cyclopentyl n-butyl sulfide | 7133-16-6

• 分子结构分类: 有机化合物 - 有机硫化合物 - 硫醚类
• 英文名称: cyclopentyl n-butyl sulfide
• 英文别名: n-Butylthiocyclopentan；n-Butyl-cyclopentylsulfid；butyl-cyclopentyl sulfide；Butyl-cyclopentyl-sulfid；(Butylthio)cyclopentane；butylsulfanylcyclopentane
• CAS: 7133-16-6
• 化学式: C₉H₁₈S
• 分子量: 158.308
• InChiKey: DALIGXBOEDZLRG-UHFFFAOYSA-N

物化性质

• 沸点：
  95 °C(Press: 12 Torr)
• 密度：
  0.91±0.1 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  3.4
• 重原子数：
  10
• 可旋转键数：
  4
• 环数：
  1.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  25.3
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  cyclopentyl n-butyl sulfide 在 双氧水 作用下， 以 丙酮 为溶剂， 生成 (丁基磺酰基)环戊烷
  参考文献：
  名称：

  Intramolecular alkylation as an approach to cyclic sulfones and sulfides

  摘要：

  DOI：

  10.1021/jo01265a009
• 作为产物：
  描述：

  1,1-Bis(n-butylthio)-cyclopentan 以 环己烷 为溶剂， 生成 cyclopentyl n-butyl sulfide
  参考文献：
  名称：

  Free radical rearrangement of cyclic ketone mercaptols

  摘要：

  DOI：

  10.1007/bf01100019

文献信息

• Biotransformation of organic sulfides—VII. A predictive model for sulfoxidation by Helminthosporium species NRRL 4671
  作者：Herbert L. Holland、Frances M. Brown、Gingipalli Lakshmaiah、Brett G. Larsen、Manish Patel

  DOI：10.1016/s0957-4166(97)00006-2

  日期：1997.3

  range of prochiral sulfides to the corresponding chiral sulfoxides, the majority of which have (S) configuration at sulfur. The formation of a series of chiral cyclopentyl alkyl, cyclohexyl alkyl, benzyl alkyl, and methyl alkyl sulfoxides by biotransformation of the corresponding sulfides using Helminthosporium species is described. The analysis of over 90 such biotransformations has resulted in the

  蠕虫孢子菌种NRRL 4671将多种前手性硫化物转化为相应的手性亚砜，其中大多数在硫原子上具有（S）构型。描述了通过使用蠕虫属物种对相应的硫化物进行生物转化而形成一系列的手性环戊基烷基，环己基烷基，苄基烷基和甲基烷基亚砜。对超过90种此类生物转化的分析导致开发了基于限制性空间描述符的模型，该模型已用于合理化这些反应，并被提议作为蠕虫孢子催化的硫氧化作用的预测因子。
• Procatalysts, catalyst systems, and use in olefin polymerization
  申请人：——

  公开号：US20010025005A1

  公开（公告）日：2001-09-27

  There are described solid procatalysts, catalyst systems incorporating the solid procatalysts, and the use of the catalyst systems in olefin polymerization and interpolymerization.

  本文介绍了固体原催化剂、含有固体原催化剂的催化剂体系以及催化剂体系在烯烃聚合和互聚中的应用。
• Procatalysts, catalyst systems, and use in OLEFIN polymerization
  申请人：——

  公开号：US20010029286A1

  公开（公告）日：2001-10-11

  There are described solid procatalysts, catalyst systems incorporating the solid procatalysts, and the use of the catalyst systems in olefin polymerization and interpolymerization.

  本文介绍了固体原催化剂、含有固体原催化剂的催化剂体系以及催化剂体系在烯烃聚合和互聚中的应用。
• [EN] COLLECTOR COMPOSITIONS FOR THE FROTH FLOTATION OF MINERAL VALUES
  申请人：THE DOW CHEMICAL COMPANY

  公开号：WO1987003222A1

  公开（公告）日：1987-06-04

  (EN) A collector composition, useful for the recovery of metal-containing sulfide minerals, sulfidized metal-containing oxide minerals, metals-containing oxide minerals and metals occuring in the metallic state from ores in a froth flotation process, comprises two collectors. One collector is an organic compound containing at least 4 carbon atoms and one or more monosulfide units, wherein the carbon atoms to which the sulfur atoms are bound are aliphatic or cycloaliphatic carbons. The other collector is preferably an omega-(hydrocarbylthio)alkylamine, S-(omega-aminoalkyl)-hydrocarbyl thioate, N-(hydrocarbyl)-alpha, omega-alkane-diamine, (omega-aminoalkyl)hydrocarbon amide, omega-(hydrocarbyloxy)alkylamine, omega-aminoalkyl hydrocarbonoate, omega-(hydrocarbylthio)-alkylamide or mixture thereof.(FR) Une composition collectrice qui est utile pour extraire des minéraux de sulfure contenant des métaux, des minéraux d'oxyde contenant des métaux sulfurés, des minéraux d'oxyde contenant des métaux, et des métaux présents à l'état métallique dans des minerais lors d'un processus de flottation par écumage, comprend deux collecteurs. L'un de ces collecteurs est un composé organique contenant au moins quatre atomes de carbone et un ou plusieurs unités de monosulfure, dans lequel les atomes de carbone auquel sont liés les atomes de soufre sont des carbones aliphatiques ou cycloaliphatiques. L'autre collecteur est de préférence une oméga-(hydrocarbylthio)alkylamine, S-(oméga-aminoalkyle)-hydrocarbyle thioate, N-(hydrocarbyle)-alpha,oméga-alkane-diamine, un amide d'hydrocarbure (oméga-aminoalkyle), une oméga-(hydrocarbyloxy)alkylamine, un oméga-aminoalkyl hydrocarbonoate, un oméga-(hydrocarbylthio)-alkylamide ou un mélange de ceux-ci.

  一种用于从矿石中通过泡沫浮选过程回收含金属硫化矿物、硫化金属氧化物矿物、含金属氧化物矿物以及以金属态存在的金属的收集剂组合物，包含两种收集剂。其中一种收集剂是一种含有至少4个碳原子和一个或多个单硫代单元的有机化合物，且与硫原子相连的碳原子为脂肪族或环脂肪族碳原子。另一种收集剂优选为ω-(烃基硫基)烷基胺、S-(ω-氨基烷基)-烃基硫酯、N-(烃基)-α,ω-亚烷基二胺、(ω-氨基烷基)烃基酰胺、ω-(烃基氧基)烷基胺、ω-氨基烷基烃酸盐或它们的混合物。
• [DE] SUBSTITUIERTE 2-ARYLPYRIDINE ALS HERBIZIDE<br/>[EN] SUBSTITUTED 2-ARYLPYRIDINE AS HERBICIDE<br/>[FR] ARYLPYRIDINE SUBSTITUEE EN 2 UTILISEE COMME HERBICIDE
  申请人：BASF AKTIENGESELLSCHAFT

  公开号：WO1998007720A1

  公开（公告）日：1998-02-26

  (DE) Substituierte 2-Arylpyridine (I) und deren Salze, wobei R1 = SH, SO2OH, SO2C1, SO2NH2, C1-C6-Alkylthio, C1-C6-Alkylsulfinyl, C1-C6-Alkylsulfonyl, C1-C6-Alkylaminosulfonyl, Di(C1-C6-alkyl)aminosulfonyl; R2, R3 = H, Halogen; R4 = H, C1-C6-Alkyl, C1-C6-Halogenalkyl, Cyano-C1-C6-alkyl, C1-C6-Alkoxy, C1-C6-Alkoxy-C1-C6-alkyl, C1-C4-Halogenalkoxy-C1-C4-alkyl, C1-C6-Alkylthio-C1-C6-alkyl, C1-C6-Alkylsulfinyl-C1-C6-alkyl, C1-C6-Alkylsulfonyl-C1-C6-alkyl, C1-C4-Alkoxy-C1-C4-alkoxy-C1-C4-alkyl, C1-C6-Alkoxycarbonyl-C1-C6-alkyl, C1-C3-Alkoxy-C1-C3-alkoxycarbonyl-C1-C6-alkyl, C2-C4-Alkenyloxy-C1-C4-alkyl, C3-C4-Alkinyloxy-C1-C4-alkyl, C3-C7-Cycloalkyl, C3-C7-Cycloalkyl-C1-C6-alkyl, C3-C7-Cycloalkyloxy-C1-C6-alkyl, C3-C7-Cycloalkylthio-C1-C6-alkyl, C3-C8-Alkenyl, C3-C8-Alkinyl, C3-C8-Halogenalkenyl, C3-C8-Halogenalkinyl, C1-C6-Alkoxy-C3-C8-alkenyl, C1-C6-alkoxy-C3-C8-alkinyl, C1-C6-Alkylcarbonyl, C1-C6-Alkylsulfonyl, C3-C6-Alkenyloxy, C3-C6-Alkinyloxy oder geg. subst. Benzyl; X = -O-, -S-, -NH-, -N(CH3)-, -CH2-; Y = chemische Bindung, -CO-, C(R5,R6); R5,R6 = H, NO2, CN, OCH3, SCH3, Halogen, C1-C4-Alkyl, C1-C4-Halogenalkyl, C1-C4-Alkoxycarbonyl, C2-C6-Alkenyl, C3-C6-Alkinyl, C1-C4-Alkoxycarbonyl-C1-C4-alkyl. Verwendung: als Herbizide; zur Desikkation/Defoliation von Pflanzen.(EN) Substituted 2-arylpyridine of formula (I) and salts thereof. In said formula (I), R1 = SH, SO2OH, SO2C1, SO2NH2, C1-C6-Alkylthio, C1-C6-Alkyl sulfinyl, C1-C6-alkylsulfonyl, C1-C6-alkylamino-sulfonyl, Di(C1-C6-alkyl)aminosulfonyl; R2, R3 = H, halogen; R4 = H, C1-C6-alkyl, C1-C6-halogenalkyl, cyano-C1-C6-alkyl, C1-C6-alkoxy, C1-C6-alkoxy-C1-C6-alkyl, C1-C4-halogen-alkoxy-C1-C4-alkyl, C1-C6-alkylthio-C1-C6-alkyl, C1-C6 alkyl sulfinyl-C1-C6-alkyl, C1-C6-alkylsulfonyl-C1-C6-alkyl, C1-C4-alkoxy-C1-C4-alkoxy-C1-C4-alkyl, C1-C6-alkoxycarbonyl-C1-C6-alkyl, C1-C3-alkoxy-C1-C3-alkoxycarbonyl-C1-C6-alkyl, C2-C4-alkenyloxy-C1-C4-alkyl, C3-C4-alkinyloxy-C1-C4-alkyl, C3-C7-cycloalkyl, C3-C7-cycloalkyl-C1-C6-alkyl, C3-C7-cycloalkyloxy-C1-C6-alkyl, C3-C7-cycloalkylthio-C1-C6-alkyl, C3-C8-alkenyl, C3-C8-alkinyl, C3-C8-halogenalkenyl, C3-C8-halogenalkinyl, C1-C6-alkoxy-C3-C8-alkenyl, C1-C6-alkoxy-C3-C8-alkinyl, C1-C6-alkylcarbonyl, C1-C6-alkylsulfonyl, C3-C6-alkenyloxy, C3-C6-alkinyloxy or eventually substituted benzyl; X = -O-, -S-, -NH-, -N(CH3)-, -CH2-; Y = chemical bond, -CO-, C(R5,R6); R5,R6 = H, NO2, CN, OCH3, SCH3, halogen, C1-C4-alkyl, C1-C4-halogenalkyl, C1-C4-alkoxycarbonyl, C2-C6-alkenyl, C3-C6-alkinyl, C1-C4-alkoxycarbonyl-C1-C4-alkyl. Application as herbicide; for plant desiccation/defoliation.(FR) Arylpyridine substituée en 2 répondant à la formule (I) et ses sels. Dans ladite formule (I), R1 = SH, SO2OH, SO2C1, SO2NH2, C1-C6-Alkylthio, C1-C6-Alkyle sulfinyle, C1-C6-alkylsulfonyle, C1-C6-alkylamino-sulfonyle, Di(C1-C6-alkyl)aminosulfonyle; R2, R3 = H, halogène; R4 = H, C1-C6-alkyle, C1-C6-halogenalkyle, cyano-C1-C6-alkyle, C1-C6-alkoxy, C1-C6-alkoxy-C1-C6-alkyle, C1-C4-halogène-alkoxy-C1-C4-alkyle, C1-C6-alkylthio-C1-C6-alkyle-, C1-C6-alkylsulfinyle-C1-C6-alkyle, C1-C6-alkylsulfonyl-C1-C6 alkyle, C1-C4-alkoxy-C1-C4-alkoxy-C1-C4-alkyle, C1-C6-alkoxycarbonyle-C1-C6-alkyle, C1-C3-alkoxy-C1-C3-alkoxycarbonyl-C1-C6-alkyle, C2-C4-alkenyloxy-C1-C4-alkyle, C3-C4-alkinyloxy-C1-C4-alkyle, C3-C7-cycloalkyle, C3-C7-cycloalkyl-C1-C6-alkyle, C3-C7-cycloalkyloxy-C1-C6-alkyle, C3-C7-cycloalkylthio-C1-C6-alkyle, C3-C8-alkenyle, C3-C8-alkinyle, C3-C8-halogenalkenyle, C3-C8-halogenalkinyle, C1-C6-alkoxy-C3-C8-alkenyle, C1-C6-alkoxy-C3-C8-alkinyle, C1-C6-alkylcarbonyle, C1-C6-alkylsulfonyle, C3-C6-alkenyloxy, C3-C6-alkinyloxy ou benzyl éventuellement substitué; X = -O-, -S-, -NH-, -N(CH3)-, -CH2-; Y = liaison chimique, -CO-, C(R5,R6); R5,R6 = H, NO2, CN, OCH3, SCH3, halogène, C1-C4-alkyle, C1-C4-halogenalkyle, C1-C4-alkoxycarbonyle, C2-C6-alkenyle, C3-C6-alkinyle, C1-C4-alkoxycarbonyl-C1-C4-alkyle. Application: comme herbicide; pour la dessication/défoliation des plantes.

  ( DE ) Substituierte 2-Arylpyridine ( I ) und deren Salze , wobei R1 = SH , SO2OH , SO2C1 , SO2NH2 , C1-C6-Alkylthio , C1-C6-Alkylsulfinyl , C1-C6-Alkylsulfonyl , C1-C6-Alkylaminosulfonyl , Di(C1-C6-alkyl)aminosulfonyl ; R2 , R3 = H , Halogen ; R4 = H , C1-C6-Alkyl , C1-C6-Halogenalkyl , Cyano-C1-C6-alkyl , C1-C6-Alkoxy , C1-C6-Alkoxy-C1-C6-alkyl , C1-C4-Halogenalkoxy-C1-C4-alkyl , C1-C6-Alkylthio-C1-C6-alkyl , C1-C6-Alkylsulfinyl-C1-C6-alkyl , C1-C6-Alkylsulfonyl-C1-C6-alkyl , C1-C4-Alkoxy-C1-C4-alkoxy-C1-C4-alkyl , C1-C6-Alkoxycarbonyl-C1-C6-alkyl , C1-C3-Alkoxy-C1-C3-alkoxycarbonyl-C1-C6-alkyl , C2-C4-Alkenyloxy-C1-C4-alkyl , C3-C4-Alkinyloxy-C1-C4-alkyl , C3-C7-Cycloalkyl , C3-C7-Cycloalkyl-C1-C6-alkyl , C3-C7-Cycloalkyloxy-C1-C6-alkyl , C3-C7-Cycloalkylthio-C1-C6-alkyl , C3-C8-Alkenyl , C3-C8-Alkinyl , C3-C8-Halogenalkenyl , C3-C8-Halogenalkinyl , C1-C6-Alkoxy-C3-C8-Alkenyl , C1-C6-Alkoxy-C3-C8-Alkinyl , C1-C6-Alkylcarbonyl , C1-C6-Alkylsulfonyl , C3-C6-Alkenyloxy , C3-C6-Alkinyloxy oder geg. substit. Benzyl ; X = -O- , -S- , -NH- , -N(CH3)- , -CH2- ; Y = chemische Bindung , -CO- , C(R5,R6) ; R5,R6 = H , NO2 , CN , OCH3 , SCH3 , Halogen , C1-C4-Alkyl , C1-C4-Halogenalkyl , C1-C4-Alkoxycarbonyl , C2-C6-Alkenyl , C3-C6-Alkinyl , C1-C4-Alkoxycarbonyl-C1-C4-alkyl. Benutzung: als Herbicide ; zur Entsechung/Ent.Decimalisierung von Pflanzen. ( EN ) Substituted 2-arylpyridine of formula ( I ) and its salts. In formula ( I ), R1 = SH , SO2OH , SO2C1 , SO2NH2 , C1-C6-alkylthio , C1-C6-alkyl sulfinyl , C1-C6-alkylsulfonyl , C1-C6-alkylaminosulfonyl , Di(C1-C6-alkyl)aminosulfonyl ; R2 , R3 = H , halogen ; R4 = H , C1-C6-alkyl , C1-C6-halogenalkyl , cyano-C1-C6-alkyl , C1-C6-alkoxy , C1-C6-alkoxy-C1-C6-alkyl , C1-C4-halogen-alkoxy-C1-C4-alkyl , C1-C6-alkylthio-C1-C6-alkyl , C1-C6-alkylsulfinyl-C1-C6-alkyl , C1-C6-alkylsulfonyl-C1-C6-alkyl , C1-C4-alkoxy-C1-C4-alkoxy-C1-C4-alkyl , C1-C6-alkoxycarbonyl-C1-C6-alkyl , C1-C3-alkoxy-C1-C3-alkoxycarbonyl-C1-C6-alkyl , C2-C4-alkenyloxy-C1-C4-alkyl , C3-C4-alkinyloxy-C1-C4-alkyl , C3-C7-cycloalkyl , C3-C7-cycloalkyl-C1-C6-alkyl , C3-C7-cycloalkyloxy-C1-C6-alkyl , C3-C7-cycloalkylthio-C1-C6-alkyl , C3-C8-alkenyl , C3-C8-alkinyl , C3-C8-halogenalkenyl , C3-C8-halogenalkinyl , 1-C6-alkoxy-C3-C8-alkenyl , 1-C6-alkoxy-C3-C8-alkinyl , 1-C6-alkylcarbonyle , 1-C6-alkylsulfonyl , C3-C6-alkenyloxy , C3-C6-alkinyloxy or eventually substitute benzyl ; X = -O- , -S- , -NH- , -N(CH3)- , -CH2- ; Y = chemical bond , -CO- , C(R5,R6) ; R5,R6 = H , NO2 , CN , OCH3 , SCH3 , halogen , C1-C4-alkyl , C1-C4-halogenalkyl , C1-C4-alkoxycarbonyl , C2-C6-alkenyl , C3-C6-alkinyl , C1-C4-alkoxycarbonyl-C1-C4-alkyl. Application: as herbicide ; for plant desiccation/defoliation.