1,1-bis(2-hydroxyphenyl)propane | 34240-91-0

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 1,1-bis(2-hydroxyphenyl)propane
• 英文别名: bis (2-hydroxyphenyl)-propane；diglycidylether of diphenylolpropane；2-[1-(2-hydroxyphenyl)propyl]phenol
• CAS: 34240-91-0
• 化学式: C₁₅H₁₆O₂
• 分子量: 228.291
• InChiKey: PDFIIHNUDFWDNM-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4
• 重原子数：
  17
• 可旋转键数：
  3
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.2
• 拓扑面积：
  40.5
• 氢给体数：
  2
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  1,1-bis(2-hydroxyphenyl)propane 生成 Methyl 12-ethyl-12H-dibenzo[d,g][1,3]dioxocin-6-carboxylate
  参考文献：
  名称：

  Herbicidal 12-substituted 12H-dibenzo(D,G)(1,3)dioxocin-6-carboxylic

  摘要：

  二苯并[d,g][1,3]二噁喃-6-羧酸在12位被甲基或乙基或一种基团--CH.sub.2 CH.sub.2--取代，并且在其他位置可选择性地被取代，例如甲基4'-氯螺(cyclopropane-1,12'(12'H)-dibenzo[d,g][1,3]二噁喃)-6'-羧基酸，以及它们的农业可接受的酯、酰胺和盐对于控制不良植被是有用的。用于螺环丙烷化合物的1,1-二芳基环丙烷中间体可以通过与苯硫甲基锂试剂反应制备，该试剂由适当取代的1,1-二芳基乙烯前体制备而成。

  公开号：

  US04938790A1
• 作为产物：
  描述：

  丙醛二乙基乙缩醛 、 bromomagnesium phenolate 以 苯 为溶剂， 反应 24.0h， 以70%的产率得到1,1-bis(2-hydroxyphenyl)propane
  参考文献：
  名称：

  Casiraghi, Giovanni; Casnati, Giuseppe; Pochini, Andrea, Journal of the Chemical Society. Perkin transactions I, 1982, p. 805 - 808

  摘要：

  DOI：

文献信息

• Two stage cure two component coating composition containing hydroxyl butyl acrylate polymers
  申请人：Lewin Ann Laura

  公开号：US20060051594A1

  公开（公告）日：2006-03-09

  An acrylic oligomer useful in a two stage curing coating composition having a weight average molecular weight of 100 to 3000, a polydispersity of 1.01 to 1.7 and one or more reactive functionalities reactive with isocyanate groups and having 7.0 to 40.0 weight percent, based on the weight of the acrylic oligomer, of hydroxyl moieties wherein at least 40.0 to 70.0 weight percent of the hydroxyl moieties are provided by hydroxy butyl acrylate and the remaining hydroxyl moieties are provided by fast reacting hydroxyl constituents of hydroxy ethyl acrylate, hydroxy ethyl methacrylate or any mixtures thereof and by slow reacting hydroxyl constituents of secondary hydroxyl containing hydroxy propyl acrylate and secondary hydroxyl containing hydroxy propyl methacrylate and any mixtures thereof.

  一种丙烯酸低聚物，适用于两阶段固化涂料组合物，其重均分子量为100至3000，聚分散度为1.01至1.7，具有与异氰酸酯基反应的一个或多个反应性官能团，并具有7.0至40.0重量百分比的羟基官能团，其中至少40.0至70.0重量百分比的羟基官能团由羟丙基丙烯酸丁酯提供，其余的羟基官能团由羟乙基丙烯酸酯，羟乙基甲基丙烯酸酯或二者的任何混合物以及次级羟基含量的羟丙基丙烯酸酯和次级羟基含量的羟丙基甲基丙烯酸酯和任何混合物提供。
• COMPOSITIONS COMPRISING ALKOXYSILANE-CONTAINING ISOCYANATES AND ACID STABILISERS
  申请人：SPYROU Emmanouil

  公开号：US20150274760A1

  公开（公告）日：2015-10-01

  The present invention relates to a composition comprising (A) an isocyanate of formula (I) OCN-A-SiR 1 R 2 R 3 (I), wherein A is straight-chain, branched, substituted and/or unsubstituted aliphatic hydrocarbyl of 1 to 12 carbon atoms or substituted or unsubstituted cycloaliphatic hydrocarbyl of 4 to 18 carbon atoms, wherein R 1 is selected from the group comprising —O—R alk , wherein R 2 and R 3 are each independently selected from the group of substituents comprising —R alk and —O—R alk , and wherein —R alk is hydrocarbyl of 1 to 6 carbon atoms, and B) a Bronstedt or Lewis acid or a compound which releases a Bronstedt or Lewis acid at room temperature; and also to a process for producing a stabilized alkoxysilane-containing isocyanate comprising the step of adding a Lewis or Bronstedt acid or a compound which releases a Bronstedt or Lewis acid at room temperature to an alkoxysilane-containing isocyanate.

  本发明涉及一种组合物，包括（A）式（I）OCN-A-SiR1R2R3（I）的异氰酸酯，其中A是1至12个碳原子的直链、支链、取代和/或未取代的脂肪烃基或4至18个碳原子的取代或未取代的环脂肪烃基，其中R1选自包括-O-Ralk的基团，其中R2和R3各自独立地选自包括-Ralk和-O-Ralk的取代基团的群，其中-Ralk是1至6个碳原子的烃基，以及（B）布朗斯特或路易斯酸或在室温下释放布朗斯特或路易斯酸的化合物；还涉及一种生产稳定的含烷氧基硅烷的异氰酸酯的方法，该方法包括向含烷氧基硅烷的异氰酸酯中加入路易斯或布朗斯特酸或在室温下释放布朗斯特或路易斯酸的化合物的步骤。
• Herbicidal 12-substituted 12H-dibenzo[d,g]dioxocin-6-carboxylic acids
  申请人：The Dow Chemical Company

  公开号：US05158597A1

  公开（公告）日：1992-10-27

  Dibenzo[d,g][1,3]dioxocin-6-carboxylic acids substituted by methyl or ethyl or a moiety --CH.sub.2 CH.sub.2 -- at the 12-position and optionally substituted at other positions, such as methyl 4'-chlorospiro(cyclopropane-1,12'(12'H)-dibenzo[d,g][1,3]dioxocin)-6'-carb oxylic acid, and their agriculturally acceptable esters, amides, and salts are useful for the control of undesirable vegetation. The 1,1-diarylcyclopropane intermediates required for the spirocyclopropane compounds can be prepared from appropriately substituted 1,1-diarylethene procursors by reaction with phenylthiomethyl lithium reagent.

  甲基或乙基或一个基团--CH.sub.2 CH.sub.2 --取代的Dibenzo[d,g][1,3]二噁烷-6-羧酸以及其在其他位置如甲基4'-氯代螺环丙烷-1,12'(12'H)-dibenzo[d,g][1,3]二噁烷)-6'-羧酸中的取代物，以及它们的农业可接受的酯，酰胺和盐对于控制不良的植被是有用的。制备螺环丙烷化合物所需的1,1-二芳基环丙烷中间体可以通过与苯硫甲基锂试剂反应的适当取代的1,1-二芳基乙烯前体制备。
• Method of preparing bis-phenol ethers
  申请人：The Dow Chemical Company

  公开号：US04999448A1

  公开（公告）日：1991-03-12

  A method of preparing a compound of Formula XII ##STR1## wherein R.sub.1 and R.sub.2 together represent the fragment --Ch.sub.2 CH.sub.2 --; each R.sup.4 independently represents C.sub.1 -C.sub.4 alkyl optionally substituted with 1 to 2 C.sub.1 -C.sub.4 alkoxy groups; and X, X', Y, Y', Z, and Z' each, independently represent H, F, Cl, Br, I, CN, NO.sub.2, C.sub.1 -C.sub.4 alkyl, C.sub.1 -C.sub.4 alkoxy, phenoxy, C.sub.1 -C.sub.4 alkylthio, phenylthio, or C.sub.1 -C.sub.4 dialkylamino, wherein each alkyl, alkoxy, and alkylthio group is optionally substituted with one or more compatible groups selected from C.sub.1 -C.sub.4 alkoxy, C.sub.1 -C.sub.4 alkylthio, F, Cl, Br, CN, and phenyl and wherein each phenyl group is optionally substituted with up to 3 groups selected from F, Cl, Br, CN, CF.sub.3, C.sub.1 -C.sub.4 alkyl, and C.sub.1 -C.sub.4 alkoxy.

  一种制备式为XII的化合物的方法：##STR1## 其中R.sub.1和R.sub.2一起代表--Ch.sub.2 CH.sub.2--；每个R.sup.4独立地代表C.sub.1-C.sub.4烷基，可选择地取代1至2个C.sub.1-C.sub.4烷氧基；而X、X'、Y、Y'、Z和Z'各自独立地代表H、F、Cl、Br、I、CN、NO.sub.2、C.sub.1-C.sub.4烷基、C.sub.1-C.sub.4烷氧基、苯氧基、C.sub.1-C.sub.4烷基硫醚、苯基硫醚或C.sub.1-C.sub.4二烷基氨基，其中每个烷基、烷氧基和烷基硫醚基可选择地取代一个或多个与C.sub.1-C.sub.4烷氧基、C.sub.1-C.sub.4烷基硫醚基、F、Cl、Br、CN和苯基相容的基团，而每个苯基可选择地取代最多3个F、Cl、Br、CN、CF.sub.3、C.sub.1-C.sub.4烷基和C.sub.1-C.sub.4烷氧基。
• Initiator systems comprising beta-ketone compounds and bonding compositions made therewith
  申请人：3M Innovative Properties Company

  公开号：US20030228973A1

  公开（公告）日：2003-12-11

  The invention provides initiator systems capable of initiating polymerization. More specifically, the invention relates to initiator systems comprising a complexed initiator and a &bgr;-ketone compound decomplexer. The invention further relates to the use of these initiator systems for initiating polymerization, as well as kits, bonding compositions, and polymerized compositions made therewith, and coated substrates and bonded articles prepared therefrom.

  本发明提供了能够启动聚合反应的引发系统。更具体地说，本发明涉及包括复合引发剂和β-酮化合物解离剂的引发系统。本发明还涉及使用这些引发系统启动聚合反应，以及使用这些引发系统制备的工具包、粘合剂组合物和聚合物组合物，以及制备的涂层基材和粘接制品。