3,3',5,5'-tetra-tert-butyl-4,4'-biphenol | 34692-93-8

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 3,3',5,5'-tetra-tert-butyl-4,4'-biphenol
• 英文别名: 3,3',5,5'-tetra-t-butyl-4,4'-biphenol；4-(3,7,11,15-Tetramethyl-6,10,14-hexadecatrienoyl)morpholine；3,5-ditert-butyl-4-(2,6-ditert-butyl-4-hydroxyphenyl)phenol
• CAS: 34692-93-8
• 化学式: C₂₈H₄₂O₂
• 分子量: 410.64
• InChiKey: LYQIPMLFCQTVQK-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  9.5
• 重原子数：
  30
• 可旋转键数：
  5
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.57
• 拓扑面积：
  40.5
• 氢给体数：
  2
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  3,3',5,5'-tetra-tert-butyl-4,4'-biphenol 在 对甲苯磺酸 作用下， 以 2,6-二叔丁基苯酚 、 2-叔丁基苯酚 、 2,4,6-三叔丁基苯酚 、 苯酚 、 4-叔丁基苯酚 为溶剂， 205.0~220.0 ℃ 、50.0 kPa 条件下， 反应 16.0h， 以83%的产率得到4,4'-二羟基联苯
  参考文献：
  名称：

  Method of producing 4,4'-biphenol

  摘要：

  一种生产4,4'-联苯酚的方法，包括以下步骤：为两个或更多步骤准备串联的反应槽；在反应溶剂中依次加入至少一种苯酚，所述苯酚选自苯酚、单烷基苯酚、双烷基苯酚和三烷基苯酚，比例至少为0.5摩尔部分相对于1摩尔部分的3,3',5,5'-四-t-丁基-4,4'-联苯酚，以酸性催化剂的存在顺序进行去丁基化反应；其中，单烷基苯酚、双烷基苯酚和三烷基苯酚中烷基基团的碳原子数各自独立在1至4的范围内，而用于后一步反应槽的添加溶剂的平均烷基基团数小于用于前一步反应槽的添加溶剂的平均烷基基团数。

  公开号：

  US20040147790A1
• 作为产物：
  描述：

  2,6-二叔丁基苯酚 、 2-叔丁基苯酚 、 2,4,6-三叔丁基苯酚 在 氢氧化钾 氧气 作用下， 180.0~190.0 ℃ 、300.01 kPa 条件下， 反应 16.0h， 生成 3,3',5,5'-tetra-tert-butyl-4,4'-biphenol
  参考文献：
  名称：

  Method for continuously producing 3,3',5,5'-tetra-t-butyl-4,4'-biphenol

  摘要：

  一种通过氧化/二聚2,6-二叔丁基苯酚连续生产3,3'，5,5'-四叔丁基-4,4'-联苯酚的方法，包括以下步骤：将2,6-二叔丁基苯酚供给反应设备的第一反应部分，该反应设备至少连接有第一反应部分和第二反应部分；向至少该第一反应部分提供碱性催化剂；并分别向每个反应部分分配含氧气体；从最后一个反应部分获得含有3,3'，5,5'-四叔丁基-4,4'-联苯酚的反应混合物。

  公开号：

  EP1415966A1

文献信息

• Method for preparing p,p'-biphenol
  申请人：Honshu Chemical Industry Co., Ltd.

  公开号：US05099076A1

  公开（公告）日：1992-03-24

  The present invention is directed to a method for the preparation of p,p'-biphenol by simplified processes achieved by batch or continuous operations which comprises using phenol and isobutylene as starting materials, allowing phenol to react with isobutylene in the presence of aluminum phenoxide, oxidizing the resulting reaction liquid in the presence of an alkaline catalyst, and debutylating the reaction liquid in the presence of a debutylation catalyst.

  本发明涉及一种制备p，p'-联苯酚的方法，通过批处理或连续操作实现简化流程，包括使用苯酚和异丁烯作为起始材料，在铝酚盐的存在下使苯酚与异丁烯反应，然后在碱性催化剂的存在下氧化所得的反应液，并在去丁基化催化剂的存在下进行脱丁基化反应。
• Process for preparing p,p'-biphenol of high purity
  申请人：UNION CARBIDE CORPORATION

  公开号：EP0013436A1

  公开（公告）日：1980-07-23

  Aprocess for producing p,p'-biphenol which comprises heating a 4,4'-bis(substituted phenol) at elevated temperatures below the decomposition temperature of p,p'-biphenol in the absence of a catalyst under an inert non-reactive atmosphere for the length of time sufficient to obtain a reaction product containing a substantial amount of p,p'-biphenol while removing the olefin by-product formed and then recovering the p,p'-biphenol product. The 4,4'-bis (substituted phenol) is made by oxidative coupling of a phenol having the formula wherein R, and R2 may be the same or different and is a member selected from the group consisting of alkyl radicals containing from 2 to 10 carbon atoms, aralkyl radicals containing from 8 to 10 carbon atoms and having a β alkyl carbon - hydrogen group, and cyclic alkyl radicals having a /3 alkyl carbon - hydrogen group with oxygen or an oxygen containing gas in the presence of a catalytic quantity of a catalyst selected from the group consisting of alkali metal hydroxides, alkali metal salts of a weak acid, alkaline earth metal hydroxides, alkaline earth metal salts of a weak acid, amine bases, and mixtures of the same at an elevated temperature forthe time necessary to react up to a stoichiometric amount of oxygen with said phenol to form a reaction product containing a substantial amount of 4,4'-bis(2,6,-disubstitutedphenol).

  一种生产p,p'-联苯酚的工艺，包括在没有催化剂的情况下，在惰性非反应气氛下，在低于p,p'-联苯酚分解温度的高温下加热4,4'-双（取代苯酚），加热时间足以获得含有大量p,p'-联苯酚的反应产物，同时除去形成的烯烃副产物，然后回收p,p'-联苯酚产物。 4,4'-双（取代苯酚）是通过氧化偶联具有以下式子的苯酚制得的 其中 R 和 R2 可以相同或不同，并且是从以下组成的组中选出的成员：含 2 至 10 个碳原子的烷基、含 8 至 10 个碳原子并具有一个 β 烷基碳氢基的芳烷基和具有一个 /3 烷基碳氢基的环状烷基、弱酸的碱金属盐、碱土金属氢氧化物、弱酸的碱土金属盐、胺碱和它们的混合物，在升高的温度下，在必要的时间内，与所述苯酚反应，生成含有大量 4,4'-双(2,6,-二取代苯酚)的反应产物。
• HIGHLY HEAT-RESISTANT, HIGH-PURITY POLYARYLATE AND FILM PRODUCED FROM THE SAME
  申请人：UNITIKA LTD.

  公开号：EP0943640A1

  公开（公告）日：1999-09-22

  The present invention provides a polyarylate film comprising 9,9-bis(alkyl-4-hydroxyphenyl)fluorene residue and bisphenol residue with a molar ratio of the former of in the range of 0.05 to 1 in which the carboxylic acid component is composed of terephthalic acid residue and isophthalic acid residue, wherein the polyarylate film having good abrasion resistance and heat resistance, being highly transparent and having less incident-angle dependent birefringence can be obtained by solvent casting of a polyarylate solution with an inherent viscosity in the range of 0.25 to 2.50. The film has high abrasion resistance, heat resistance and purity along with being excellent in such optical characteristics as high transparency and low birefringence, which is applicable as molding materials for use in electric, electronic and optical fields and in automobile industry; as insulating materials in electric appliances, power generators, capacitors and interlayer insulators; and as surface coating films as dielectric films for use in transformers, wire coating and capacitors, and substrates for liquid crystal display panel.

  本发明提供了一种聚芳酸酯薄膜，该薄膜由9,9-双(烷基-4-羟基苯基)芴残基和双酚残基组成，前者的摩尔比在0.其中羧酸组分由对苯二甲酸残留物和间苯二甲酸残留物组成，通过溶剂浇铸固有粘度在 0.25 至 2.50 范围内的聚芳酸酯溶液，可获得耐磨性和耐热性良好、透明度高且随事件角而产生的双折射较小的聚芳酸酯薄膜。这种薄膜具有很高的耐磨性、耐热性和纯度，同时还具有高透明度和低双折射等优异的光学特性，可用作电气、电子和光学领域以及汽车工业中的成型材料；用作电器、发电机、电容器和层间绝缘体中的绝缘材料；以及用作变压器、电线涂层和电容器中的介质薄膜和液晶显示面板基板的表面涂层薄膜。
• Method of producing 4,4-biphenol
  申请人：Honshu Chemical Industry Co., Ltd.

  公开号：EP1440960A1

  公开（公告）日：2004-07-28

  A method for producing 4,4'-biphenol, comprising the steps of: providing serially arranged reaction baths for two or more steps; and carrying out a debutylation reaction of 3,3',5,5'-tetra-t-butyl-4,4'-biphenol sequentially in the presence of an acid catalyst in a reaction solvent by supplying at least one kind of phenol selected from the group consisting of phenol, monoalkylphenols, dialkylphenols, and trialkylphenols, in a proportion of at least 0.5 mole part relative to one mole part of 3,3',5,5'-tetra-t-butyl-4,4'-biphenol, to each reaction bath as a solvent for addition,    wherein the number of carbon atoms of the alkyl groups in the alkylphenols selected from the group consisting of the monoalkylphenols, dialkylphenols, and trialkylphenols, is each independently in the range of 1 to 4, and    wherein a solvent for addition to a reaction bath for the latter step has a smaller average number of alkyl groups than a solvent for addition to a reaction bath for the former step.

  一种生产 4,4'-联苯酚的方法，包括以下步骤 为两个或多个步骤提供连续排列的反应槽；以及 在酸催化剂存在下，在反应溶剂中依次对 3,3',5,5'-四丁基-4,4'-联苯酚进行脱丁基化反应，提供至少一种选自苯酚、单烷基酚、二烷基酚和三烷基酚组成的组中的苯酚，其比例至少为 0.5 摩尔份的 3,3',5,5'-四叔丁基-4,4'-联苯酚作为溶剂加入到每个反应槽中、 其中，选自单烷基酚、二烷基酚和三烷基酚组成的组中的烷基酚中烷基的碳原子数各自独立地在 1 至 4 的范围内，以及 其中，用于加入后一步骤反应浴的溶剂的烷基平均数目少于用于加入前一步骤反应浴的溶剂。
• RESIN, RESIN COMPOSITIONS, PROCESS FOR PRODUCTION THEREOF, AND MOLDINGS MADE BY USING THE SAME
  申请人：TORAY INDUSTRIES, INC.

  公开号：EP1518884A1

  公开（公告）日：2005-03-30

  The present invention relates to a thermoplastic resin having excellent heat resistance, optical properties, and mechanical properties, a method for manufacturing the same, and a molded material including the same. The resin contains a polymer, and the polymer includes a divalent phosphate residue having a spiro ring, represented by the following General formula (1), in a molecule and has a number average molecular weight of at least 2,000:    where, in General formula (1), R1 is independently selected from the group consisting of a hydrogen atom, a halogen atom, an aliphatic hydrocarbon group having the carbon number of 1 to 20, an aromatic hydrocarbon group having the carbon number of 1 to 20, and a nitro group; p and q are integers satisfying p + q = 0 to 16; X independently represents oxygen, sulfur, selenium, or an unshared electron pair; Y is independently selected from oxygen, sulfur, and a methylene group; and n and m are integers satisfying n + m = 0 to 4.

  本发明涉及一种具有优异耐热性、光学性能和机械性能的热塑性树脂，一种制造该树脂的方法，以及一种包括该树脂的模塑材料。 该树脂含有一种聚合物，该聚合物在分子中包括具有螺环的二价磷酸残基，由以下通式（1）表示，其平均分子量至少为 2 000： 其中，在通式（1）中，R1 独立地选自由氢原子、卤素原子、碳原子数为 1 至 20 的脂肪烃基、碳原子数为 1 至 20 的芳香烃基和硝基组成的组；p 和 q 是满足 p + q = 0 至 16 的整数；X 独立地代表氧、硫、硒或未共享电子对；Y 独立地选自氧、硫和亚甲基；以及 n 和 m 是满足 n + m = 0 至 4 的整数。