copper (II) lactate | 814-81-3

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• 英文名称: copper (II) lactate
• 英文别名: bis(D,L-lactato)copper(II)；copper(II) lactate；copper lactate；DL-Milchsaeure; Kupfer(II)-lactat；cupric lactate；copper;2-hydroxypropanoate
• CAS: 814-81-3
• 化学式: 2C₃H₅O₃*Cu
• 分子量: 241.688
• InChiKey: ZKIOYTGLFYDYQT-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  -1.89
• 重原子数：
  7
• 可旋转键数：
  0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.67
• 拓扑面积：
  60.4
• 氢给体数：
  1
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  copper (II) lactate 以 solid 为溶剂， 生成 铜
  参考文献：
  名称：

  Effect of synthesis method of nanocopper catalysts on the morphologies of carbon nanofibers prepared by catalytic decomposition of acetylene

  摘要：

  Regularly coiled carbon nanofibers with a novel "V"-type symmetric growth mode were synthesized by the decomposition of acetylene with nanocopper catalysts. These were obtained from an aqueous copper sulfate solution by borohydride reduction and from the decomposition of copper tartrate, butyrate, oxalate, and lactate precursors, whereas copper nanoparticles prepared by the hydrogen-arc plasma only revealed ribbon-like fibers under identical reaction conditions. The morphology of the catalyst particles before and after fiber growth has been investigated and the effect of the synthesis method on the morphology and growth of the fibers is discussed. (C) 2004 Elsevier Inc. All rights reserved.

  DOI：

  10.1016/j.jcat.2004.02.004
• 作为产物：
  描述：

  aquobis(D,L-lactato)copper(II) monohydrate 以 neat (no solvent) 为溶剂， 生成 copper (II) lactate
  参考文献：
  名称：

  Chelating properties of lactate anion. perturbing effect of additional ligands on bis(DL-lactato)-metal(II) complexes

  摘要：

  DOI：

  10.1016/s0020-1693(00)86249-0

文献信息

• Electrochemical Synthesis of Complex Compounds of Transition Elements with Carboxyl- and Carbonyl-containing Ligands
  作者：V. Yu. Frolov、S. N. Bolotin、V. T. Panyshkin

  DOI：10.1007/s11167-005-0416-7

  日期：2005.6

  Complex compounds of d- and f-elements with carboxyl- and carbonyl-containing ligands were synthesized by the electrochemical method. The influence exerted by a number of factors on the process course was studied. The dependence of the electrosynthesis parameters on the composition of the forming compounds was established. The composition of these compounds was determined. A new method for anodic synthesis of these compounds was developed.

  采用电化学方法合成了 d 元素和 f 元素与含羧基和羰基配体的复合物。研究了多种因素对合成过程的影响。确定了电合成参数对形成的化合物组成的依赖性。确定了这些化合物的组成。开发了阳极合成这些化合物的新方法。
• Structure and Stability of a Copper(II) Lactate Complex in Alkaline Solution: a Case Study by Energy-Dispersive X-ray Absorption Spectroscopy
  作者：Elisabetta Achilli、Alberto Vertova、Alberto Visibile、Cristina Locatelli、Alessandro Minguzzi、Sandra Rondinini、Paolo Ghigna

  DOI：10.1021/acs.inorgchem.7b00553

  日期：2017.6.19

  Energy-dispersive X-ray absorption spectroscopy was applied, aimed at solving the problem of the structure and stability of a copper(II) lactate complex in alkaline solution, used as a precursor for the electrodeposition of Cu2O. The application of multiple scattering calculations to the simulation of the X-ray absorption near-edge structure part of the spectra allowed an accurate resolution of the structure: the

  应用能量分散X射线吸收光谱法，旨在解决乳酸铜（II）络合物在碱性溶液中的结构和稳定性问题，该络合物用作电沉积Cu 2的前体O.将多次散射计算应用于光谱的X射线吸收近边缘结构部分的模拟，可以精确解析结构：在扭曲的四面体环境中，铜（II）阳离子被四个乳酸离子包围，其中乳酸阴离子充当单齿配体。这导致了原子排列，其中铜被距离很短的四个氧原子（约1.87Å）和距离很远的四个氧原子（约3.1–3.2Å）包围。最终发现该络合物在广泛的应用电势中是稳定的。
• Gmelin Handbuch der Anorganischen Chemie, Gmelin Handbook: Cu: MVol.B1, 32, page 63 - 65
  作者：

  DOI：——

  日期：——
• Richards, T. W.; Whitridge, A. H., American Chemical Journal, 1895, vol. 17, p. 145 - 152
  作者：Richards, T. W.、Whitridge, A. H.

  DOI：——

  日期：——
• CCIII.—Metallic hydroxy-acid complexes. Part I. Cuprilactates
  作者：Ian William Wark

  DOI：10.1039/ct9232301815

  日期：——