Process for producing copolymer latex and paper coating composition, carpet backing composition or adhesive composition comprising said latex
申请人:JAPAN SYNTHETIC RUBBER CO., LTD.
公开号:EP0407059A2
公开(公告)日:1991-01-09
A process for producing a copolymer latex having a gel content of 5% by weight or more, comprising emulsion-polymerizing
(a) 2-80% by weight of a conjugated diene compound,
(b) 0.1-10% by weight of an ethylenically unsaturated carboxylic acid, and
(c) 10-97.9% by weight of an ethylenically unsaturated compound other than the components (a) and (b) in the presence of
(d) a chain transfer agent comprising at least one member selected from the group consisting of the following (d-1) to (d-6):
(d-1) an a-methylstyrene dimer,
(d-2) at least one disulfide compound selected from the group consisting of dimethylxanthogen disulfide, diethylxanthogen disulfide and thiuram disulfide,
(d-3) at least one hydrocarbon compound selected from the group consisting of hydrocarbon compounds having an aromatic ring and at least one saturated carbon atom directly bonded to the ring, said carbon atom having bonded thereto at least one hydrogen atom and forming an aliphatic ring, and alicyclic hydrocarbon compounds having in the ring at least two carbon-to-carbon double bonds and at least one saturated carbon atom adjacent to the carbon-to-carbon double bonds and forming the aliphatic ring, said carbon atom having at least one hydrogen atom,
(d-4) an unsaturated heterocyclic compound having in the heterocyclic ring a carbon-to-carbon double bond and at least one saturated carbon atom adjacent to the carbon-to-carbon double bond and forming the heterocyclic ring, said carbon atom having at least one hydrogen atom,
(d-5) a hydrocarbon compound having at least two unsaturated bonds and at least one saturated carbon atom adjacent to the carbon atoms taking part in the two unsaturated bonds, said saturated carbon atom forming no ring structure and having at least one hydrogen atom, and
(d-6) a mixture consisting of (X) 5-95% by weight of at least one compound selected from the group consisting of terpinolene, a-terpinene, y-terpinene and dipentene and (Y) 95-5% by weight of at least one compound selected from the group consisting of alkylmercaptans, halogenated hydrocarbons and disulfide compounds. The copolymer latex produced according to the above process contains fine coagula only in a very small amount, and is suitable for use in paper coating compositions, carpet backing compositions and adhesive compositions.
一种生产凝胶含量大于或等于 5%(按重量计)的共聚物胶乳的工艺,包括乳液聚合
(a) 2-80%(按重量计)的共轭二烯化合物、
(b) 0.1-10%(重量百分比)的乙烯不饱和羧酸,和
(c) 10-97.9%(重量百分比)的乙烯基不饱和化合物(组分(a)和(b)除外),在有以下物 质存在的情况下
(d) 链转移剂,包括至少一种选自以下 (d-1) 至 (d-6) 组的成员:
(d-1) 甲基苯乙烯二聚体、
(d-2) 至少一种二硫化物,选自由二甲基黄原二硫化物、二乙基黄原二硫化物和秋兰姆二 硫化物组成的组、
(d-3) 至少一种烃类化合物,选自由下列化合物组成的组,这些烃类化合物具有一个芳香环和 至少一个直接与该环键合的饱和碳原子,所述碳原子与至少一个氢原子键合并形成脂环;脂环 烃类化合物在环中具有至少两个碳碳双键和至少一个与碳碳双键相邻并形成脂环的饱和碳原子,所述碳原子 具有至少一个氢原子、
(d-4) 不饱和杂环化合物,其杂环上有一个碳碳双键和至少一个与碳碳双键相邻的饱和碳原子,并形成杂环,所述碳原子上至少有一个氢原子; (d-5) 碳氢化合物,其杂环上有一个碳碳双键和至少一个与碳碳双键相邻的饱和碳原子,并形成脂环,所述碳原子上至少有一个氢原子、
(d-5) 具有至少两个不饱和键和至少一个饱和碳原子的碳氢化合物,所述饱和碳原子 不形成环状结构并具有至少一个氢原子,以及
(d-6) 一种混合物,其中(X)5-95%(按重量计)的至少一种选自萜品烯、a-萜品烯、y-萜品烯和二戊烯的化合物,以及(Y)95-5%(按重量计)的至少一种选自烷基硫醇、卤代烃和二硫化物的化合物。根据上述工艺生产的共聚物胶乳仅含有极少量的细小凝结物,适用于纸张涂层组合物、地毯衬底组合物和粘合剂组合物。