Bis-<2-jod-phenylacetyl>-peroxid | 101290-83-9

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: Bis-<2-jod-phenylacetyl>-peroxid
• 英文别名: Bis-(2-jod-phenylacetyl)-peroxid；Bis(o-iodophenylacetyl) peroxide；[2-(2-iodophenyl)acetyl] 2-(2-iodophenyl)ethaneperoxoate
• CAS: 101290-83-9
• 化学式: C₁₆H₁₂I₂O₄
• 分子量: 522.078
• InChiKey: GOODMWOACNAJPW-UHFFFAOYSA-N

物化性质

• 沸点：
  525.6±60.0 °C(Predicted)
• 密度：
  1.954±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  4.7
• 重原子数：
  22
• 可旋转键数：
  7
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.12
• 拓扑面积：
  52.6
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  Bis-<2-jod-phenylacetyl>-peroxid 以 丙酮 为溶剂， 生成 2-碘苄醇
  参考文献：
  名称：

  The Decomposition of Bis(o-iodophenylacetyl) Peroxide

  摘要：

  DOI：

  10.1021/jo01073a030
• 作为产物：
  描述：

  2-(2-碘苯基)乙酸甲酯 在 sodium hydroxide 、 氯化亚砜 、 双氧水 作用下， 生成 Bis-<2-jod-phenylacetyl>-peroxid
  参考文献：
  名称：

  The Decomposition of Bis(o-iodophenylacetyl) Peroxide

  摘要：

  DOI：

  10.1021/jo01073a030

文献信息

• Construction of 3-Oxazolin-5-one via Visible Light-Induced Nondecarboxylative Coupling and Sequential Reactions
  作者：Shanshan Ma、Haoying Cao、Rongwan Gao、Yanhong Feng、Yawen Guo、Wei Guan、Xinfang Duan、Peng Jiao

  DOI：10.1021/acs.orglett.3c00469

  日期：2023.3.31

  imines or pyrrole compounds. Harnessing the power of photocatalysis, we accomplished a straightforward synthesis of 3-oxazolin-5-ones from redox-active esters and secondary nitro compounds. Visible light-induced nondecarboxylative coupling of a redox-active ester, nitro aldol condensation, and subsequent visible light-induced N-oxide deoxygenation were accomplished within 2 h. The reaction mechanism was

  3-Oxazolin-5-ones 是腈叶立德的前体，代表有价值的 1,3-偶极子，可用于构建环状亚胺或吡咯化合物。利用光催化的力量，我们从氧化还原活性酯和仲硝基化合物中直接合成了 3-恶唑啉-5-酮。可见光诱导的氧化还原活性酯的非脱羧偶联、硝基羟醛缩合和随后的可见光诱导的N-氧化物脱氧在 2 小时内完成。反应机理得到了实验数据和DFT计算的支持。
• PARTICLES COMPRISING AMPHIPHILIC COPOLYMERS, HAVING A CROSS-LINKED SHELL DOMAIN AND AN INTERIOR CORE DOMAIN, USEFUL FOR PHARMACEUTICAL AND OTHER APPLICATIONS
  申请人：G.D. Searle & Co.

  公开号：EP0910351A1

  公开（公告）日：1999-04-28
• METHODS FOR ELECTROCHEMICAL DETECTION/QUANTIFICATION OF A NUCLEIC ACID
  申请人：Gao Zhiqiang

  公开号：US20100133117A1

  公开（公告）日：2010-06-03

  The invention provides methods and kits for the electrochemical detection and/or quantification of a target nucleic acid molecule by means of a detection electrode. In one method there is immobilized on the detection electrode a peptide nucleic acid (PNA) capture molecule, which has a nucleotide sequence that is at least partially complementary to at least a portion of the target nucleic acid molecule. The electrode is contacted with a solution expected to include the target nucleic acid molecule and the target nucleic acid molecule allowed to hybridize to the PNA, thereby allowing the formation of a complex between the PNA capture molecule and the target nucleic acid molecule. A polymerisable positively chargeable precursor is added, which associates to the complex formed between the PNA capture molecule and the target nucleic acid molecule. A suitable reactant molecule is added, initiating the polymerisation of the polymerisable positively chargeable precursor and the formation of an electroconductive polymer. An electrochemical measurement at the detection electrode is performed. In another method a nucleic acid capture molecule is immobilized on the electrode. In this method a polymerisable positively chargeable precursor, a suitable substrate molecule, and an enzyme attached to a detection probe nucleic acid molecule are used. The detection probe nucleic acid molecule is at least partially complementary to at least a portion of the target nucleic acid molecule. The detection probe hybridizes to a portion of the target nucleic acid that is different from the portion to which the capture nucleic acid molecule hybridises.
• US6383500B1
  申请人：——

  公开号：US6383500B1

  公开（公告）日：2002-05-07
• US6491903B1
  申请人：——

  公开号：US6491903B1

  公开（公告）日：2002-12-10