bis(2-bromophenyl)-phenylsilane | 353281-18-2

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: bis(2-bromophenyl)-phenylsilane
• CAS: 353281-18-2
• 化学式: C₁₈H₁₄Br₂Si
• 分子量: 418.203
• InChiKey: XVODUTFWEQYHGI-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.46
• 重原子数：
  21.0
• 可旋转键数：
  3.0
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  0.0
• 氢给体数：
  0.0
• 氢受体数：
  0.0

反应信息

• 作为反应物：
  描述：

  bis(2-bromophenyl)-phenylsilane 在 lithium aluminium tetrahydride 、 正丁基锂 、 三乙胺 作用下， 以 四氢呋喃 、 四氯化碳 、 乙醚 、 正己烷 为溶剂， 反应 8.5h， 生成 cis-9,10-diphenyl-9,10-dihydro-9,10-disilaanthracene
  参考文献：
  名称：

  Radical isomerization of 9,10-dihydro-9,10-disilaanthracene derivatives: stabilization factor of silyl radicals

  摘要：

  In order to examine the nature of the silyl radical in the disilaanthracene framework, separation and radical isomerization of the cis and trans isomers of the disilaanthracene derivatives were investigated. When a pentane solution of the disilaanthracene derivative was irradiated with a 400 W mercury lamp in the presence of DTBP for 4 h. both isomers readily isomerized to give a mixture of cis and trans isomers in a ratio of ca. 50:50. However, no such isomerization reaction of 9,10-dihydro-9-silaanthracene derivatives occurred under similar conditions. (C) 2001 Elsevier Science B.V. All rights reserved.

  DOI：

  10.1016/s0022-328x(00)00942-6
• 作为产物：
  描述：

  苯基二氯硅烷 、 1,2-二溴苯 在 正丁基锂 作用下， 以 四氢呋喃 、 乙醚 、 正己烷 为溶剂， 反应 2.33h， 以70%的产率得到bis(2-bromophenyl)-phenylsilane
  参考文献：
  名称：

  Radical isomerization of 9,10-dihydro-9,10-disilaanthracene derivatives: stabilization factor of silyl radicals

  摘要：

  In order to examine the nature of the silyl radical in the disilaanthracene framework, separation and radical isomerization of the cis and trans isomers of the disilaanthracene derivatives were investigated. When a pentane solution of the disilaanthracene derivative was irradiated with a 400 W mercury lamp in the presence of DTBP for 4 h. both isomers readily isomerized to give a mixture of cis and trans isomers in a ratio of ca. 50:50. However, no such isomerization reaction of 9,10-dihydro-9-silaanthracene derivatives occurred under similar conditions. (C) 2001 Elsevier Science B.V. All rights reserved.

  DOI：

  10.1016/s0022-328x(00)00942-6

文献信息

• Radical isomerization of 9,10-dihydro-9,10-disilaanthracene derivatives: stabilization factor of silyl radicals
  作者：Kozaburo Nishiyama、Makoto Oba、Hidenori Takagi、Takeshi Saito、Yoko Imai、Izumi Motoyama、Shigeru Ikuta、Hiroshi Hiratsuka

  DOI：10.1016/s0022-328x(00)00942-6

  日期：2001.4

  In order to examine the nature of the silyl radical in the disilaanthracene framework, separation and radical isomerization of the cis and trans isomers of the disilaanthracene derivatives were investigated. When a pentane solution of the disilaanthracene derivative was irradiated with a 400 W mercury lamp in the presence of DTBP for 4 h. both isomers readily isomerized to give a mixture of cis and trans isomers in a ratio of ca. 50:50. However, no such isomerization reaction of 9,10-dihydro-9-silaanthracene derivatives occurred under similar conditions. (C) 2001 Elsevier Science B.V. All rights reserved.