(Z)-3-(2-bromo-3-cyclohexylprop-1-enyl)cyclohex-1-ene | 1414802-71-3

• 分子结构分类: 有机化合物 - 有机卤素化合物 - 乙烯基卤化物
• 英文名称: (Z)-3-(2-bromo-3-cyclohexylprop-1-enyl)cyclohex-1-ene
• 英文别名: 3-[(Z)-2-bromo-3-cyclohexylprop-1-enyl]cyclohexene
• CAS: 1414802-71-3
• 化学式: C₁₅H₂₃Br
• 分子量: 283.252
• InChiKey: LTBLAYPYWJFQPW-PTNGSMBKSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6.4
• 重原子数：
  16
• 可旋转键数：
  3
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.73
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为产物：
  描述：

  3-环己基-1-丙炔 、 2-环己烯醇 在 indium(III) bromide 作用下， 以 1,2-二溴乙烷 为溶剂， 以85%的产率得到(Z)-3-(2-bromo-3-cyclohexylprop-1-enyl)cyclohex-1-ene
  参考文献：
  名称：

  Indium-Promoted Allylation of Alkynes with Allylic Alcohols: Highly Regioselective Synthesis of Halogen-Substituted 1,4-Dienes

  摘要：

  Indium-promoted allylation of alkynes by direct use of allyl alcohols as the allylating agents has been developed under mild conditions, in which a wide range of allylic alcohols and alkynes (both aromatic and aliphatic alkynes) could be tolerated, and the corresponding halogen-substituted 1,4-dienes were obtained in moderate to excellent yields.

  DOI：

  10.1080/00397911.2011.604896

文献信息

• Indium-Promoted Allylation of Alkynes with Allylic Alcohols: Highly Regioselective Synthesis of Halogen-Substituted 1,4-Dienes
  作者：Hui-Lan Yue、Lei Ma、Jian-Xin Ji

  DOI：10.1080/00397911.2011.604896

  日期：2013.1.1

  Indium-promoted allylation of alkynes by direct use of allyl alcohols as the allylating agents has been developed under mild conditions, in which a wide range of allylic alcohols and alkynes (both aromatic and aliphatic alkynes) could be tolerated, and the corresponding halogen-substituted 1,4-dienes were obtained in moderate to excellent yields.