N-(prop-2-en-1-yl)cyclooctanamine | 17630-23-8

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: N-(prop-2-en-1-yl)cyclooctanamine
• 英文别名: N-prop-2-enylcyclooctanamine
• CAS: 17630-23-8
• 化学式: C₁₁H₂₁N
• mdl: MFCD11138010
• 分子量: 167.294
• InChiKey: YOUMYWCRQRYICW-UHFFFAOYSA-N

物化性质

• 沸点：
  245.9±9.0 °C(Predicted)
• 密度：
  0.85±0.1 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  3.3
• 重原子数：
  12
• 可旋转键数：
  3
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.818
• 拓扑面积：
  12
• 氢给体数：
  1
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  一氧化碳 、 N-(prop-2-en-1-yl)cyclooctanamine 在 三(三苯基膦)羰基氢化铑 sodium tetrahydroborate 作用下， 以 二氯甲烷 、 异丙醇 为溶剂， 100.0 ℃ 、3.5 MPa 条件下， 反应 24.0h， 以79%的产率得到1-Cyclooctyl-pyrrolidin-2-one
  参考文献：
  名称：

  Synthesis of pyrrolidines and pyrrolidinones by the rhodium complex catalyzed cyclization of unsaturated amines

  摘要：

  N-Allylic arylamines react with carbon monoxide, sodium borohydride, 2-propanol, and catalytic amounts of the zwitterionic complex eta-6-C6H6BPh3-Rh(COD)+ (1), to form pyrrolidines as the main products in most cases. Pyrrolidinones result from N-allylic alkylamines. An alternate route to the lactams from N-allylic alkylamines involves synthesis gas instead of CO/NaBH4, together with the dual catalytic system 1/[Ru(CO)3Cl2]2. Complementary to the N-allylic arylamine route to pyrrolidines with NaBH4 and 1 is the use of synthesis gas, 1, and 1,4-bis(diphenylphosphino)butane.

  DOI：

  10.1021/jo00038a019
• 作为产物：
  描述：

  环辛酮 、 丙烯胺 在 葡萄糖 、 GDH 、 reductive aminase from Aspergillus oryzae 、 还原型辅酶Ⅰ 作用下， 以 二甲基亚砜 为溶剂， 反应 24.0h， 生成 N-(prop-2-en-1-yl)cyclooctanamine
  参考文献：
  名称：

  生物催化级联反应，用于胺化未官能化的环烷†

  摘要：

  在这里，我们描述了一种一锅三酶级联反应，涉及一种细胞色素P450单加氧酶，一种醇脱氢酶和一种还原性氨化酶，用于从环烷烃合成仲胺。胺产品浓度达到了19.6 mM。还证明了环己烷的制备规模胺化反应的时空产率为2 g L -1 d -1。

  DOI：

  10.1039/c7ob02569f

文献信息

• PURIFICATION OF ALKENYL COMPOUNDS
  申请人：——

  公开号：US20020038059A1

  公开（公告）日：2002-03-28

  A process for purifying alkenyl compounds having a divalent or trivalent heteroatom in the &agr;-position relative to the double bond by distillation comprises carrying out at least two distillations in which the purified alkenyl compounds are obtained from the gas phase by condensation, where the time between the first distillation after the synthesis of the alkenyl compounds and at least one further distillation is at least one day and the purified alkenyl compounds have an APHA color number of <30.

  一种用蒸馏法纯化α-位于双键旁的含二价或三价杂原子的烯基化合物的方法，包括进行至少两次蒸馏，其中通过冷凝从气相中获得纯化的烯基化合物，第一次蒸馏后至少一次进一步蒸馏的时间至少为一天，纯化的烯基化合物的APHA色数小于30。
• Process for disproportionating silanes
  申请人：MITSUI TOATSU CHEMICALS, Inc.

  公开号：EP0206621A1

  公开（公告）日：1986-12-30

  A process for disproportionating silanes, which comprises contacting a silane having at least one Si-H bond represented by the general formula wherein R represents an alkyl or aryl group, X represents a halogen atom or an alkoxy group, ℓis 0, 1 or 2, and m is 1, 2 or 3 and ℓ+m is 1, 2 or 3, and when fis 2, R's may be identical or different, and when ℓ+m is 1 or 2, X's may be identical or different, with a reaction product of a strong acid-type cation exchange resin with an amine.

  一种歧化硅烷的工艺，其包括与具有至少一个 Si-H 键的硅烷接触，该硅烷由通式表示 其中 R 代表烷基或芳基，X 代表卤素原子或烷氧基，ℓ 为 0、1 或 2，m 为 1、2 或 3，ℓ+m 为 1、2 或 3，当 f 为 2 时，R 可以相同或不同，当 ℓ+m 为 1 或 2 时，X 可以相同或不同。
• Resin composition for laser engraving, relief printing starting plate for laser engraving and process for producing the same
  申请人：Fujifilm Corporation

  公开号：EP2301750A1

  公开（公告）日：2011-03-30

  A resin composition for laser engraving is provided that includes (a) a binder polymer having a reactive group, (b) a compound having a hydrophilic group and a bonding group that can react with the reactive group, and (c) a crosslinking agent.

  提供了一种用于激光雕刻的树脂组合物，其中包括 (a) 具有活性基团的粘合剂聚合物，(b) 具有亲水性基团和可与活性基团反应的键合基团的化合物，以及 (c) 交联剂。
• Resin composition for laser engraving, relief printing plate precursor for laser engraving and process for producing same, process for making relief printing plate, and relief printing plate
  申请人：Fujifilm Corporation

  公开号：EP2565046A2

  公开（公告）日：2013-03-06

  Disclosed are a resin composition for laser engraving, a relief printing plate precursor for laser engraving and process for producing the same, a process for making relief printing plate, and a relief printing. The resin composition for laser engraving comprising: (Component A) a compound represented by following Formula (1), and (Component B) a binder polymer having a functional group that is capable of reacting with a hydrolyzable silyl group and/or a silanol group and thereby forming a crosslinked structure: wherein in Formula (1), W, X and Y each independently represent a hydrolyzable group selected from the group consisting of an alkoxy group, an aryloxy group, a mercapto group, a halogen atom, an amide group, an acetoxy group, an amino group and an isopropenoxy group, or a hydroxy group; L represents a divalent linking group or a single bond; Z1 represents a divalent group having 4 to 45 carbon atoms in total and containing at least two of a unit selected from an ethylene oxide unit and a propylene oxide unit; Z2 represents an alkyl group having 7 or less carbon atoms, or a benzyl group; and the sum of the numbers of carbon atoms of L, Z1 and Z2 is 10 to 50.

  本发明公开了一种用于激光雕刻的树脂组合物、一种用于激光雕刻的浮雕印版前体及其生产工艺、一种浮雕印版的生产工艺以及一种浮雕印刷。 激光雕刻用树脂组合物包括：（A 组分）由下式（1）表示的化合物；和（B 组分）具有能与可水解硅基和/或硅醇基反应从而形成交联结构的官能团的粘合剂聚合物： 式（1）中，W、X 和 Y 各自独立地代表可水解基团，该基团选自由烷氧基、芳氧基、巯基、卤素原子、酰胺基、乙酰氧基、氨基和异丙烯氧基或羟基组成的组；L 代表二价连接基团或单键；Z1 代表总共具有 4 至 45 个碳原子的二价基团，至少含有两个选自环氧乙烷单元和环氧丙烷单元的单元；Z2 代表具有 7 个或更少碳原子的烷基或苄基；L、Z1 和 Z2 的碳原子数之和为 10 至 50。
• Stabilizing and/or lowering the color number of alkenyl compounds
  申请人：——

  公开号：US20020091254A1

  公开（公告）日：2002-07-11

  A process is provided for stabilizing and/or lowering the color number of alkenyl compounds containing a divalent or trivalent heteroatom in the &agr;-position to the double bond, wherein an oxidizing agent is added to the alkenyl compounds.

  提供了一种稳定和/或降低在双键的&agr;-位上含有二价或三价杂原子的烯基化合物色数的工艺，其中在烯基化合物中加入了氧化剂。