dimethyl[(E)-2-phenylethenyl]propylsilane | 18192-47-7

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: dimethyl[(E)-2-phenylethenyl]propylsilane
• 英文别名: dimethyl-propyl-trans-styryl-silane；Dimethyl-propyl-trans-styryl-silan；dimethyl-[(E)-2-phenylethenyl]-propylsilane
• CAS: 18192-47-7
• 化学式: C₁₃H₂₀Si
• 分子量: 204.387
• InChiKey: BRACRAYYZKMFLY-ZRDIBKRKSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.36
• 重原子数：
  14
• 可旋转键数：
  4
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.38
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为产物：
  描述：

  1,1-二甲基硅杂环丁烷 二甲基三亚甲基硅烷 、 苯乙烯 在 bis(1,5-cyclooctadiene)nickel (0) 、 三环己基膦 作用下， 以 甲苯 为溶剂， 反应 12.0h， 以98%的产率得到dimethyl[(E)-2-phenylethenyl]propylsilane
  参考文献：
  名称：

  Nickel-Catalyzed Regio- and Stereoselective Silylation of Terminal Alkenes with Silacyclobutanes:  Facile Access to Vinylsilanes from Alkenes

  摘要：

  Treatment of terminal alkenes with silacyclobutanes under nickel catalysis resulted in silylation of the alkenes and yielded the corresponding vinylsilanes in a highly regio- and stereoselective fashion. The reaction provides a facile access to vinylsilanes starting from trivial terminal alkenes as well as styrenes, 1,3-dienes, and acrylate esters.

  DOI：

  10.1021/ja070938t

文献信息

• Petrow et al., Zhurnal Obshchei Khimii, 1957, vol. 27, p. 1535,1537,1538; engl.Ausg.S.1609,1611,1612
  作者：Petrow et al.

  DOI：——

  日期：——
• Nickel-Catalyzed Regio- and Stereoselective Silylation of Terminal Alkenes with Silacyclobutanes:  Facile Access to Vinylsilanes from Alkenes
  作者：Koji Hirano、Hideki Yorimitsu、Koichiro Oshima

  DOI：10.1021/ja070938t

  日期：2007.5.1

  Treatment of terminal alkenes with silacyclobutanes under nickel catalysis resulted in silylation of the alkenes and yielded the corresponding vinylsilanes in a highly regio- and stereoselective fashion. The reaction provides a facile access to vinylsilanes starting from trivial terminal alkenes as well as styrenes, 1,3-dienes, and acrylate esters.