Benzene-1,4-disulfonohydrazide | 29082-45-9

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: Benzene-1,4-disulfonohydrazide
• CAS: 29082-45-9
• 化学式: C₆H₁₀N₄O₄S₂
• 分子量: 266.302
• InChiKey: CDAVWYNKSAKSIE-UHFFFAOYSA-N

物化性质

• 沸点：
  523.4±60.0 °C(Predicted)
• 密度：
  1.614±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  -1.6
• 重原子数：
  16
• 可旋转键数：
  4
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  161
• 氢给体数：
  4
• 氢受体数：
  8

反应信息

• 作为反应物：
  描述：

  Benzene-1,4-disulfonohydrazide 、 benzenediazonium tetrafluoroborate 在 potassium acetate 、 四丁基碘化铵 、 双(二环己基膦)甲烷 、 palladium dichloride 作用下， 以 二甲基亚砜 为溶剂， 反应 12.0h， 以88%的产率得到对三联苯
  参考文献：
  名称：

  芳基磺酰肼与芳基重氮盐的脱硫和脱氮钯催化交叉偶联

  摘要：

  建立了在相对温和的条件下钯催化的芳基磺酰肼与芳基重氮盐的交叉偶联，以提供联芳基产物。该反应用四丁基碘化铵平稳地进行，并得到在空气中用PdCl 2 /双（二环己基膦基）甲烷催化剂形成的具有CC键的相应产物。该方法还允许容易地获得重要的功能性联芳基，以用于药物和有机化学的潜在应用。

  DOI：

  10.1002/aoc.4484

文献信息

• Hindered amine light stabilizer hydrazides
  申请人：ELF ATOCHEM NORTH AMERICA, INC.

  公开号：EP0467344A1

  公开（公告）日：1992-01-22

  New and novel carboxylic acid hydrazides bearing a 2,2,6,6-tetra-alkyl-4-piperidine ring and new and novel polymeric compositions stabilized therewith are provided. The novel compounds which contain a light stabilizing group and a reactive hydrazide functionality in the same molecule are prepared by hydrazinolysis of the ester group of an intermediate carboxylic acid ester which contains the 2,2,6,6-tetralkylpiperidine moiety.

  本发明提供了含有 2，2，6，6-四烷基-4-哌啶环的新型羧酸酰肼以及用其稳定的新型聚合物组合物。这些新型化合物在同一分子中含有光稳定基团和活性酰肼官能团，其制备方法是对含有 2,2,6,6- 四烷基哌啶分子的中间羧酸酯的酯基进行酰肼水解。
• WATER SOLUBLE BIODEGRADABLE MATERIAL
  申请人：Li, Xiaolu

  公开号：EP1942137A1

  公开（公告）日：2008-07-09

  Disclosed herein is a water-soluble fully biodegradable material comprising a main material and a foaming agent, wherein the main material is a product formed by melting a mixture containing starch, polyol, and water-containing polyvinyl alcohol; and the polyvinyl alcohol is hydrophilic polyvinyl alcohol. The main material is a product formed from a molten mixture and has a melting temperature of 130-190 ° C which is much lower than its decomposition temperature of 250-400 ° C, therefore the water-soluble fully biodegradable material can achieve molten state, has thermoplastic processability incomparable to that of conventional simple physical mixture of polyvinyl alcohol, starch, and polyol, and can achieve real extrusion granulation and foam molding. The foam product prepared from the inventive material by foam molding has excellent foaming ratio, compression strength, resilience rate and dimension stability. The foam product can be dissolved in water so as to accelerate decomposition at waste treatment condition or ambient condition after disposal, and will not cause environment pollution.

  本文公开了一种水溶性全生物降解材料，由主材料和发泡剂组成，其中主材料是通过熔化含有淀粉、多元醇和含水聚乙烯醇的混合物形成的产品；聚乙烯醇是亲水性聚乙烯醇。主材料是由熔融混合物形成的产品，其熔化温度为 130-190 °C，远低于其 250-400 °C的分解温度，因此水溶性全生物降解材料可以达到熔融状态，具有传统的聚乙烯醇、淀粉和多元醇简单物理混合物无法比拟的热塑性加工性，可以实现真正的挤压造粒和泡沫成型。本发明材料通过发泡成型制备的泡沫产品具有优异的发泡率、压缩强度、回弹率和尺寸稳定性。泡沫产品可溶解于水，从而在废物处理条件下或处置后的环境条件下加速分解，不会造成环境污染。
• HYDROPHOBIC BIODEGRADABLE MATERIAL
  申请人：Li, Xiaolu

  公开号：EP1942139A1

  公开（公告）日：2008-07-09

  Disclosed herein is a hydrophobic fully biodegradable material comprising a main material and a foaming agent, wherein the main material is a product formed by melting a mixture containing polyol and water-containing polyvinyl alcohol, and optionally containing starch; and the polyvinyl alcohol is hydrophobic polyvinyl alcohol. The main material is a product formed from a molten mixture and has a melting temperature of 130-210°C which is much lower than its decomposition temperature of 240-420° C, therefore the hydrophobic fully biodegradable material can achieve molten state, and can achieve real extrusion granulation and foam molding. The foam product prepared from the inventive material by foam molding has excellent foaming ratio (higher than 45%), compression strength (≥35 Mpa), resilience rate, dimension stability, water-resistance and biodegradability.

  本发明公开了一种疏水性全生物降解材料，包括主材料和发泡剂，其中主材料是通过熔化含有多元醇和含水聚乙烯醇的混合物形成的产品，也可选择含有淀粉；聚乙烯醇是疏水性聚乙烯醇。主材料是由熔融混合物形成的产品，其熔化温度为 130-210℃，远低于其分解温度 240-420℃，因此疏水性全生物降解材料可以达到熔融状态，可以实现真正的挤压造粒和泡沫成型。用本发明材料发泡成型制备的泡沫产品具有优异的发泡率（高于 45%）、压缩强度（≥35 兆帕）、回弹率、尺寸稳定性、耐水性和生物降解性。
• EP1942137B1
  申请人：——

  公开号：EP1942137B1

  公开（公告）日：2014-05-07
• METHOD FOR PREPARING A HYDROPHOBIC BIODEGRADABLE MATERIAL
  申请人：Li, Xiaolu

  公开号：EP1942139B1

  公开（公告）日：2012-04-18