Dodecane-5-thiol | 189175-95-9

• 分子结构分类: 有机化合物 - 有机硫化合物 - 硫醇
• 英文名称: Dodecane-5-thiol
• CAS: 189175-95-9
• 化学式: C₁₂H₂₆S
• 分子量: 202.4
• InChiKey: OQHJTWHQSNAPGL-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.8
• 重原子数：
  13
• 可旋转键数：
  9
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  1
• 氢给体数：
  1
• 氢受体数：
  1

文献信息

• Preparation of alkoxysulfates
  申请人：Shell Internationale Research Maatschappij B.V.

  公开号：EP2236493A1

  公开（公告）日：2010-10-06

  The present invention relates to the use of an alkylene sulfate for reducing the level of at least one undesirable by-product in the formation of alkoxysulfates from one or more nucleophile.

  本发明涉及使用烷基磺酸盐来降低在从一个或多个亲核试剂形成烷氧基磺酸盐时至少一种不良副产物的水平。
• [EN] PREPARATION OF AN ALKOXYLATE COMPOSITION<br/>[FR] PREPARATION D'UNE COMPOSITION D'ALCOXYLATE
  申请人：SHELL INT RESEARCH

  公开号：WO2005005360A1

  公开（公告）日：2005-01-20

  Use of a double metal cyanide complex catalyst for reducing the level of free active hydrogen containing organic compound and/or 1,4-dioxane in an alkoxylate composition prepared by the reaction of a starting alcohol with an alkylene oxide.

  使用双金属氰化物络合物催化剂来降低含有自由活性氢的有机化合物和/或1,4-二噁烷在由起始醇与烷基氧化物反应制备的烷氧基化合物中的含量。
• PREPARATION OF ALKOXYSULFATES
  申请人：MEURS Jan Hermen Hendrik

  公开号：US20100010251A1

  公开（公告）日：2010-01-14

  A process for the preparation of alkoxysulfates from organic compounds containing one or more nucleophilic groups by reacting said organic compound, in a water-miscible solvent selected from the group consisting of sulfur-containing solvents such as dimethylsulfoxide (DMSO) or sulfolane, or polar solvents such as tetrahydrofuran (THF), dimethylformamide (DMF), dimethylacetamide (DMA) and hexamethylphosphoric triamide (HMPT), with an alkylene sulfate, in a non-water-miscible solvent selected from the group consisting of chlorinated solvents such as methylene chloride, chloroform, carbon tetrachloride, trichloroethane or chlorinated aromatics, such as chlorobenzene or dichlorobenzene, and non-chlorinated aromatics, such as toluene or xylenes, in the presence of a base selected from the group consisting of hydroxides, carbonates and hydrogen carbonates of alkali metals or alkaline earth metals.

  一种制备烷氧基硫酸盐的方法，包括将含有一个或多个亲核基团的有机化合物与烷基硫酸盐在非水溶性溶剂中反应，所述非水溶性溶剂选自包括含硫溶剂（如二甲基亚砜（DMSO）或硫代乙酮）或极性溶剂（如四氢呋喃（THF）、二甲基甲酰胺（DMF）、二甲基乙酰胺（DMA）和六甲基膦酰胺（HMPT））的溶剂组，所述有机化合物在水亲和性溶剂中反应。所述非水溶性溶剂选自包括氯化溶剂，如二氯甲烷、氯仿、四氯化碳、三氯乙烷或氯化芳烃，如氯化苯或二氯苯，以及非氯化芳烃，如甲苯或二甲苯，存在碱金属或碱土金属的氢氧化物、碳酸盐和氢碳酸盐中的一种。
• Preparation of efficient REPO and LAPO catalysts
  申请人：Edwards Lee Charles

  公开号：US20050154238A1

  公开（公告）日：2005-07-14

  A method of ensuring the production of efficient lanthanum phosphate catalysts (LAPO's) and rare earth phosphate catalysts (REPO's), and methods of alkoxylation using said efficient catalysts.

  确保高效生产镧磷酸盐催化剂（LAPO）和稀土磷酸盐催化剂（REPO）的方法以及使用该高效催化剂的烷氧基化方法。
• PREPARATION OF EFFICIENT REPO AND LAPO CATALYSTS
  申请人：EDWARDS Lee Charles

  公开号：US20060247476A1

  公开（公告）日：2006-11-02

  A method of ensuring the production of efficient lanthanum phosphate catalysts (LAPO's) and rare earth phosphate catalysts (REPO's), and methods of alkoxylation using said efficient catalysts.

  一种确保高效生产镧磷酸盐催化剂（LAPO）和稀土磷酸盐催化剂（REPO）的方法，以及使用该高效催化剂的烷氧基化方法。