benzoylphosphine | 91166-46-0

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: benzoylphosphine
• 英文别名: Benzophosphid；Benzoyl-phosphin；phenyl(phosphanyl)methanone
• CAS: 91166-46-0
• 化学式: C₇H₇OP
• 分子量: 138.106
• InChiKey: FZGSCNQUWMMDIG-UHFFFAOYSA-N

物化性质

• 沸点：
  219.0±23.0 °C(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  1.8
• 重原子数：
  9
• 可旋转键数：
  1
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  17.1
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  benzoylphosphine 以69%的产率得到
  参考文献：
  名称：

  LIOTTA, CH. L.;MCLAUGHLIN, M. L.;OBRIEN, B. A., TETRAHEDRON LETT., 1984, 25, N 12, 1249-1252

  摘要：

  DOI：
• 作为产物：
  描述：

  苯甲酸异丙酯 在 18-冠醚-6 二氢磷化钾 、 三氟乙酸 作用下， 以 氘代氯仿 、 苯 为溶剂， 反应 72.0h， 生成 benzoylphosphine
  参考文献：
  名称：

  The synthesis and reactions of potassium benzoylphosphide, benzoylphosphine, and benzoylmethylphosphine.

  摘要：

  DOI：

  10.1016/s0040-4039(01)80125-8

文献信息

• PRODUCTION OF OPHTHALMIC DEVICES BASED ON PHOTO-INDUCED STEP GROWTH POLYMERIZATION
  申请人：Medina Arturo Norberto

  公开号：US20110269869A1

  公开（公告）日：2011-11-03

  The invention provide a new lens curing method for making hydrogel contact lenses. The new lens curing method is based on actinically-induced step-growth polymerization. The invention also provides hydrogel contact lenses prepared from the method of the invention and fluid compositions for making hydrogel contact lenses based on the new lens curing method. In addition, the invention provide prepolymers capable of undergoing actinically-induced step-growth polymerization to form hydrogel contact lenses.

  这项发明提供了一种新的透镜固化方法，用于制造水凝胶隐形眼镜。这种新的透镜固化方法基于光引发的步聚合反应。该发明还提供了通过该发明方法制备的水凝胶隐形眼镜，以及基于新的透镜固化方法制造水凝胶隐形眼镜的液体组合物。此外，该发明提供了能够经历光引发的步聚合反应形成水凝胶隐形眼镜的预聚合物。
• [EN] A VERSATILE PROCESS FOR THE PREPARATION OF ACYLPHOSPHINES<br/>[FR] PROCÉDÉ POLYVALENT DE PRÉPARATION D'ACYLPHOSPHINES
  申请人：ETH ZUERICH

  公开号：WO2018050901A1

  公开（公告）日：2018-03-22

  The present invention relates to a versatile, highly efficient process for the preparation of acylphosphines such as mono- and bisacylphosphines via reaction of phosphines (PH3 and higher homologues) or silylated phosphines with acylhalides in the presence of at least one lewis acid. The invention further relates to novel acyl phosphines obtainable by said process.

  本发明涉及一种多功能、高效的制备酰基膦化合物（如单酰基膦和双酰基膦）的过程，通过磷化氢（PH3和更高级同系物）或硅烷基膦与酰卤在至少一种路易斯酸存在下反应制备。该发明还涉及通过该过程获得的新型酰基膦化合物。
• UV-ABSORBING VINYLIC MONOMERS AND USES THEREOF
  申请人：Novartis AG

  公开号：US20170242275A1

  公开（公告）日：2017-08-24

  Described herein are water-soluble UV-absorbing vinylic monomers and their uses in preparing UV-absorbing contact lenses capable of blocking ultra-violet (“UV”) radiation and optionally (but preferably) violet radiation with wavelengths from 380 nm to 440 nm, thereby protecting eyes to some extent from damages caused by UV radiation and potentially from violet radiation. This invention also provides a UV-absorbing contact lens.

  本文描述了水溶性UV吸收乙烯单体及其在制备UV吸收隐形眼镜中的用途，这些隐形眼镜能够阻挡紫外线（“UV”）辐射，还可选择性地（但最好）阻挡波长在380纳米至440纳米之间的紫外线辐射，从而在一定程度上保护眼睛免受紫外线辐射和潜在的紫外线辐射造成的伤害。该发明还提供了一种UV吸收隐形眼镜。
• [EN] WATER-SOLUBLE UV-ABSORBING COMPOUNDS AND USES THEREOF<br/>[FR] COMPOSÉS HYDROSOLUBLES ABSORBANT LES UV ET LEURS UTILISATIONS
  申请人：NOVARTIS AG

  公开号：WO2017093835A1

  公开（公告）日：2017-06-08

  Described herein are dimethyl acetal-containing UV-absorbing compounds and their uses in preparing UV-absorbing polyvinyl alcohol prepolymers suitable for producing UV- absorbing contact lenses capable of blocking ultra-violet ("UV") radiation and optionally (but preferably) violet radiation with wavelengths from 380 nm to 440 nm, thereby protecting eyes to some extent from damages caused by UV radiation and potentially from violet radiation. This invention also provides a UV-absorbing polyvinyl alcohol prepolymer.

  本文描述了含有二甲基缩醛的吸收紫外线化合物及其在制备适用于生产能够阻挡紫外线（"UV"）辐射和可选地（但最好）波长为380纳米至440纳米的紫外线吸收聚乙烯醇预聚合物的紫外线吸收接触镜中的用途，从而在一定程度上保护眼睛免受紫外线辐射和潜在的紫外辐射造成的损害。本发明还提供了一种吸收紫外线的聚乙烯醇预聚合物。
• UV/VISIBLE-ABSORBING VINYLIC MONOMERS AND USES THEREOF
  申请人：Novartis AG

  公开号：US20170242274A1

  公开（公告）日：2017-08-24

  Described herein are UV-absorbing vinylic monomers and their uses in preparing UV-absorbing contact lenses capable of blocking ultra-violet (“UV”) radiation and violet radiation with wavelengths from 380 nm to 440 nm, thereby protecting eyes to some extent from damages caused by UV radiation and potentially from violet radiation.

  本文描述了UV吸收乙烯基单体及其在制备能够阻挡380纳米至440纳米波长的紫外辐射和紫外辐射的UV吸收隐形眼镜中的用途，从而在一定程度上保护眼睛免受紫外辐射和潜在的紫外辐射造成的损害。