5-(cyclohex-3-en-1-yl)bicyclo[2.2.1]hept-2-ene | 4711-96-0

• 分子结构分类: 有机化合物 - 碳氢化合物 - 多环烃
• 英文名称: 5-(cyclohex-3-en-1-yl)bicyclo[2.2.1]hept-2-ene
• 英文别名: 5--norborn-2-en；5-(3-cyclohexen-1-yl)bicyclo[2.2.1]hept-2-ene；5-(3-cyclohexen-1-yl)-2-norbornene；5-cyclohex-3-enyl-norborn-2-ene；5-Cyclohex-3-enyl-norborn-2-en；2-(4-Cyclohexenyl)bicyclo(2.2.1)hept-5-ene；5-cyclohex-3-en-1-ylbicyclo[2.2.1]hept-2-ene
• CAS: 4711-96-0
• 化学式: C₁₃H₁₈
• 分子量: 174.286
• InChiKey: KKCXDWJDGRCIAB-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4
• 重原子数：
  13
• 可旋转键数：
  1
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.69
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  5-(cyclohex-3-en-1-yl)bicyclo[2.2.1]hept-2-ene 在 水 、 氢溴酸 、 双氧水 、 potassium hydroxide 作用下， 以 乙醚 为溶剂， 反应 2.5h， 以4.8 g的产率得到6-(7-oxabicyclo[4.1.0]hept-3-yl)-3-oxatetracyclo-[3.2.1.0^2.4]octane
  参考文献：
  名称：

  使用金属卤化物和过氧化氢液相合成环状二烯二环氧化合物

  摘要：

  发现了在[MHlg-HA或HHlg] -H 2 O系统中诱导环二烯（四氢茚，4-乙烯基环己烯和5-乙烯基和5-环己烯基双环[2.2.1]庚-2-烯）的羟基卤化的最佳条件。2（或NaClO）。用粉末状碳酸钾将如此获得的氯代和溴代醇脱氢卤化，得到相应的二环氧衍生物，它们的水解导致形成立体异构的四元醇的混合物。

  DOI：

  10.1134/s1070428012100077
• 作为产物：
  描述：

  4-乙烯基-1-环己烯 、 环戊二烯 生成 5-(cyclohex-3-en-1-yl)bicyclo[2.2.1]hept-2-ene
  参考文献：
  名称：

  Alder; Rickert, Chemische Berichte, 1938, vol. 71, p. 379,384

  摘要：

  DOI：

文献信息

• Phenolic compounds
  申请人：Shell Oil Company

  公开号：US05382713A1

  公开（公告）日：1995-01-17

  A phenolic compound is provided which can be described by the formula ##STR1## in which Ar is a C.sub.6-20 aromatic moiety, L is a cyclohexanenorbornane linking moiety, L' is a divalent cycloaliphatic moiety, and each of m and n is a number within the range of 0 to about 10. Such phenols include the product of the addition reaction of phenol with a cyclohexenenorbornene compound such as 5-(3-cyclohexen-1-yl)bicyclo[2.2.1]hept-2-ene.

  提供一种酚类化合物，其可以用以下式子描述：##STR1## 其中Ar是一个C.sub.6-20芳香基团，L是一个环己烷-藿烷连接基团，L'是一个二价的环烷基团，m和n分别是0到约10之间的数字。这些酚包括苯酚与环己烯藿烯化合物（例如5-(3-环己烯-1-基)bicyclo[2.2.1]hept-2-ene）的加成反应产物。
• Phenolic allyl ethers
  申请人：Shell Oil Company

  公开号：US05495051A1

  公开（公告）日：1996-02-27

  A phenolic allyl ether is provided which can be prepared by reacting a polyphenol with an allyl halide, said polyphenol described by the formula ##STR1## in which Ar is an aromatic moiety, L is a divalent cyclohexanenorbornane linking moiety, L' is a divalent cycloaliphatic moiety, Allyl is a phenolic allyl ether group, and each of m and n is a number within the range of 0 to about 10. Such phenolic allyl ethers include the reaction product of allyl halide with the product of the addition reaction of a phenol and a cyclohexenenorbornene compound such as 5-(3-cyclohexen-1-yl)bicyclo[2.2.1]hept-2-ene. The resulting phenolic allyl ether resins are useful as processing agents for polymaleimides.

  提供了一种酚基烯丙基醚，可以通过将多酚与烯丙基卤化物反应制备，所述多酚由以下公式描述：##STR1## 其中Ar是芳香基，L是二价的环己烷-莽卡烷连接基，L'是二价的环状脂肪族基，Allyl是酚基烯丙基醚基团，m和n分别是0到约10之间的数字。这样的酚基烯丙基醚包括烯丙基卤化物与酚和环己烯莽卡烷化合物（例如5-(3-环己烯-1-基)bicyclo [2.2.1]hept-2-ene）的加成反应产物。所得的酚基烯丙基醚树脂可用作聚马来酰亚胺的加工剂。
• Epoxy resins with cyclohexenenorbornene moieties
  申请人：Shell Oil Company

  公开号：US05284929A1

  公开（公告）日：1994-02-08

  An epoxy resin is provided which can be described by the formula ##STR1## in which Ar is an aromatic moiety, L is a divalent cyclohexanenorbornane linking moiety, L' is a divalent cycloaliphatic moiety, Gly is a glycidyl ether group, and each of m and n is a number within the range of 0 to about 10. Such epoxy resins include the product of glycidation of the product of the addition reaction of a phenol and a cyclohexenenorbornene compound such as 5-(3-cyclohexen-1-yl)bicyclo[2.2.1]hept-2-ene. The resulting epoxy resins have low melt viscosity and low water absorbance in the cured state and are useful as the resinous component of high-performance electrical laminating and encapsulation formulations.

  提供了一种环氧树脂，可以通过以下公式描述：##STR1## 其中Ar是芳香基，L是二价环己烷-去氢萘连接基，L'是二价环烷基，Gly是环氧乙烷基，m和n分别是0到约10的数字。这样的环氧树脂包括对苯酚和环己烯去氢萘化合物（如5-(3-环己烯-1-基)双环[2.2.1]庚-2-烯）的加成反应产物的环氧化产物。所得的环氧树脂在固化状态下具有低熔融粘度和低吸水性，可用作高性能电气层压和封装配方的树脂组分。
• Cyanate resins
  申请人：Shell Oil Company

  公开号：US05340912A1

  公开（公告）日：1994-08-23

  A cyanate-functional compound is provided which can be described by the formula ##STR1## in which Ar is a C.sub.6-20 aromatic moiety, L is a hexanenorbornane linking moiety, L' is a divalent cycloaliphatic moiety, and each of m and n is a number within the range of 0 to about 10. Such cyanate esters include the product of cyanation of the addition reaction of a phenol with a cyclohexene norbornene compound such as 5-(3-cyclohexen-1-yl)bicyclo[2.2.1]hept-2-ene. The resulting cyanate esters have low melt viscosity and low water absorbance in the cured state and are useful as the resinous component of high-performance electrical laminating and encapsulation formulations.

  提供了一种氰酸酯官能化合物，其可以用以下公式描述：##STR1## 其中Ar是C.sub.6-20芳香基团，L是己烷脱环戊烷连接基团，L'是二价环状脂肪族基团，m和n分别是在0到约10范围内的数字。这样的氰酸酯包括苯酚与类似5-(3-环己烯-1-基)双环[2.2.1]庚-2-烯的环己烯脱环戊烷化合物的加成反应的氰化产物。所得的氰酸酯在固化状态下具有低熔融粘度和低吸水性，并可用作高性能电气层压和封装配方的树脂组分。
• Cyclohexanenorbornane epoxy resin with curing agent
  申请人：Shell Oil Company

  公开号：US05359023A1

  公开（公告）日：1994-10-25

  An epoxy resin is provided which can be described by the formula ##STR1## in which Ar is an aromatic moiety, L is a divalent cyclohexanen or bornane linking moiety, L' is a divalent cycloaliphatic moiety, Gly is a glycidyl ether group, and each of m and n is a number within the range of 0 to about 10. Such epoxy resins include the product of glycidation of the product of the addition reaction of a phenol and a cyclohexenenorbornene compound such as 5-(3-cyclohexen-1-yl)bicyclo[2.2.1]hept-2-ene. The resulting epoxy resins have low melt viscosity and low water absorbance in the cured state and are useful as the resinous component of high-performance electrical laminating and encapsulation formulations.

  提供了一种环氧树脂，可以用以下公式描述：##STR1## 其中Ar是芳香基团，L是二价的环己烷或伯兰烷连接基团，L'是二价的环状脂肪族基团，Gly是缩水甘油醚基团，m和n各自在0到约10的范围内。这样的环氧树脂包括苯酚和环己烯-伯兰烯化合物（例如5-（3-环己烯-1-基）双环[2.2.1]庚-2-烯）的加成反应产物的缩水甘油醚化产物。所得到的环氧树脂在固化状态下具有低熔融粘度和低吸水性，并且可用作高性能电气层压和封装配方的树脂组分。