bis(4-dodecylphenyl)iodonium chloride | 143086-87-7

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: bis(4-dodecylphenyl)iodonium chloride
• 英文别名: Bis(4-dodecylphenyl)iodanium chloride；bis(4-dodecylphenyl)iodanium;chloride
• CAS: 143086-87-7
• 化学式: C₃₆H₅₈I*Cl
• 分子量: 653.214
• InChiKey: MHAWBNRTGDFEKR-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  5.75
• 重原子数：
  38
• 可旋转键数：
  24
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.67
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  溴五氟苯 、 bis(4-dodecylphenyl)iodonium chloride 在 gallium(III) trichloride 、 正丁基锂 作用下， 以 乙醚 、 正己烷 、 二氯甲烷 为溶剂， 反应 2.0h， 以59%的产率得到bis(4-dodecylphenyl)iodonium tetrakis(pentafluorophenyl)gallate
  参考文献：
  名称：

  Synthesis, properties and photolysis of new iodonium tetrakis(pentafluorophenyl)gallate photoinitiators and comparison with their indate and aluminate analogs

  摘要：

  A series of new iodonium tetrakis (pentafluorophenyl) gallates were synthesized in high yield via an improved preparation of the lithium gallate, their photoproducts analyzed by UV, F-19 NMR and GC-MS spectra and a photolysis mechanism postulated. The stability of these photoinitiators was also compared with their borate, aluminate and indate analogs. (C) 2002 Published by Elsevier Science Ltd.

  DOI：

  10.1016/s0040-4020(02)00497-0
• 作为产物：
  描述：

  potassium metaperiodate 、 正十二烷基苯 在 硫酸 、 溶剂黄146 作用下， 以31%的产率得到bis(4-dodecylphenyl)iodonium chloride
  参考文献：
  名称：

  MASS POLYMERIZABLE POLYCYCLOOLEFIN COMPOSITIONS CONTAINING SOLUBLE PHOTOACID GENERATORS

  摘要：

  根据本发明的实施例，包括可溶性光酸发生剂、有机钯化合物、光敏剂和一种或多种烯烃单体的组合物被涵盖在内，当该组合物暴露于适当的光辐射下时，这些单体会经历乙烯基加成聚合反应，形成一个基本透明的薄膜。其中使用的单体具有不同的光学和机械性能，因此这些组合物可以定制成具有各种光电性能的薄膜。因此，本发明的组合物在各种应用中都是有用的，包括作为涂料、封装材料、填充剂、平整剂等。

  公开号：

  US20210380733A1

文献信息

• SILICON-CONTAINING PARTICLE, PROCESS FOR PRODUCING THE SAME, ORGANIC-POLYMER COMPOSITION, CERAMIC, AND PROCESS FOR PRODUCING THE SAME
  申请人：Dow Corning Toray Co., Ltd.

  公开号：EP2241586A1

  公开（公告）日：2010-10-20

  A process for producing silicon-containing particles having an extremely small particle diameter by a simple process without using surface-active agents or the like. The process is characterized by forming silicon-containing particles as a result of phase separation from an organic polymer, wherein the phase separation is achieved by an addition reaction, condensation reaction, ring-opening reaction, or a radical reaction of a curable silicon-containing compound or a curable composition that contains said compound, and the silicon-containing compound or the composition is maintained in a uniform liquid, fused, or dissolved phase with the organic polymer that is free of silicon and does not participate in the curing reaction of the silicon-containing compound or the composition.

  一种不使用表面活性剂等，通过简单工艺生产具有极小颗粒直径的含硅颗粒的工艺。该工艺的特点是通过与有机聚合物的相分离形成含硅颗粒，其中相分离是通过可固化的含硅化合物或含有所述化合物的可固化组合物的加成反应、缩合反应、开环反应或自由基反应实现的，含硅化合物或组合物与有机聚合物保持在均匀的液相、熔融相或溶解相中，有机聚合物不含硅、不参与含硅化合物或组合物的固化反应。
• SILICON-CONTAINING PARTICLES, METHOD FOR MANUFACTURING THEREOF, OIL COMPOSITION, CERAMIC MATERIAL, AND METHOD FOR MANUFACTURING THEREOF
  申请人：Dow Corning Toray Co., Ltd.

  公开号：EP2271702A2

  公开（公告）日：2011-01-12
• Silicon-Containing Particles, Method For Manufacturing Thereof, Oil Composition, Ceramic Material, And Method For Manufacturing Thereof
  申请人：Harimoto Yukinari

  公开号：US20110045963A1

  公开（公告）日：2011-02-24

  This invention relates to a method for manufacturing silicon-containing particles characterized by preparing a uniform phase comprising a curable composition that includes a silicon-containing compound having in one molecule one or more reactive functional groups per 50 silicon atoms and an oil that does not participate in curing of the composition, then curing the composition, and causing phase separation from the oil for obtaining the silicon-containing particles; and to silicon-containing particles obtained by the above method. The method provides silicon-containing particles of an extremely small diameter in a simple process without the use of surfactants. And the silicon-containing particles possess excellent dispersibility in oil and a high degree of ceramification by baking.
• Silicon-Containing Particle, Process For Producing The Same, Organic-Polymer Composition, Ceramic, And Process For Producing The Same
  申请人：Harimoto Yukinari

  公开号：US20110033708A1

  公开（公告）日：2011-02-10

  A process for producing silicon-containing particles having an extremely small particle diameter by a simple process without using surface-active agents or the like. The process is characterized by forming silicon-containing particles as a result of phase separation from an organic polymer, wherein the phase separation is achieved by an addition reaction, condensation reaction, ring-opening reaction, or a radical reaction of a curable silicon-containing compound or a curable composition that contains said compound, and the silicon-containing compound or the composition is maintained in a uniform liquid, fused, or dissolved phase with the organic polymer that is free of silicon and does not participate in the curing reaction of the silicon-containing compound or the composition.
• US5340898A
  申请人：——

  公开号：US5340898A

  公开（公告）日：1994-08-23