1-bromo-3-methyloctane

• 分子结构分类: 有机化合物 - 有机卤素化合物 - 有机溴化物
• 英文名称: 1-bromo-3-methyloctane
• 英文别名: (R)(S)-1-bromo-3-methyloctane；1-Brom-3-methyl-octan
• 化学式: C₉H₁₉Br
• 分子量: 207.154
• InChiKey: PZZBSMKSCWYJJW-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.8
• 重原子数：
  10
• 可旋转键数：
  6
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  1-bromo-3-methyloctane 在 lithium aluminium tetrahydride 、 magnesium 作用下， 以 乙醚 为溶剂， 反应 5.0h， 生成 4-methylnonan-1-ol
  参考文献：
  名称：

  Carpita, Adriano; Magistris, Elisabetta De; Rossi, Renzo, Gazzetta Chimica Italiana, 1989, vol. 119, # 2, p. 99 - 106

  摘要：

  DOI：
• 作为产物：
  描述：

  辛酸甲酯 在 platinum(IV) oxide lithium aluminium tetrahydride 、 氢气 、 lithium bromide 作用下， 以 吡啶 、 甲醇 、 乙醚 、 丙酮 为溶剂， -78.0~100.0 ℃ 、10.13 MPa 条件下， 反应 22.0h， 生成 1-bromo-3-methyloctane
  参考文献：
  名称：

  Carpita, Adriano; Magistris, Elisabetta De; Rossi, Renzo, Gazzetta Chimica Italiana, 1989, vol. 119, # 2, p. 99 - 106

  摘要：

  DOI：

文献信息

• Polgar; Robinson, Journal of the Chemical Society, 1945, p. 393
  作者：Polgar、Robinson

  DOI：——

  日期：——
• Insect pheromones and their analogues XLIII. Chiral pheromones from (S)-(+)-3,7-dimethylocta-1,6-diene 3. Synthesis of (4R)-4-methylnonan-1-OL — Sex pheromone of Tenebrio molitor and its racemic analogue
  作者：V. N. Odinokov、G. Yu. Ishmuratov、M. P. Yakovleva、O. V. Sokol'skaya、R. Ya. Kharisov、É. P. Serebryakov、G. A. Tolstikov

  DOI：10.1007/bf00630443

  日期：1992.11
• 318. Studies in the polyene series. Part XLVI. The synthesis of o-tolyl and mesityl analogues of vitamin A acid
  作者：K. R. Bharucha、B. C. L. Weedon

  DOI：10.1039/jr9530001571

  日期：——
• The Monomethyldecoic Acids
  作者：C. V. Wilson

  DOI：10.1021/ja01228a029

  日期：1945.12
• Synthesis of novel narrow-band-gap copolymers based on [1,2,5]thiadiazolo[3,4-f]benzotriazole and their application in bulk-heterojunction photovoltaic devices
  作者：Yang Dong、Wanzhu Cai、Xiaowen Hu、Chengmei Zhong、Fei Huang、Yong Cao

  DOI：10.1016/j.polymer.2012.02.014

  日期：2012.3

  Two novel conjugated alternating copolymers with [1,2,5]thiadiazolo[3,4-f]benzotriazole as acceptor and 9,9-dioctylfluorene or N-9'-heptadecanyl-carbazole as donors respectively, were synthesized by Suzuki polycondensation. Both of the two copolymers have nearly ideal band gaps and show excellent absorption spectra in near infrared region. Polymer solar cells based on the blends of them and [6,6]-phenyl-C-71 butyric acid methyl ester show excellent performance when using a water/alcohol soluble conjugated polymer as cathode interlayer, which exhibit a maximum power conversion efficiency of 3.17% with the short-circuit current density of 8.50 mA/cm(2), the open-circuit voltage of 0.70 V and the fill factor of 41%. Our results demonstrate that [1,2,5]thiadiazolo[3,4-f]benzotriazole is a promising acceptor unit for low band gap polymer donor materials design. (C) 2012 Elsevier Ltd. All rights reserved.