2-(triphenylstannyl)thiophene | 54663-76-2

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 2-(triphenylstannyl)thiophene
• 英文别名: triphenyl-[2]thienyl-stannane；Triphenyl-[2]thienyl-stannan；Triphenyl(thiophen-2-yl)stannane
• CAS: 54663-76-2
• 化学式: C₂₂H₁₈SSn
• 分子量: 433.161
• InChiKey: RKDVYOKAPQRDLH-UHFFFAOYSA-N

物化性质

• 沸点：
  478.7±37.0 °C(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  3.13
• 重原子数：
  24
• 可旋转键数：
  4
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  28.2
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  2-(triphenylstannyl)thiophene 在 溴 作用下， 生成 溴三苯基锡烷
  参考文献：
  名称：

  Krause, E.; Renwanz, G., Berichte der Deutschen Chemischen Gesellschaft, 1929, vol. 62, p. 1710 - 1717

  摘要：

  DOI：
• 作为产物：
  描述：

  2-噻吩基锂 、 三苯基氯化锡 以 not given 为溶剂， 以81%的产率得到2-(triphenylstannyl)thiophene
  参考文献：
  名称：

  研究Ç -杂环锡化合物。噻吩四有机锡（IV）化合物的合成与光谱表征

  摘要：

  一系列选择性含有2-噻吩基，3-噻吩基，5-甲基-2-噻吩基，5-叔丁基-2-噻吩基，4-甲基-2-噻吩基和3-的四有机锡（IV）化合物的合成据报道，式R 4- n Sn [L] n（R = Ph，对甲苯基，Me，环戊基，环己基; n = 1-4）的（2-吡啶基）-2-噻吩基[L] 。考虑了从119m SnMössbauer和NMR（13 C和119 Sn模式）光谱得出的结构感兴趣的特征。

  DOI：

  10.1016/0022-328x(87)80093-1

文献信息

• Thienyl and perfluorophenyl derivatives of divalent lanthanides
  作者：O.P. Syutkina、L.F. Rybakova、E.S. Petrov、I.P. Beletskaya

  DOI：10.1016/0022-328x(85)88124-9

  日期：1985.2

  ne to zero-valent lanthanides has been carried out. The formation of organolanthanide derivatives RLnX (R = α-C4H3S, C6F5) has been confirmed by isolation of the corresponding RSnPh3 resulting from the interaction of RLnX with Ph3SnCl. The reaction of lanthanide with C6F5Br is sensitive to the nature of the metal.

  已经进行了α-碘噻吩和溴五氟苯的氧化加成到零价镧系元素的反应。金属有机衍生物RLnX（R =α-C的形成4 ħ 3 S，C 6 ˚F 5）已经由相应RSnPh隔离证实3从RLnX的的Ph的相互作用而产生的3的SnCl。镧系元素与C 6 F 5 Br的反应对金属的性质敏感。
• Mössbauer and NMR studies of intramolecular coordination in thienyltetraorganotin(IV) compounds, and the x-ray crystal structure of {C,N-[3-(2-pyridyl)-2-thienyl]} tri(p-tolyl)tin(IV)
  作者：V.G. Kumar Das、Lo Kong Mun、Chen Wei、Stephen J. Blunden、Thomas C.W. Mak

  DOI：10.1016/0022-328x(87)85004-0

  日期：1987.3

  Tetraorganotin(IV) compounds containing the [3-(2-pyridyl)-2-thienyl] group (L), of formula R3SnL (1: R = p-tolyl; 2: R = Ph; 3: R = p-ClC6H4; 4: R = cyclo-C5H9; 5; R = cyclo-C6H11) have been synthesized and their structures examined by 119mSn Mössbauer and NMR (119Sn and 13C modes) spectroscopic techniques, and in the case of compound 1 by X-ray analysis.

  含有式R 3 SnL的[3-（2-吡啶基）-2-噻吩基]（L）基团的四有机锡（IV）化合物（1：R =对甲苯基; 2：R = Ph; 3：R = p -ClC 6 H 4；4：R =环C 5 H 9；5； R =环C 6 H 11）已经合成并通过119m SnMössbauer和NMR（119 Sn和13 C模式）光谱检查了其结构技术，以及对于化合物1的X射线分析。
• Gmelin Handbuch der Anorganischen Chemie, Gmelin Handbook: Sn: Org.Verb.2, 1.1.2.15.9, page 422 - 426
  作者：

  DOI：——

  日期：——
• Synthesis of A-D-A type quinoxaline-based small molecules for organic photovoltaic cells
  作者：Seok Woo Lee、Ho Cheol Jin、Joo Hyun Kim、Dong Wook Chang

  DOI：10.1080/15421406.2020.1741817

  日期：2020.7.2

  We have synthesized two acceptor-donor-acceptor (A-D-A) type quinoxaline-based small molecules for organic photovoltaic cells (OPVs). To construct the A-D-A architecture, the electron-accepting quinoxaline derivative (Qx) was attached on both ends of the electron-donating benzodithiophene (BDT) unit via the Stille coupling reaction. After the confirmation of the structural features, the optical and electrochemical characteristics and the photovoltaic properties of the two small molecules were investigated. A typical inverted-type device with the configuration of ITO/ZnO/small molecules: PC71BM/MoO3/Ag was fabricated and examined. It has been observed that the performances of OPVs were improved by the incorporation of the additional thiophene linkage between the BDT and Qx moieties. Therefore, this study can provide insights into the design and structure-property correlation of quinoxaline-based organic small molecules for OPVs
• Rybakova, L. F.; Garbar, A. V.; Petrov, E. S., Doklady Chemistry, 1986, vol. 286 - 291, p. 496 - 498
  作者：Rybakova, L. F.、Garbar, A. V.、Petrov, E. S.

  DOI：——

  日期：——