2.6-Dimethoxy-benzoyl-phosphonsaeurediethylester | 16656-44-3

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 2.6-Dimethoxy-benzoyl-phosphonsaeurediethylester
• 英文别名: Diethoxyphosphoryl-(2,6-dimethoxyphenyl)methanone
• CAS: 16656-44-3
• 化学式: C₁₃H₁₉O₆P
• 分子量: 302.264
• InChiKey: NXHLDHFIUIKBRC-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.6
• 重原子数：
  20
• 可旋转键数：
  8
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.46
• 拓扑面积：
  71.1
• 氢给体数：
  0
• 氢受体数：
  6

反应信息

• 作为反应物：
  描述：

  2.6-Dimethoxy-benzoyl-phosphonsaeurediethylester 在 三(2-氯乙基)胺 、 硫酸 作用下， 以 氯仿 为溶剂， 反应 0.08h， 以62%的产率得到2,6-二甲氧基苯甲腈
  参考文献：
  名称：

  二烷基酰基膦酸酯的施密特反应

  摘要：

  酮的施密特重排的范围已扩展到酰基膦酸二烷基酯 (11a-111)。令人惊讶的是，发现 11a-11d 和 11g，其中酰基部分是单独的苯甲酰基或带有吸电子或轻度放电子取代基的苯甲酰基，产生了绝大多数由芳基的 C 到 N 迁移产生的产物组（N-芳基氨基甲酰基膦酸酯，12 和 N-芳基甲酰胺，15）。相反，带有强大的电子释放对烷氧基的芳烃羰基膦酸酯产生由膦酸酯基团从 C 迁移到 N 或消除的产物（N-芳烃羰基磷酰胺二烷基酯，13 和芳烃甲腈，分别为 17）

  DOI：

  10.1021/ja00082a024
• 作为产物：
  描述：

  2,6-二甲氧基苯甲酰氯 、 亚磷酸三乙酯 反应 3.0h， 以90%的产率得到2.6-Dimethoxy-benzoyl-phosphonsaeurediethylester
  参考文献：
  名称：

  二烷基酰基膦酸酯的施密特反应

  摘要：

  酮的施密特重排的范围已扩展到酰基膦酸二烷基酯 (11a-111)。令人惊讶的是，发现 11a-11d 和 11g，其中酰基部分是单独的苯甲酰基或带有吸电子或轻度放电子取代基的苯甲酰基，产生了绝大多数由芳基的 C 到 N 迁移产生的产物组（N-芳基氨基甲酰基膦酸酯，12 和 N-芳基甲酰胺，15）。相反，带有强大的电子释放对烷氧基的芳烃羰基膦酸酯产生由膦酸酯基团从 C 迁移到 N 或消除的产物（N-芳烃羰基磷酰胺二烷基酯，13 和芳烃甲腈，分别为 17）

  DOI：

  10.1021/ja00082a024

文献信息

• Ink composition
  申请人：Fujifilm Corporation

  公开号：EP2236571A1

  公开（公告）日：2010-10-06

  The present invention provides an ink composition containing: a radical polymerizable compound; a photopolymerization initiator, and a chain transfer agent; and the radical polymerizable compound includes a monofunctional monomer at a ratio of 85% by weight or more in the total weight of the radical polymerizable compound.

  本发明提供了一种油墨组合物，其中含有：可自由基聚合的化合物、光聚合引发剂和链转移剂；可自由基聚合的化合物包括单官能团单体，在可自由基聚合的化合物总重量中的比例为 85% （重量比）或更高。
• Sprecher Milon, Kost Daniel, J. Amer. Chem. Soc, 116 (1994) N 3, S 1016-1026
  作者：Sprecher Milon, Kost Daniel

  DOI：——

  日期：——
• INK SET FOR INKJET RECORDING AND INKJET RECORDING METHOD
  申请人：UMEBAYASHI Tsutomu

  公开号：US20080180503A1

  公开（公告）日：2008-07-31

  An ink set for inkjet recording is provided that includes at least a colored liquid composition comprising at least a radically polymerizable compound, a photopolymerization initiator, and a colorant, and an undercoat liquid composition comprising at least a radically polymerizable compound and a photopolymerization initiator, the colored liquid composition comprising as the photopolymerization initiator at least one type of α-aminoacetophenone compound, and the undercoat liquid composition comprising as the photopolymerization initiator at least one type of compound selected from the group consisting of an acylphosphine oxide compound, an α-hydroxyacetophenone compound, and an oxime ester compound. There is also provided an inkjet recording method employing the ink set for inkjet recording, the method including a step of applying the undercoat liquid composition on top of a recording medium, a step of semi-curing the undercoat liquid composition, and a step of carrying out image formation by discharging the colored liquid composition on top of the semi-cured undercoat liquid composition.
• INK COMPOSITION AND INKJET RECORDING METHOD USING THE SAME
  申请人：MATSUMURA Tokihiko

  公开号：US20080182031A1

  公开（公告）日：2008-07-31

  An ink composition of the present invention is disclosed, which contains (i) a sensitizing dye represented by the following Formula (I); (ii) at least one polymerization initiator selected from the group consisting of α-aminoketones and acyl phosphine oxides; and (iii) an ethylenically unsaturated bond-containing polymerizable compound. In Formula (I), X represents O, S or NR; n represents an integer of 0 or 1; R represents a hydrogen atom, an alkyl group or an acyl group; R 1 to R 8 each independently represent a hydrogen atom or a monovalent substituent; R 1 and R 2 , R 2 and R 3 , and R 3 and R 4 may be connected to each other to form a ring; and R 5 or R 6 may be connected to R 7 or R 8 to form an aliphatic ring but not to form an aromatic ring.
• INK COMPOSITION
  申请人：UMEBAYASHI Tsutomu

  公开号：US20090087576A1

  公开（公告）日：2009-04-02

  An ink composition is provided that includes compound A represented by Formula (I) below, compound B represented by Formula (II) below, and a polymerizable compound, wherein, in Formula (I), X denotes O, S, or NR a , n1 denotes 0 or 1, R a , R 1 , R 2 , R 3 , R 4 , R 5 , R 6 , R 7 , R 8 , R 9 , and R 10 independently denote a hydrogen atom or a monovalent substituent, and two of R 1 , R 2 , R 3 , R 4 , R 5 , R 6 , R 7 , and R 8 that are adjacent may be linked to each other to form a ring, and in Formula (II), X denotes O, S, or NR b , n2 denotes 0 or 1, R b , R 11 , R 12 , R 13 , R 14 , R 15 , R 16 , R 17 , and R 18 independently denote a hydrogen atom or a monovalent substituent, and two of R 11 , R 12 , R 13 , and R 14 that are adjacent may be linked to each other to form a ring. There is also provided an inkjet recording method comprising (a) a step of discharging the ink composition onto a recording medium, and (b) a step of curing the ink composition by irradiating the discharged ink composition with actinic radiation.