Silane, diphenyldi(but-3-en-1-yloxy)- | 154854-46-3

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: Silane, diphenyldi(but-3-en-1-yloxy)-
• 英文别名: bis(but-3-enoxy)-diphenylsilane
• CAS: 154854-46-3
• 化学式: C₂₀H₂₄O₂Si
• 分子量: 324.495
• InChiKey: ZNXQEKHFHWZJRC-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.43
• 重原子数：
  23
• 可旋转键数：
  10
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.2
• 拓扑面积：
  18.5
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  Silane, diphenyldi(but-3-en-1-yloxy)- 在 Grubbs catalyst first generation 作用下， 以 二氯甲烷 为溶剂， 生成 (Z)-2,2-Diphenyl-4,5,8,9-tetrahydro-[1,3,2]dioxasilonine 、 (E)-2,2-Diphenyl-4,5,8,9-tetrahydro-[1,3,2]dioxasilonine
  参考文献：
  名称：

  Silicon tethered ring-closing metathesis reactions for self- and cross-coupling of alkenols

  摘要：

  The title process can be used to couple allylic, homoallylic, and bishomoallylic alkenols. Cyclic silaketals with ring sizes from 7-11 members can all be formed. This constitutes a general and versatile strategy for approximately doubling the molecular complexity of readily available alkenol precursors. (C) 1999 Elsevier Science Ltd. An rights reserved.

  DOI：

  10.1016/s0040-4039(98)02697-5
• 作为产物：
  描述：

  3-丁烯-1-醇 、 二苯二氯硅烷 在 三乙胺 作用下， 以 二氯甲烷 为溶剂， 以82%的产率得到Silane, diphenyldi(but-3-en-1-yloxy)-
  参考文献：
  名称：

  Silicon tethered ring-closing metathesis reactions for self- and cross-coupling of alkenols

  摘要：

  The title process can be used to couple allylic, homoallylic, and bishomoallylic alkenols. Cyclic silaketals with ring sizes from 7-11 members can all be formed. This constitutes a general and versatile strategy for approximately doubling the molecular complexity of readily available alkenol precursors. (C) 1999 Elsevier Science Ltd. An rights reserved.

  DOI：

  10.1016/s0040-4039(98)02697-5

文献信息

• Silicon tethered ring-closing metathesis reactions for self- and cross-coupling of alkenols
  作者：Thomas R. Hoye、Michele A. Promo

  DOI：10.1016/s0040-4039(98)02697-5

  日期：1999.2

  The title process can be used to couple allylic, homoallylic, and bishomoallylic alkenols. Cyclic silaketals with ring sizes from 7-11 members can all be formed. This constitutes a general and versatile strategy for approximately doubling the molecular complexity of readily available alkenol precursors. (C) 1999 Elsevier Science Ltd. An rights reserved.