Trichlormethansulfensaeure-<4-chlor-anilid> | 88693-68-9

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: Trichlormethansulfensaeure-<4-chlor-anilid>
• 英文别名: trichloro-methanesulfenic acid-(4-chloro-anilide)；S-Trichlormethyl-N-(4-chlor-phenyl)-thiohydroxylamin；Trichlor-methansulfensaeure-(4-chlor-anilid)；4-Chloro-N-[(trichloromethyl)sulfanyl]aniline；4-chloro-N-(trichloromethylsulfanyl)aniline
• CAS: 88693-68-9
• 化学式: C₇H₅Cl₄NS
• 分子量: 277.001
• InChiKey: YQFNMVVMBFATGJ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.9
• 重原子数：
  13
• 可旋转键数：
  2
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.14
• 拓扑面积：
  37.3
• 氢给体数：
  1
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  Trichlormethansulfensaeure-<4-chlor-anilid> 在 双氧水 作用下， 以 溶剂黄146 为溶剂， 生成 Trichlormethansulfinsaeure-<4-chlor-anilid>
  参考文献：
  名称：

  611.卤代甲烷和乙烷磺酸的芳酰胺

  摘要：

  DOI：

  10.1039/jr9600003058
• 作为产物：
  描述：

  对氯苯胺 、 三氯硫氯甲烷 以 乙醚 为溶剂， 生成 Trichlormethansulfensaeure-<4-chlor-anilid>
  参考文献：
  名称：

  A new synthesis of N-sulfinylamines via β-elimination of chloroform from trichloromethanesulfinamides

  摘要：

  The synthesis of various N-monosubstituted trichloromethanesulfinamides by two alternative and novel procedures is described. All these compounds have been found to undergo base-induced elimination of chloroform with formation of the corresponding N-sulfinylamines. Reaction proceeds smoothly under mild conditions. Copyright (C) 1996 Published by Elsevier Science Ltd

  DOI：

  10.1016/s0040-4039(96)02351-9

文献信息

• 611. Arylamides of halogenated methane- and ethane-sulphonic acids
  作者：W. V. Farrar

  DOI：10.1039/jr9600003058

  日期：——
• 176. The constitution and reactions of thiocarbonyl tetrachloride. Part I. Reaction with arylamines
  作者：Joseph M. Connolly、G. Malcolm Dyson

  DOI：10.1039/jr9340000822

  日期：——
• A new synthesis of N-sulfinylamines via β-elimination of chloroform from trichloromethanesulfinamides
  作者：Samuel Braverman、Marina Cherkinsky

  DOI：10.1016/s0040-4039(96)02351-9

  日期：1997.1

  The synthesis of various N-monosubstituted trichloromethanesulfinamides by two alternative and novel procedures is described. All these compounds have been found to undergo base-induced elimination of chloroform with formation of the corresponding N-sulfinylamines. Reaction proceeds smoothly under mild conditions. Copyright (C) 1996 Published by Elsevier Science Ltd