1-Chlor-2-methyl-2-phenylbutan | 49623-36-1

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 1-Chlor-2-methyl-2-phenylbutan
• 英文别名: (1-Chloro-2-methylbutan-2-yl)benzene
• CAS: 49623-36-1
• 化学式: C₁₁H₁₅Cl
• 分子量: 182.693
• InChiKey: FZIUWYQFYWIJRJ-UHFFFAOYSA-N

物化性质

• 沸点：
  242.2±9.0 °C(Predicted)
• 密度：
  0.992±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  4
• 重原子数：
  12
• 可旋转键数：
  3
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.45
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  重氮甲烷 、 二氧化碳 、 1-Chlor-2-methyl-2-phenylbutan 生成 (+/-)-3-methyl-3-phenyl-valeric acid methyl ester
  参考文献：
  名称：

  Halomethyl-metal compounds. LXIII. Insertion of phenyl(bromodichloromethyl)mercury-derived dichlorocarbene into benzylic carbon-hydrogen bonds. Stereochemistry and mechanism

  摘要：

  DOI：

  10.1021/ja00801a039
• 作为产物：
  描述：

  仲丁基苯 在 三苯基氢化锡 作用下， 生成 1-Chlor-2-methyl-2-phenylbutan
  参考文献：
  名称：

  Halomethyl-metal compounds. LXIII. Insertion of phenyl(bromodichloromethyl)mercury-derived dichlorocarbene into benzylic carbon-hydrogen bonds. Stereochemistry and mechanism

  摘要：

  DOI：

  10.1021/ja00801a039

文献信息

• SYNTHESIS OF A SUBSTITUTED FURAN
  申请人：Agency for Science, Technology and Research

  公开号：US20160122450A1

  公开（公告）日：2016-05-05

  The present invention provides a polymer comprising an aliphatic backbone having a plurality of aromatic rings bonded thereon, said plurality of aromatic rings comprising a first aromatic ring type that has an alkyl halide group substitution on the aromatic ring and a second aromatic ring type that has an optionally substituted ammonium halide group substitution on the aromatic ring. The present invention also provides a method for making an optionally substituted furan, the method comprising the step of subjecting a sugar to a dehydration reaction in the presence of a catalyst comprising said polymer.
• Halomethyl-metal compounds. LXIII. Insertion of phenyl(bromodichloromethyl)mercury-derived dichlorocarbene into benzylic carbon-hydrogen bonds. Stereochemistry and mechanism
  作者：Dietmar. Seyferth、Ying Ming. Cheng

  DOI：10.1021/ja00801a039

  日期：1973.10