1,4-dithiabutanediyl-2,2'-bis(phenol) | 107777-29-7

• 分子结构分类: 有机化合物 - 有机硫化合物 - 硫醚类
• 英文名称: 1,4-dithiabutanediyl-2,2'-bis(phenol)
• 英文别名: di(2-hydroxyphenyl)ethanebisulphide；2,2'-ethanediyldimercapto-di-phenol；2,2'-Aethandiyldimercapto-di-phenol；2-[2-(2-Hydroxyphenyl)sulfanylethylsulfanyl]phenol
• CAS: 107777-29-7
• 化学式: C₁₄H₁₄O₂S₂
• 分子量: 278.396
• InChiKey: DBXBUQCXHDEBQE-UHFFFAOYSA-N

物化性质

• 熔点：
  108 °C
• 沸点：
  427.1±40.0 °C(Predicted)
• 密度：
  1.35±0.1 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  3.9
• 重原子数：
  18
• 可旋转键数：
  5
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.14
• 拓扑面积：
  91.1
• 氢给体数：
  2
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  1,4-dithiabutanediyl-2,2'-bis(phenol) 生成 1,2-bis-(2-acetoxy-phenylsulfanyl)-ethane
  参考文献：
  名称：

  309. Benz-1：3-氧杂硫醇，benz-1：4-氧杂噻吩，和αω-双芳基硫代烷烃

  摘要：

  DOI：

  10.1039/jr9530001514
• 作为产物：
  描述：

  1,3-benzoxathiole 在 palladium on activated charcoal 氢气 作用下， 以 乙醇 为溶剂， 生成 1,4-dithiabutanediyl-2,2'-bis(phenol)
  参考文献：
  名称：

  金属化反应：III。正丁基锂对1,3-苯并二恶唑和1,3-苯并草硫醇衍生物的作用

  摘要：

  研究了正丁基锂与1,3-苯并二恶唑，1,3-苯并恶唑及其2,2-二甲基衍生物的反应。除1，3-苯并恶硫醇外，在金属化和醚键裂解之间存在竞争。金属化发生在氧的邻位，而裂解产生取代，消除和还原的产物。

  DOI：

  10.1016/s0022-328x(00)82112-9

文献信息

• MODIFIER FOR AROMATIC POLYESTER AND AROMATIC POLYESTER RESIN COMPOSITION COMPRISING THE SAME
  申请人：TABATA Masayoshi

  公开号：US20110224343A1

  公开（公告）日：2011-09-15

  The present invention provides a modifier for aromatic polyesters which enhances the melt fluidity of aromatic polyesters without a significant decrease in the heat resistance of the aromatic polyesters, and an aromatic polyester resin composition including the modifier for aromatic polyesters. The present invention relates to a modifier for aromatic polyesters comprising polyhydric phenol residues and residues of aromatic polycarboxylic acid, acid halide or acid anhydride thereof, and the modifier comprises a material having a structure composed of a first residue selected from the group consisting of divalent residues represented by Formula (I): —Ar—W 1 x —Ar— and by Formula (II): —Ar—, the first residues being bonded to two identical or different second residues selected from the group consisting of monovalent residues represented by Formula (III): and monovalent residues represented by Formula (IV): —O—C(O)—R 7 —.

  本发明提供了一种用于芳香族聚酯的改性剂，可以增强芳香族聚酯的熔融流动性，而不明显降低芳香族聚酯的耐热性，以及包括该改性剂的芳香族聚酯树脂组合物。本发明涉及一种用于芳香族聚酯的改性剂，包括多羟基酚残基和芳香族多羧酸、酸卤或其酸酐残基，该改性剂包括具有以下结构的材料：第一残基，选择自由式(I)所代表的二价残基：—Ar—W1x—Ar—和自由式(II)所代表的：—Ar—，第一残基与选择自由式(III)所代表的单价残基：和自由式(IV)所代表的单价残基：—O—C(O)—R7—的两个相同或不同的第二残基结合。
• Bis(phenolato)molybdenum complexes as catalyst precursors for the deoxydehydration of biomass-derived polyols
  作者：Klaus Beckerle、Andreas Sauer、Thomas P. Spaniol、Jun Okuda

  DOI：10.1016/j.poly.2016.03.053

  日期：2016.9

  and furan derivatives in one step by combined reduction and dehydration (deoxydehydration, DODH). A series of octahedral complexes of hexavalent molybdenum containing an (OSSO)-type bis(phenolate) ligand were prepared and structurally characterized. These complexes were screened as catalyst precursors for the deoxydehydration of anhydroerythritol using 3-octanol as reducing agent. Microwave heating

  摘要生物基多元醇可通过还原和脱水（脱氧脱水，DODH）的组合一步转化为烯烃和呋喃衍生物。制备了一系列含有（OSSO）型双（酚盐）配体的六价钼八面体配合物，并对其结构进行了表征。使用3-辛醇作为还原剂，筛选这些络合物作为用于脱水赤藓糖醇脱氧脱水的催化剂前体。微波加热可以降低反应温度。
• Structural Features of a Sulfur-Containing Group 4 Metalla[11]-crown-4 Derivative
  作者：Alexander Snell、Gerald Kehr、Birgit Wibbeling、Roland Frönlich、Gerhard Erker

  DOI：10.1515/znb-2003-0905

  日期：2003.9.1

  Treatment of the ligand system (ο-C₆H₄OH)-S-CH₂-CH₂-S-(ο-C₆H₄-OH) (2a) with TiCl₄ gave the metalla-crown ether derivative [(-S-CH₂-CH₂-S-)(ο-C₆H₄O)₂]TiCl₂ (5a). Complex 5a was characterized by an X-ray crystal structure analysis. It showed a pseudo-octahedral structure with both sulfur atoms being cis-coordinated to the metal center. The chloride ligands are also cispositioned, whereas the remaining two Ti−oxygen bonds are trans to each other to complete the distorted octahedral coordination geometry. The reaction of 2a with ZrCl₄ gave the analogous complex 5c. The related ligand system (ο-C₆H₄OH)-O-CH₂-CH₂-O-(ο-C₆H₄OH) (2b) was doubly deprotonated by treatment with butyl lithium and then reacted with TiCl₄ to yield the complex [(-O-CH₂-CH₂-O-)(ο-C₆H₄O)₂]TiCl₂ (5b).

  用TiCl4处理配体系统(ο-C6H4OH)-S-CH2-CH2-S-(ο-C6H4-OH)(2a)产生了metalla-crown ether衍生物[(-S-CH2-CH2-S-)(ο-C6H4O)2]TiCl2(5a)。通过X射线晶体结构分析表征了复合物5a。它显示出一个伪八面体结构，两个硫原子都与金属中心顺式配位。氯配体也是顺位排列的，而其余两个Ti-氧键则相互反向以完成扭曲的八面体配位几何。2a与ZrCl4的反应产生了类似的复合物5c。与此相关的配体系统(ο-C6H4OH)-O-CH2-CH2-O-(ο-C6H4OH)(2b)经过丁基锂处理后被双重去质子化，然后与TiCl4反应产生了复合物[(-O-CH2-CH2-O-)(ο-C6H4O)2]TiCl2(5b)。
• AROMATIC POLYESTER
  申请人：Muroran Institute of Technology

  公开号：EP2479203A1

  公开（公告）日：2012-07-25

  The present invention provides an aromatic polyester which is substantially free from the occurrence of coloration and retains significantly high transparency even after being thermally processed at high temperature and which has high flowability. The aromatic polyester contains a polyhydric phenol residue and a residue of any one of aromatic polycarboxylic acid, halide thereof, and anhydride thereof, and terminals of the aromatic polyester have a structure represented by the formula -C(O)-R. The aromatic polyester has an end-capping rate of 90% or higher and a weight average molecular weight (Mw) ranging from 3,000 to 1,000,000.

  本发明提供了一种芳香族聚酯，该聚酯基本上不会发生着色，即使在高温热加工后仍能保持明显的高透明度，并且具有高流动性。芳香族聚酯含有多羟基苯酚残留物和芳香族多羧酸、其卤化物和其酸酐中任意一种的残留物，芳香族聚酯的端基具有式 -C(O)-R 所代表的结构。芳香族聚酯的端盖率为 90% 或更高，重量平均分子量（Mw）为 3,000 至 1,000,000 之间。
• Pathak, A. K.; Mittal, A. K.; Shukla, P. L., Synthesis and Reactivity in Inorganic and Metal-Organic Chemistry, 1995, vol. 25, p. 163 - 182
  作者：Pathak, A. K.、Mittal, A. K.、Shukla, P. L.

  DOI：——

  日期：——