phenyl dithio-2-furoate | 59014-94-7

• 分子结构分类: 有机化合物 - 有机硫化合物 - 硫醚类
• 英文名称: phenyl dithio-2-furoate
• 英文别名: furan-2-carbodithioic acid phenyl ester；Phenyl 2-Dithiofuroat；Phenyl furan-2-carbodithioate
• CAS: 59014-94-7
• 化学式: C₁₁H₈OS₂
• 分子量: 220.316
• InChiKey: CQLWUHTXCCQKIB-UHFFFAOYSA-N

物化性质

• 沸点：
  85 °C(Press: 1 Torr)
• 密度：
  1.30±0.1 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  3.9
• 重原子数：
  14
• 可旋转键数：
  3
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  70.5
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  4-甲基吡啶 、 phenyl dithio-2-furoate 以 乙腈 为溶剂， 生成
  参考文献：
  名称：

  Kinetics and Mechanism of the Pyridinolysis of Aryl Furan-2-carbodithioates in Acetonitrile

  摘要：

  Kinetic studies on the pyridinolysis of aryl furan-2-carbodithioates 1 are carried out at 60.0 degreesC in acetonitrile. The biphasic rate dependence on the pyridine basicity with a breakpoint at pK(a)degrees = 5.2 is interpreted to indicate a change of the rate-limiting step from breakdown (betax = 0.7-0.8) to formation (betax = 0.2) of the tetrahedral intermediate, T+/-:, at the breakpoint as the basicity of the pyridine nucleophile is increased. Observation of the breakpoint is possible with pyridines since the expulsion rate of the pyridine (k-(a)) from T+/- is sufficiently low, with the low k(-a)/k(b) ratio leading to a low breakpoint, pK(a)degrees. The clear-cut change in the cross-interaction constants, pxz, from a positive (rhoxz = +0.86) to a small negative (rhoxz = -0.11) value at the breakpoint supports the mechanistic change proposed. The magnitudes of rhoz and activation parameters are also consistent with the proposed mechanism.

  DOI：

  10.1021/jo0264269
• 作为产物：
  描述：

  糠酸（呋喃甲酸） 在 2,4-bis<4-(methylthio)phenyl>-1,3,2,4-dithiadiphosphetane 2,4-disulfide 作用下， 以 甲苯 为溶剂， 反应 0.08h， 以37%的产率得到phenyl dithio-2-furoate
  参考文献：
  名称：

  ImprovedO/SExchange Reagents

  摘要：

  DOI：

  10.1055/s-1984-30980

文献信息

• Non-toxic corrosion-protection pigments based on manganese
  申请人：——

  公开号：US20040011252A1

  公开（公告）日：2004-01-22

  Corrosion-inhibiting pigments based on manganese are described that contain a trivalent or tetravalent manganese/valence stabilizer complex. An inorganic or organic material is used to stabilize the trivalent or tetravalent manganese ion to form a compound that is sparingly soluble, exhibits low solubility, or is insoluble in water, depending upon the intended usage. Specific stabilizers are chosen to control the release rate of trivalent or tetravalent manganese during exposure to water and to tailor the compatibility of the powder when used as a pigment in a chosen binder system. Stabilizers may also modify the processing and handling characteristics of the formed powders. Manganese/valence stabilizer combinations are chosen based on the well-founded principles of manganese coordination chemistry. Many manganese-valence stabilizer combinations are presented that can equal the performance of conventional hexavalent chromium or tetravalent lead systems. It is emphasized that this abstract is provided to comply with the rules requiring an abstract which will allow a searcher or other reader to quickly ascertain the subject matter of the technical disclosure. It is submitted with the understanding that it will not be used to interpret or limit the scope or meaning of the claims.

  以锰为基础的缓蚀颜料含有三价或四价锰/价稳定剂复合物。一种无机或有机材料可用于稳定三价或四价锰离子，从而形成一种可少量溶解、溶解度低或不溶于水的化合物，具体取决于预期用途。选择特定的稳定剂是为了控制三价锰或四价锰在遇水时的释放率，并调整粉末在所选粘合剂体系中用作颜料时的相容性。稳定剂还可以改变成型粉末的加工和处理特性。锰/价稳定剂组合的选择是基于锰配位化学的基本原理。文中介绍了许多锰价稳定剂组合，其性能与传统的六价铬或四价铅体系相当。需要强调的是，提供本摘要是为了符合要求提供摘要的规则，以便检索者或其他读者快速确定技术公开的主题。提交本摘要的前提是，本摘要不用于解释或限制权利要求的范围或含义。
• Non-toxic corrosion-protection pigments based on rare earth elements
  申请人：——

  公开号：US20040104377A1

  公开（公告）日：2004-06-03

  A corrosion-inhibiting pigment comprising a rare earth element and a valence stabilizer combinded to form a rare earth/valence stabilizer complex. The rare earth element is selected from cerium, terbium, praseodymium, or a combination thereof, and at least one rare earth element is in the tetravalent oxidation state. An inorganic or organic material is used to stabilize the tetravalent rare earth ion to form a compound that is sparingly soluble in water. Specific stabilizers are chosen to control the release rate of tetravalent cerium, terbium, or praseodymium during exposure to water and to tailor the compatibility of the powder when used as a pigment in a chosen binder system. Stabilizers may also modify the processing and handling characteristics of the formed powders. Many rare earth-valence stabilizer combinations are presented that can equal the performance of conventional hexavalent chromium systems.

  一种缓蚀颜料，由稀土元素和价态稳定剂结合形成稀土/价态稳定剂复合物。稀土元素选自铈、铽、镨或它们的组合，至少有一种稀土元素处于四价氧化态。使用无机或有机材料来稳定四价稀土离子，以形成稀溶于水的化合物。选择特定的稳定剂是为了控制四价铈、铽或镨在遇水时的释放率，并调整粉末在所选粘合剂体系中用作颜料时的相容性。稳定剂还可以改变成型粉末的加工和处理特性。本文介绍了许多稀土-价稳定剂组合，其性能可与传统的六价铬体系媲美。
• Aminolysis of aryl dithio-2-thiophenates and dithio-2-furoates in acetonitrile
  作者：Hyuck Keun Oh、So Young Woo、Chul Ho Shin、Ikchoon Lee

  DOI：10.1002/(sici)1097-4601(1998)30:11<849::aid-kin7>3.0.co;2-v

  日期：——

  The aminolyses of the title substrates with anilines and benzylamines are investigated in acetonitrile. A clean second-order kinetics is obtained with a first-order rate law in the amine concentration, which is uncomplicated by the fast proton transfer step. The large magnitude of rho(z) (rho(1g)) as well as rho(x) (rho(nuc)) together with relatively large positive p(xz) values is consistent with a stepwise mechanism in which thiophenolate ion expulsion from the intermediate is rate limiting. For the reactions of aryl dithio-2-thiophenates with benzylamines the magnitude of rho(x) and rho(z) values is relatively smaller suggesting that both the addition and expulsion of thiophenolate are partially rate determining. Relatively large secondary kinetic isotope effects, k(H)/k(D) greater than or equal to 1.7, with deuterated nucleophiles, support involvement a concurrent proton transfer to the departing thiophenolate ion in the transition state. (C) 1998 John Wiley & Sons, Inc.
• YOKOYAMA, MASATAKA;HASEGAWA, YUTAKA;HAFANAKA, HIDEKATSU;KAWAZOE, YUKI;IMA+, SYNTHESIS, BRD, 1984, N 10, 827-829
  作者：YOKOYAMA, MASATAKA、HASEGAWA, YUTAKA、HAFANAKA, HIDEKATSU、KAWAZOE, YUKI、IMA+

  DOI：——

  日期：——
• BENATI L.; MONTEVECCHI P. C., J. ORG. CHEM. <JOCE-AH>, 1976, 41, NO 15, 2639-2640
  作者：BENATI L.、 MONTEVECCHI P. C.

  DOI：——

  日期：——