N-[6-(benzylideneamino)hexyl]-1-phenylmethanimine | 3009-40-3

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: N-[6-(benzylideneamino)hexyl]-1-phenylmethanimine
• 英文别名: N,N'-dibenzylidenehexane-1,6-diamine
• CAS: 3009-40-3
• 化学式: C₂₀H₂₄N₂
• 分子量: 292.424
• InChiKey: WOEJOHJAOFCVCI-KSTNYAOJSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.79
• 重原子数：
  22.0
• 可旋转键数：
  9.0
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.3
• 拓扑面积：
  24.72
• 氢给体数：
  0.0
• 氢受体数：
  2.0

安全信息

• 海关编码：
  2921590090

反应信息

• 作为反应物：
  描述：

  N-[6-(benzylideneamino)hexyl]-1-phenylmethanimine 在 乙腈 作用下， 以 二氯甲烷 、 水 为溶剂， 生成 2-({[6-({[(1-Carboxy-1-methyl-ethoxy)-hydroxy-phosphoryl]-phenyl-methyl}-amino)-hexylamino]-phenyl-methyl}-hydroxy-phosphinoyloxy)-2-methyl-propionic acid
  参考文献：
  名称：

  Efficient synthesis of bolaform- and gemini-type alkyl-bis-[(α-amino)phosphonocarboxylic or phosphonic acid] surfactants

  摘要：

  The synthesis of a new series of bolaform- and gemini-type phosphorus acid surfactants is described. The Pudovik addition reaction of P-H bond tetraoxyspirophosphoranes to symmetrical, prochiral bis-imines bearing different more or less long and rigid linkers occurs instantaneously at room temperature. This reaction is diastereoselective and quantitatively leads to the corresponding alkyl-bis-[alpha-aminospirophosphoranes] in good to high diastereomeric ratio. Selective and one-pot hydrolysis of these P*-C* bond bis-spirophosphoranes can be readily achieved either at room temperature by moist solvents giving the corresponding alkyl-bis-[alpha-aminophosphonocarboxylic acid] amphiphiles, or by a more drastic reaction of 20% aqueous hydrochloric acid under reflux affording free alkyl-bis[alpha-aminophosphonic acid] surfactants in good yields. (C) 2002 Elsevier Science Ltd. All rights reserved.

  DOI：

  10.1016/s0040-4020(02)00535-5
• 作为产物：
  描述：

  1,6-己二胺 、 苯甲醛 在 3 A molecular sieve 作用下， 以 氯仿 为溶剂， 反应 6.0h， 以91%的产率得到N-[6-(benzylideneamino)hexyl]-1-phenylmethanimine
  参考文献：
  名称：

  Efficient synthesis of bolaform- and gemini-type alkyl-bis-[(α-amino)phosphonocarboxylic or phosphonic acid] surfactants

  摘要：

  The synthesis of a new series of bolaform- and gemini-type phosphorus acid surfactants is described. The Pudovik addition reaction of P-H bond tetraoxyspirophosphoranes to symmetrical, prochiral bis-imines bearing different more or less long and rigid linkers occurs instantaneously at room temperature. This reaction is diastereoselective and quantitatively leads to the corresponding alkyl-bis-[alpha-aminospirophosphoranes] in good to high diastereomeric ratio. Selective and one-pot hydrolysis of these P*-C* bond bis-spirophosphoranes can be readily achieved either at room temperature by moist solvents giving the corresponding alkyl-bis-[alpha-aminophosphonocarboxylic acid] amphiphiles, or by a more drastic reaction of 20% aqueous hydrochloric acid under reflux affording free alkyl-bis[alpha-aminophosphonic acid] surfactants in good yields. (C) 2002 Elsevier Science Ltd. All rights reserved.

  DOI：

  10.1016/s0040-4020(02)00535-5

文献信息

• Fast curing olefin copolymer rubber composition
  申请人：E.I. DU PONT DE NEMOURS AND COMPANY

  公开号：EP0101827A1

  公开（公告）日：1984-03-07

  An elastomeric composition comprising an EPDM copolymer rubber; a sulfur curative for the copolymer rubber; about 5-15 parts by weight per 100 parts copolymer rubber of a chlorosulfonated polyolefin which contains 20-50 weight percent chlorine and 0.2-1.5 weight percent sulfur; and about 0.25-1 parts by weight per 100 parts copolymer rubber of a diamine-generating curing agent.

  一种弹性体组合物，包括三元乙丙橡胶（EPDM）共聚物橡胶；用于共聚物橡胶的硫磺固化剂；每 100 份共聚物橡胶中约 5-15 份（按重量计）氯磺化聚烯烃（含 20-50 重量百分比的氯和 0.2-1.5 重量百分比的硫）；以及每 100 份共聚物橡胶中约 0.25-1 份（按重量计）二胺固化剂。
• MODIFIED CONJUGATED DIENE POLYMER AND METHOD FOR PRODUCING SAME, POLYMER COMPOSITION, CROSSLINKED POLYMER, AND TIRE
  申请人：JSR Corporation

  公开号：EP2963066A1

  公开（公告）日：2016-01-06

  There is obtained a rubber composition which can improve low fuel consumption performance, workability, and abrasion resistance at the same time in uses of automobile tires and the like. A modified conjugated diene polymer is produced by a method comprising: a polymerization step of polymerizing a conjugated diene compound or polymerizing a conjugated diene compound and an aromatic vinyl compound to obtain a conjugated diene polymer having an active end in the presence of a metal amide compound obtained by mixing an alkali metal compound or an alkaline earth metal compound with a secondary amine compound and a first modification step of reacting the active end with the following compound (C1): (C1) a compound having a functional group (a) that interacts with silica, having one or more linear structures where three or more groups or atoms in total derived from at least either of a methylene group and a divalent atom are linearly connected, and capable of binding to a plurality of the active ends.

  本发明获得了一种橡胶组合物，该组合物在汽车轮胎等用途中可同时改善低油耗性能、加工性和耐磨性。改性共轭二烯聚合物的生产方法包括：聚合步骤，在碱金属化合物或碱土金属化合物与仲胺化合物混合得到的金属酰胺化合物存在下，聚合共轭二烯化合物或聚合共轭二烯化合物和芳香乙烯基化合物，以获得具有活性端的共轭二烯聚合物；第一改性步骤，使活性端与下列化合物（C1）反应： (C1) 具有与二氧化硅相互作用的官能团(a)的化合物，该化合物具有一个或多个线性结 构，其中三个或三个以上的基团或原子至少从亚甲基和二价原子中的任一基团或原子线性连 接，并能与多个活性末端结合。
• Polymer composition comprising crosslinked silicones with exchangeable crosslinking points, preparation method and uses
  申请人：ECOLE SUPERIEURE DE PHYSIQUE ET DE CHIMIE INDUSTRIELLES DE LA VILLE DE PARIS

  公开号：US10889715B2

  公开（公告）日：2021-01-12

  The invention relates to a silicone composition comprising (a) crosslinked polymers comprising consecutive —Si—O— units containing exchangeable pendant bonds and exchangeable crosslinking points, that are exchangeable by aldehyde-imine exchange reactions and/or by imine-imine exchange reactions and/or by imine-primary amine exchange reactions, obtained by crosslinking linear or branched polymers comprising consecutive —Si—O— units and (b) monofunctional free aldehydes and/or monofunctional free imines and/or monofunctional free primary amines.

  本发明涉及一种有机硅组合物，该组合物包含(a)交联聚合物，该聚合物包含连续的 -Si-O- 单元，其中含有可交换的悬键和可交换的交联点，可通过醛-亚胺交换反应和/或亚胺-亚胺交换反应和/或亚胺-伯胺交换反应进行交换，该聚合物是通过交联包含连续 -Si-O- 单元的线性或支化聚合物和(b)单官能团游离醛和/或单官能团游离亚胺和/或单官能团游离伯胺获得的。
• Mlochowski, J.; Abdel-Latif, F. F.; Kubicz, E., Polish Journal of Chemistry, 1993, vol. 67, # 4, p. 711 - 722
  作者：Mlochowski, J.、Abdel-Latif, F. F.、Kubicz, E.、Said, S. B.

  DOI：——

  日期：——
• DEVINSKY F.; LACKO I.; KRASNEC L., SYNTHESIS, 1980, NO 4, 303-305
  作者：DEVINSKY F.、 LACKO I.、 KRASNEC L.

  DOI：——

  日期：——