pentamethylfluorobenzene | 319-83-5

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: pentamethylfluorobenzene
• 英文别名: Pentamethyl-fluorbenzol；1-Fluoro-2,3,4,5,6-pentamethylbenzene
• CAS: 319-83-5
• 化学式: C₁₁H₁₅F
• 分子量: 166.239
• InChiKey: YZDYPFIXYFKHAP-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.8
• 重原子数：
  12
• 可旋转键数：
  0
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.45
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  pentamethylfluorobenzene 在 硝酸 作用下， 以 氟磺酸 为溶剂， 生成 4-Fluoro-2,3,5,6,6-pentamethyl-cyclohexa-2,4-dienone
  参考文献：
  名称：

  Detsina,A.N. et al., Journal of Organic Chemistry USSR (English Translation), 1979, vol. 15, # 9, p. 1703 - 1709

  摘要：

  DOI：
• 作为产物：
  描述：

  五甲基苯 在 N-氟代双苯磺酰胺 作用下， 反应 1.67h， 以10%的产率得到pentamethylfluorobenzene
  参考文献：
  名称：

  Fluorination of aromatic compounds with N-fluorobenzenesulfonimide under solvent-free conditions

  摘要：

  Reactions of N-fluorobenzenesulfonimide with methylbenzenes, phenols, and phenol ethers were studied under solvent-free conditions. The rate constant ratio for the reactions with mesitylene and durene indicates polar mechanism of the process. Solvent-free fluorination of aromatic compounds with N-fluorobenzenesulfonimide in some cases is more selective than reactions with other N-F reagents in a solvent.

  DOI：

  10.1134/s107042800910008x

文献信息

• DEOXYNOJIRIMYCIN AND D-ARABINITOL ANALOGS AND METHODS OF USING
  申请人：Butters Terry D.

  公开号：US20070275998A1

  公开（公告）日：2007-11-29

  A compound of Formula I are provided: wherein R is: R 1 is a substituted or unsubstituted alkyl group; W 1-4 are independently selected from hydrogen, substituted or unsubstituted alkyl groups, substituted or unsubstituted haloalkyl groups, substituted or unsubstituted alkanoyl groups, substituted or unsubstituted aroyl groups, or substituted or unsubstituted haloalkanoyl groups; X 1-5 are independently selected from H, NO 2 , N 3 , and NH 2 ;Y is absent or is a substituted or unsubstituted C 1 -alkyl group, other than carbonyl; Z is selected from a bond or NH, provided that when Z is a bond, Y is absent, and provided that when Z is NH, Y is a substituted or unsubstituted C 1 -alkyl group, other than carbonyl. Also provided are D-arabinitol compounds, methods for preparing such compounds and compositions of such compounds, and methods of using such compounds.

  提供了Formula I的化合物：其中R为：R1为取代或未取代的烷基基团；W1-4独立选择自氢、取代或未取代的烷基基团、取代或未取代的卤代烷基基团、取代或未取代的烷酰基团、取代或未取代的芳酰基团或取代或未取代的卤代烷酰基团；X1-5独立选择自H、NO2、N3和NH2；Y不存在或为取代或未取代的C1-烷基基团，除了羰基；Z从键或NH中选择，前提是当Z为键时，Y不存在，并且当Z为NH时，Y为取代或未取代的C1-烷基基团，除了羰基。还提供了D-阿拉伯糖醇化合物，制备这种化合物的方法和这种化合物的组合物，以及使用这种化合物的方法。
• METATHESIS CATALYSTS AND METHODS THEREOF
  申请人：Massachusetts Institute of Technology

  公开号：US20140330018A1

  公开（公告）日：2014-11-06

  The present application provides, among other things, novel compounds and methods for metathesis reactions. In some embodiments, a provided compound has the structure of formula I. In some embodiments, the present invention provides methods for preparing a compound of formula I. In some embodiments, the present invention provides metathesis methods comprising providing a compound of formula I.

  本申请提供了一些新的化合物和用于交换反应的方法。在某些实施例中，所提供的化合物具有公式I的结构。在某些实施例中，本发明提供了制备公式I化合物的方法。在某些实施例中，本发明提供了包括提供公式I化合物的交换反应方法。
• NOVEL SULFONIC ACID GROUP-CONTAINING SEGMENTED BLOCK COPOLYMER AND USE THEREOF
  申请人：Toyo Boseki Kabushiki Kaisha

  公开号：EP2463326A1

  公开（公告）日：2012-06-13

  Disclosed is a proton exchange membrane for use in fuel cells, which not only has improved proton conductivity and resistance to swelling caused by hot water but also has greater durability when used in a fuel cell, as well as a sulfonic acid group-containing segmented block copolymer constituting the proton exchange membrane, a membrane electrode assembly using the proton exchange membrane, and a fuel cell using the membrane electrode assembly. A sulfonic acid group-containing segmented block copolymer, which is a di- or multi-block copolymer including, within a molecule, at least one kind of hydrophilic segment and at least one kind of hydrophobic segment, a 0.5 g/dL solution thereof dissolved in N-methyl-2-pyrrolidone as a solvent showing a logarithmic viscosity measured at 30°C in the range of 0.5 to 5.0 dL/g, wherein the copolymer has at least one kind of hydrophobic segment represented by Chemical Formula 1, the segment has a structure bound to a group represented by Chemical Formula 2, and the hydrophilic segment has at least one kind of structure represented by Chemical Formula 3 or Chemical Formula 3-2.

  本发明公开了一种用于燃料电池的质子交换膜，该质子交换膜不仅具有更好的质子传导性和抗热水膨胀性，而且在用于燃料电池时具有更高的耐久性；还公开了一种构成该质子交换膜的含磺酸基的嵌段共聚物、一种使用该质子交换膜的膜电极组件和一种使用该膜电极组件的燃料电池。一种含磺酸基的嵌段共聚物，它是一种二嵌段或多嵌段共聚物，在一个分子内包括至少一种亲水嵌段和至少一种疏水嵌段，将其溶解在作为溶剂的N-甲基-2-吡咯烷酮中的0.5克/分升溶液在30°C下测得的对数粘度在0.5至5.0dL/g，其中共聚物具有至少一种由化学式1表示的疏水段，该段具有与由化学式2表示的基团结合的结构，亲水段具有至少一种由化学式3或化学式3-2表示的结构。
• Detsina, A. N.; Sidorova, N. V.; Mainagashev, I. Ya., Journal of Organic Chemistry USSR (English Translation), 1983, vol. 19, p. 1688 - 1693
  作者：Detsina, A. N.、Sidorova, N. V.、Mainagashev, I. Ya.、Zelinskii, A. G.、Koptyug, V. A.

  DOI：——

  日期：——
• Stable carbocations. CLXXIV. Charge distribution differences in benzenium and nitrobenzenium ions based on carbon-13 nuclear magnetic resonance studies and their relevance to the isomer distribution in electrophilic aromatic substitutions
  作者：George A. Olah、Henry C. Lin、David A. Forsyth

  DOI：10.1021/ja00829a017

  日期：1974.10