI：

  10.1016/s0022-1139(03)00168-4

文献信息

• Syntheses and insecticidal activities of novel 2,5-disubstituted 1,3,4-oxadiazoles
  作者：Xiumian Zheng、Zhong Li、Yanli Wang、Weidong Chen、Qingchun Huang、Chuanxiang Liu、Gonghua Song

  DOI：10.1016/s0022-1139(03)00168-4

  日期：2003.10

  Nine novel symmetrical and asymmetrical 2,5-disubstituted 1,3,4-oxadiazoles have been synthesized by a facile and mild method with high yield. Meantime, it was found that the fluorine was easy substituted by hydrazine in polyhalogen-substituted aroyl hydrazine. The preliminary bioassay tests show that two of the compounds (D5 and D6) exhibited a significant insecticidal activity (LC50=116.02 and 70

  通过简便，温和的方法合成了九种新颖的对称和不对称的2,5-二取代的1,3,4-恶二唑。同时，发现在多卤素取代的芳酰基肼中，氟易于被肼取代。初步的生物测定测试表明，两种化合物（D5和D6）对粘虫（Leucania separata Walker ）表现出显着的杀虫活性（LC 50 = 116.02和70.93 mg l -1）。使用药物发现工作台（DDW）（Cerius 2），研究了结构与活性之间的关系。
• Fluorine-containing compound
  申请人：Nippon Shokubai Co., Ltd.

  公开号：US07589228B2

  公开（公告）日：2009-09-15

  The present invention has an object to provide a fluorine-containing compound which can be used for applications such as additives making a transparent resin material low in a water absorbing ratio and high in water repellency without deteriorating of various properties such as transparency which the transparent resin material has, a fluorine-containing ester compound which is superior in properties such as heat resistance and low moisture(water) absorption property and can be suitably used in various fields such as a material for electronic information, a material for precision instruments and an optical material, a fluorine-containing aryl ester polymer, methods of producing the same. The present invention provides a fluorine-containing compound represented by the following formula (1): in the formula, X represents an oxygen atom or a sulfur atom; Rf represents a fluorine-containing alkyl group having 4 or more carbon atoms; r represents the number of Rf—X— groups bonded to an aromatic ring and is an integer of 1 or more; s represents the number of fluorine atoms bonded to an aromatic ring and is an integer of 1 or more; and r+s is an integer of 2 to 5.

  本发明旨在提供一种含氟化合物，可用于应用，如添加剂制备透明树脂材料，使其水吸收率低，耐水性高，同时不会破坏透明树脂材料所具有的透明性等各种性能；一种优异性能，如耐热性和低吸湿（水）性能的含氟酯化合物，并可适用于电子信息材料、精密仪器材料和光学材料等各个领域；一种含氟芳基酯聚合物；及其生产方法。本发明提供一种由以下式（1）表示的含氟化合物：在该式中，X代表氧原子或硫原子；Rf代表具有4个或更多碳原子的含氟烷基基团；r代表与芳香环结合的Rf—X—基团的数量，是大于或等于1的整数；s代表与芳香环结合的氟原子数量，是大于或等于1的整数；且r+s是2到5之间的整数。
• Highly luminescent 2-phenylpyridine-free diiridium complexes with bulky 1,2-diarylimidazole cyclometalating ligands
  作者：Daniel G. Congrave、Andrei S. Batsanov、Martin R. Bryce

  DOI：10.1039/c8dt04043e

  日期：——

  While a number of highly emissive dinuclear Ir(III) complexes have been reported, they have generally been restricted to structures based on 2-phenylpyridine (Hppy) cyclometalates. We now present a series of new hydrazide-bridged diiridium complexes (5–8) which incorporate bulky 1,2-diarylimidazole cyclometalating ligands in the place of Hppy. Complexes 6–8 are strongly emissive when doped into poly(methyl

  尽管已经报道了许多高发射率的双核Ir（III）配合物，但它们通常仅限于基于2-苯基吡啶（Hppy）环金属盐的结构。现在，我们提出了一系列新的酰肼桥联的二铱配合物（5-8），这些配合物取代了Hppy并带有庞大的1,2-二芳基咪唑环金属化配体。络合物6-8当掺杂到聚（甲基丙烯酸甲酯）（PMMA），显示尚未报告免费PPY-二铱发射器（最高PLQYs强烈发射Φ PL = 47-55±10％）。值得注意的是，配合物8在452 nm处具有发射峰，CIE xy颜色坐标在天蓝色区域（0.18，0.27）中，与最先进的单铱类似物竞争。X射线晶体学和溶液状态的19 F NMR光谱显示，配合物6-8具有刚性的分子内π-π相互作用，这说明与没有这些相互作用的5相比，它们的光物理性能有所提高。通过密度泛函理论（DFT）和循环伏安法（CV）数据进一步理顺了结构与属性之间的关系。在这项工作中研究的所有复合物都显示出聚集
• Transparent resin material
  申请人：NIPPON SHOKUBAI CO., LTD.

  公开号：EP1600797A1

  公开（公告）日：2005-11-30

  The present invention has an object to provide a transparent resin material having a low water absorption ratio without deteriorating various properties such as transparency which transparent resin has and also having a controllable refractive index. The present invention provides a transparent resin material containing a polymer capable of forming a formed product having transparency, wherein the transparent resin material comprises a fluorine atom-containing polymer and/or compound and contains 0.3 to 35% by weight of a fluorine atom in 100% by weight of the formed product.

  本发明的目的是提供一种透明树脂材料，该材料具有低吸水率，且不会降低透明树脂所具有的透明度等各种特性，同时还具有可控折射率。本发明提供了一种含有聚合物的透明树脂材料，该聚合物能够形成具有透明度的成型产品，其中透明树脂材料包括含氟原子的聚合物和/或化合物，在 100%（重量）的成型产品中含有 0.3 至 35%（重量）的氟原子。
• FLUORINE-CONTAINING COMPOUND
  申请人：Nishichi Ai

  公开号：US20050265686A1

  公开（公告）日：2005-12-01

  The present invention has an object to provide a fluorine-containing compound which can be used for applications such as additives making a transparent resin material low in a water absorbing ratio and high in water repellency without deteriorating of various properties such as transparency which the transparent resin material has, a fluorine-containing ester compound which is superior in properties such as heat resistance and low moisture(water) absorption property and can be suitably used in various fields such as a material for electronic information, a material for precision instruments and an optical material, a fluorine-containing aryl ester polymer, methods of producing the same. The present invention provides a fluorine-containing compound represented by the following formula (1): in the formula, X represents an oxygen atom or a sulfur atom; Rf represents a fluorine-containing alkyl group having 4 or more carbon atoms; r represents the number of Rf-X— groups bonded to an aromatic ring and is an integer of 1 or more; s represents the number of fluorine atoms bonded to an aromatic ring and is an integer of 1 or more; and r+s is an integer of 2 to 5.

  本发明的目的是提供一种含氟化合物，它可用于使透明树脂材料具有低吸水率和高防水性的添加剂等用途，而不会降低透明树脂材料所具有的透明度等各种特性、一种含氟酯化合物，其耐热性和低吸湿（水）性等性能优越，可适用于电子信息材料、精密仪器材料和光学材料等各种领域，一种含氟芳基酯聚合物，以及其生产方法。本发明提供了由下式（1）表示的含氟化合物： 式中，X 代表氧原子或硫原子；Rf 代表具有 4 个或 4 个以上碳原子的含氟烷基；r 代表与芳香环键合的 Rf-X- 基团的数目，且为 1 个或 1 个以上的整数；s 代表与芳香环键合的氟原子的数目，且为 1 个或 1 个以上的整数；r+s 为 2 至 5 的整数。