4-chloro-cyclohex-3-enecarboxylic acid | 41907-32-8

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• 英文名称: 4-chloro-cyclohex-3-enecarboxylic acid
• 英文别名: 4-Chlor-cyclohex-3-encarbonsaeure；4-Chlorocyclohex-3-ene-1-carboxylic acid
• CAS: 41907-32-8
• 化学式: C₇H₉ClO₂
• 分子量: 160.6
• InChiKey: JNNXEURCSLDENJ-UHFFFAOYSA-N

物化性质

• 熔点：
  109.5-110 °C(Solv: water (7732-18-5))
• 沸点：
  292.9±40.0 °C(Predicted)
• 密度：
  1.27±0.1 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  1.6
• 重原子数：
  10
• 可旋转键数：
  1
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.57
• 拓扑面积：
  37.3
• 氢给体数：
  1
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  4-羰基环己羧酸 在 乙醚 、 五氯化磷 作用下， 生成 4-chloro-cyclohex-3-enecarboxylic acid
  参考文献：
  名称：

  Some Diels—Alder Reactions of Chloroprene¹

  摘要：

  DOI：

  10.1021/ja01130a513

文献信息

• Aromatization process
  申请人：OCCIDENTAL CHEMICAL CORPORATION

  公开号：EP0417690A2

  公开（公告）日：1991-03-20

  Halogen substituted aromatic compounds of the formula wherein Y is selected from the group CO₂H, COF, COCl, COBr, CF₃, CN, NCO, or F, and X and X′ are independently hydrogen or a halogen selected from the group F-, Cl- and Br-, at least one of X and X′ being halogen; may be prepared by the liquid phase reaction of a brominating agent, at temperatures below about 190° Celsius, with a correspondingly substituted cyclohexene or cyclohexadiene.

  式中的卤素取代的芳香族化合物 其中 Y 选自 CO₂H、COF、COCl、COBr、CF₃、CN、NCO 或 F 组，X 和 X′ 独立地为氢或选自 F-、Cl- 和 Br- 组的卤素，X 和 X′ 中至少有一个为卤素；可通过溴化剂与相应取代的环己烯或环己二烯在低于约 190 摄氏度的温度下进行液相反应制备。
• CROSSLINKABLE AROMATIC RESINS HAVING PROTONIC ACID GROUPS AND ION CONDUCTIVE POLYMER MEMBRANES BINDERS AND FUEL CELLS MADE BY USING THE SAME
  申请人：Mitsui Chemicals, Inc.

  公开号：EP1457511A1

  公开（公告）日：2004-09-15

  The invention provides a crosslinkable aromatic resin having a protonic acid group and a crosslinkable group, suitable for electrolytic membranes and binders used in fuel cells, etc., and electrolytic polymer membranes, binders and fuel cells using the resin. The crosslinkable aromatic resin has a crosslinkable group, which is not derived from the protonic acid group and can form a polymer network without any elimination component. This resin exhibits excellent ion conductivity, heat resistance, water resistance, adhesion property and low methanol permeability. Preferably, the crosslinkable group is composed of a C1 to C10 alkyl group directly bonded to the aromatic ring and a carbonyl group, or a carbon-carbon double bond or triple bond. The aromatic resins such as aromatic polyethers, aromatic polyamides, aromatic polyimides, aromatic polyamideimides, aromatic polyazoles, etc., which contain such a crosslinkable group, are preferred as the crosslinkable aromatic resins having a protonic acid group and a crosslinkable group.

  本发明提供了一种具有质子酸基团和可交联基团的可交联芳香族树脂，适用于燃料电池等中使用的电解膜和粘结剂，以及使用该树脂的电解聚合物膜、粘结剂和燃料电池。可交联芳香族树脂具有可交联基团，该基团并非来自质子酸基团，可形成聚合物网络，且不含任何消除成分。这种树脂具有优异的离子传导性、耐热性、耐水性、粘附性和低甲醇渗透性。可交联基团最好由直接键合在芳香环上的 C1 至 C10 烷基和羰基或碳碳双键或三键组成。芳香族树脂，如芳香族聚醚、芳香族聚酰胺、芳香族聚酰亚胺、芳香族聚酰胺酰亚胺、芳香族聚唑等，含有这样的可交联基团，作为具有质子酸基团和可交联基团的可交联芳香族树脂，是优选的。
• Crosslinkable aromatic resin having protonic acid group, and ion conductive polymer membrane, binder and fuel cell using the resin
  申请人：MITSUI CHEMICALS, INC.

  公开号：US20040191602A1

  公开（公告）日：2004-09-30

  The invention provides a crosslinkable aromatic resin having a protonic acid group and a crosslinkable group, suitable for electrolytic membranes and binders used in fuel cells, etc., and electrolytic polymer membranes, binders and fuel cells using the resin. The crosslinkable aromatic resin has a crosslinkable group, which is not derived from the protonic acid group and can form a polymer network without any elimination component. This resin exhibits excellent ion conductivity, heat resistance, water resistance, adhesion property and low methanol permeability. Preferably, the crosslinkable group is composed of a C 1 to C 10 alkyl group directly bonded to the aromatic ring and/or an alkylene group having 1 to 3 carbon atoms in the main chain in which at least one carbon atom directly bonded to the aromatic ring bonds to hydrogen, and a carbonyl group, or a carbon-carbon double bond or triple bond. The aromatic resins such as aromatic polyethers, aromatic polyamides, aromatic polyimides, aromatic polyamideimides, aromatic polyazoles, etc., which contain such a crosslinkable group, are preferred as the crosslinkable aromatic resins having a protonic acid group and a crosslinkable group.

  本发明提供了一种具有质子酸基团和可交联基团的可交联芳香族树脂，适用于燃料电池等中使用的电解膜和粘结剂，以及使用该树脂的电解聚合物膜、粘结剂和燃料电池。可交联芳香族树脂具有可交联基团，该基团并非来自质子酸基团，可形成聚合物网络，且不含任何消除成分。这种树脂具有优异的离子传导性、耐热性、耐水性、粘附性和低甲醇渗透性。可交联基团最好由 C 1 至 C 10 烷基和/或主链上有 1 至 3 个碳原子的亚烷基，其中至少有一个直接与芳香环键合的碳原子与氢、羰基或碳碳双键或三键键合。芳香族树脂，如芳香族聚醚、芳香族聚酰胺、芳香族聚酰亚胺、芳香族聚酰胺酰亚胺、芳香族聚唑等，含有这样的可交联基团，作为具有质子酸基团和可交联基团的可交联芳香族树脂是首选。
• Petrow; Ssopow, Zhurnal Obshchei Khimii, 1947, vol. 17, p. 2231
  作者：Petrow、Ssopow

  DOI：——

  日期：——
• Gillois-Doucet, Annales de Chimie (Cachan, France), 1955, vol. <12> 10, p. 497,531
  作者：Gillois-Doucet

  DOI：——

  日期：——