5,11,17,23-tetra(tert-butyl)-25,26,27,28-tetra(diphenylphosphinooxy)calix[4]arene | 123332-69-4

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 5,11,17,23-tetra(tert-butyl)-25,26,27,28-tetra(diphenylphosphinooxy)calix[4]arene
• 英文别名: Diphenyl-[[5,11,17,23-tetratert-butyl-26,27,28-tris(diphenylphosphanyloxy)-25-pentacyclo[19.3.1.13,7.19,13.115,19]octacosa-1(24),3,5,7(28),9,11,13(27),15(26),16,18,21(25),22-dodecaenyl]oxy]phosphane
• CAS: 123332-69-4
• 化学式: C₉₂H₉₂O₄P₄
• 分子量: 1385.64
• InChiKey: VGPWSJQMGPTNOC-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  26.3
• 重原子数：
  100
• 可旋转键数：
  20
• 环数：
  13.0
• sp3杂化的碳原子比例：
  0.22
• 拓扑面积：
  36.9
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  tricarbonylbis(η2-cis-cyclooctene)iron 、 5,11,17,23-tetra(tert-butyl)-25,26,27,28-tetra(diphenylphosphinooxy)calix[4]arene 在 benzene 作用下， 以 正己烷 为溶剂， 以85%的产率得到
  参考文献：
  名称：

  A novel class of polyphosphorus donor ligands based on a calix[n]arene skeleton: structural characterization of a dinuclear iron(O) complex

  摘要：

  P-tert-Butylcalix[4]arene has been converted into the corresponding tetra(diphenylphosphinite) derivative which has a cone conformation; reaction with [Fe(CO)3(eta2-C8H14)2] led to binding of two Fe(CO)3 units, as confirmed by X-ray analysis, at the surface provided by the four trivalent phosphorus donors.

  DOI：

  10.1039/dt9930000813
• 作为产物：
  描述：

  5,11,17,23-tetra-t-butyl-25,26,27,28-tetrahydroxycalix-4-arene 、 二苯基氯化膦 在 正丁基锂 作用下， 生成 5,11,17,23-tetra(tert-butyl)-25,26,27,28-tetra(diphenylphosphinooxy)calix[4]arene
  参考文献：
  名称：

  Floriani, Carlo; Jacoby, Denis; Chiesi-Villa, Angiola, Angewandte Chemie, 1989, vol. 101, # 10, p. 1430 - 1431

  摘要：

  DOI：

文献信息

• Floriani, Carlo; Jacoby, Denis; Chiesi-Villa, Angiola, Angewandte Chemie, 1989, vol. 101, # 10, p. 1430 - 1431
  作者：Floriani, Carlo、Jacoby, Denis、Chiesi-Villa, Angiola、Guastini, Carlo

  DOI：——

  日期：——
• Hydroformylation of olefins catalyzed by rhodium complexes with phosphinitecalix[4]arenes
  作者：E. A. Karakhanov、Yu. S. Kardasheva、E. A. Runova、M. V. Terenina、A. Yu. Shadrova

  DOI：10.1134/s0965544107050052

  日期：2007.9

  Hydroformylation of alkenes with various carbon chain lengths and arylalkenes in the presence of the catalytic system consisting of Rh(acac)(CO)(2) and phosphinitecalix[4]arenes was studied. The influence of the P/Rh and substrate/catalyst ratios, temperature, and pressure on the process and the product composition was examined.
• A novel class of polyphosphorus donor ligands based on a calix[n]arene skeleton: structural characterization of a dinuclear iron(O) complex
  作者：Denis Jacoby、Carlo Floriani、Angiola Chiesi-Villa、Corrado Rizzoli

  DOI：10.1039/dt9930000813

  日期：——

  P-tert-Butylcalix[4]arene has been converted into the corresponding tetra(diphenylphosphinite) derivative which has a cone conformation; reaction with [Fe(CO)3(eta2-C8H14)2] led to binding of two Fe(CO)3 units, as confirmed by X-ray analysis, at the surface provided by the four trivalent phosphorus donors.