2,4,6-triisopropylphenylgermane | 190080-49-0

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 2,4,6-triisopropylphenylgermane
• 英文别名: [2,4,6-Tri(propan-2-yl)phenyl]germane；[2,4,6-tri(propan-2-yl)phenyl]germane
• CAS: 190080-49-0
• 化学式: C₁₅H₂₆Ge
• 分子量: 278.961
• InChiKey: MSIGLHPASFPNFU-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.05
• 重原子数：
  16
• 可旋转键数：
  3
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.6
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  N-氯代丁二酰亚胺 、 2,4,6-triisopropylphenylgermane 以 四氢呋喃 为溶剂， 以71%的产率得到2,4,6-triisopropylphenyl(chloro)germane
  参考文献：
  名称：

  New (2,4,6-Triisopropylphenyl) Hydro-, Halo- and Hydrohalogermanes

  摘要：

  New hydro-, halo- and hydrohalogermanes of the types IsGeH(3-n)Cl(n) (n = 0, 1, 3, Is = 2,4,6-triisopropylphenyl) and Is(R)GeH2-nXn (n = 0 or 2, X = Cl, F), potential precursors of stable, low-coordinated species of germanium, have been synthesized. All of them are substituted by at least one bulky 2,4,6-triisopropylphenyl group, R being a second Is group, a mesityl, a pentamethylcyclopentadienyl or a fluorenyl group.

  DOI：

  10.1080/00945719708000207
• 作为产物：
  描述：

  magnesium,1,3,5-tri(propan-2-yl)benzene-6-ide,bromide 、 四氯化锗 、 lithium aluminium tetrahydride 在 盐酸 作用下， 以 四氢呋喃 、 乙醚 为溶剂， 以59%的产率得到2,4,6-triisopropylphenylgermane
  参考文献：
  名称：

  New (2,4,6-Triisopropylphenyl) Hydro-, Halo- and Hydrohalogermanes

  摘要：

  New hydro-, halo- and hydrohalogermanes of the types IsGeH(3-n)Cl(n) (n = 0, 1, 3, Is = 2,4,6-triisopropylphenyl) and Is(R)GeH2-nXn (n = 0 or 2, X = Cl, F), potential precursors of stable, low-coordinated species of germanium, have been synthesized. All of them are substituted by at least one bulky 2,4,6-triisopropylphenyl group, R being a second Is group, a mesityl, a pentamethylcyclopentadienyl or a fluorenyl group.

  DOI：

  10.1080/00945719708000207

文献信息

• Synthesis, Structure, and Reactivity of Neutral Hydrogen-Substituted Ruthenium Silylene and Germylene Complexes
  作者：Paul G. Hayes、Rory Waterman、Paul B. Glaser、T. Don Tilley

  DOI：10.1021/om900348m

  日期：2009.9.14

  Reaction of. Cp*((Pr2MeP)-Pr-i)RuCl (1) with 0.5 equiv of Mg(CH2Ph)(2)(THF)(2) afforded the benzyl complex Cp*((Pr2MeP)-Pr-i)Ru(eta(3)-CH2Ph) (2). Complex 2 readily reacted with, Primary silanes H3SiR (R = trip, dmp, Mes(F); trip = 2,4,6-Pr-i(3)-C6H2, dmp = 2,6-Mes(2)-C6H3, Mes(F) = 2,4,6-(CF3)(3)-C6H2) to liberate toluene and afford hydrogen-substituted silylene complexes Cp*((Pr2MeP)-Pr-i)(H)Ru=SiH(R) (R = trip, 3; dmp, 4; Mes(F), 5]. Complexes 3-5 exhibit characteristic SiH H-1 NMR resonances downfield of 8 ppm and very small (2)J(SiH) coupling constants (8-10 Hz). The solid state structures of complexes 3 and 5 feature short Ru-Si distances of 2.205(1) and 2.1806(9) angstrom, respectively, and planar silicon centers. In addition, the silylene complex Cp*((Pr2MeP)-Pr-i)(H)Ru=SiPh(trip) (6) and the unusual, chlorine-substituted species Cp*((Pr2MeP)-Pr-i)(H)Ru=SiCl(R) [R = trip, 7; dmp, 8] were prepared. Hydrogen-substituted ruthenium germylene complex Cp*((Pr2MeP)-Pr-i)(H)Ru=GeH(trip) (9) was prepared similarly by reaction of 2 with tripGeH(3). Complex 9 is the first structurally characterized ruthernium germylene complex and has a remarkably short Ru-Ge distance of 2.2821(6) angstrom. Complex 9 adds H2O across its Ru=Ge bond to give Cp*((Pr2MeP)-Pr-i)(H)(2)RuGeH(OH)(trip) (10).
• New (2,4,6-Triisopropylphenyl) Hydro-, Halo- and Hydrohalogermanes
  作者：M. A. Chaubon、B. Dittrich、J. Escudié、H. Ramdane、H. Ranaivonjatovo、J. Satgé

  DOI：10.1080/00945719708000207

  日期：1997.4

  New hydro-, halo- and hydrohalogermanes of the types IsGeH(3-n)Cl(n) (n = 0, 1, 3, Is = 2,4,6-triisopropylphenyl) and Is(R)GeH2-nXn (n = 0 or 2, X = Cl, F), potential precursors of stable, low-coordinated species of germanium, have been synthesized. All of them are substituted by at least one bulky 2,4,6-triisopropylphenyl group, R being a second Is group, a mesityl, a pentamethylcyclopentadienyl or a fluorenyl group.