Tributyl hydroxymethanetricarboxylate | 1026986-26-4

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• 英文名称: Tributyl hydroxymethanetricarboxylate
• CAS: 1026986-26-4
• 化学式: C₁₆H₂₈O₇
• 分子量: 332.394
• InChiKey: KALURNDPQWGFCP-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.2
• 重原子数：
  23
• 可旋转键数：
  15
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.81
• 拓扑面积：
  99.1
• 氢给体数：
  1
• 氢受体数：
  7

反应信息

• 作为产物：
  描述：

  acetyl tributyl citrate 在 水 作用下， 以 甲醇 为溶剂， 生成 、 Tributyl hydroxymethanetricarboxylate 、 正丁醇
  参考文献：
  名称：

  Migration and Hydrolysis of Hydrophobic Polylactide Plasticizer

  摘要：

  Hydrophobic plasticizer protects polylactide (PLA) against hydrolytic degradation but still migrates to aging medium and there undergoes further hydrolysis contributing to the spectrum of degradation products. PLA plasticized with hydrophobic acetyl tributyl citrate (ATC) plasticizer showed a slower degradation rate compared with pure PLA because of the increased hydrophobicity of the material. The enhanced bulk hydrophobicity also overcame the degradation enhancing effect of hydrophilic surface grafting. In addition to plasticization with ATC, some of the samples were also surface grafted with acrylic acid. The materials were subjected to hydrolysis at 37 and 60 degrees C for up to 364 days to compare the effect of hydrophobic and hydrophilic bulk and surface modifications. Although considered insoluble in water, the plasticizer was detected in the water solutions immediately upon immersion of the materials, and the relative abundance of the ATC degradation products increased with hydrolysis time.

  DOI：

  10.1021/bm901157h

文献信息

• POLYMER FILM, METHOD FOR PRODUCING POLYMER FILM, OPTICAL FILM AND POLARIZING PLATE AND LIQUID CRYSTAL DISPLAY DEVICE USING THE SAME
  申请人：Fukagawa Nobutaka

  公开号：US20090122237A1

  公开（公告）日：2009-05-14

  A polymer film, which comprises: organic compound fine particles containing a retardation developer and having an average particle size of from 1 nm to 1,000 nm; a method for producing a polymer film, which comprises: casting a dope containing a polymer, a solvent for dissolving the polymer, a retardation developer and an additive other than the retardation developer on a support; peeling off; drying; and stretching, wherein the retardation developer is uniformly dissolved in the dope, and between the casting and the stretching, organic compound fine particles containing the retardation developer are formed within a film; and an optical film, which comprises: at least one compound represented by formula (I) as defined in the specification; and at least one Rth raising agent.
• Migration and Hydrolysis of Hydrophobic Polylactide Plasticizer
  作者：Anders Höglund、Minna Hakkarainen、Ann-Christine Albertsson

  DOI：10.1021/bm901157h

  日期：2010.1.11

  Hydrophobic plasticizer protects polylactide (PLA) against hydrolytic degradation but still migrates to aging medium and there undergoes further hydrolysis contributing to the spectrum of degradation products. PLA plasticized with hydrophobic acetyl tributyl citrate (ATC) plasticizer showed a slower degradation rate compared with pure PLA because of the increased hydrophobicity of the material. The enhanced bulk hydrophobicity also overcame the degradation enhancing effect of hydrophilic surface grafting. In addition to plasticization with ATC, some of the samples were also surface grafted with acrylic acid. The materials were subjected to hydrolysis at 37 and 60 degrees C for up to 364 days to compare the effect of hydrophobic and hydrophilic bulk and surface modifications. Although considered insoluble in water, the plasticizer was detected in the water solutions immediately upon immersion of the materials, and the relative abundance of the ATC degradation products increased with hydrolysis time.