1-hexyl-3,4-dimethylpyrrole | 353794-70-4

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡咯
• 英文名称: 1-hexyl-3,4-dimethylpyrrole
• CAS: 353794-70-4
• 化学式: C₁₂H₂₁N
• 分子量: 179.305
• InChiKey: RFGNRAJWYWPXIR-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.7
• 重原子数：
  13
• 可旋转键数：
  5
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.67
• 拓扑面积：
  4.9
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为产物：
  描述：

  2,3-二甲基马来酸酐 在 lithium aluminium tetrahydride 、 双氧水 、 三溴化磷 作用下， 以 吡啶 、 乙醚 、 苯 为溶剂， 反应 228.0h， 生成 1-hexyl-3,4-dimethylpyrrole
  参考文献：
  名称：

  Synthesis, Characterization and Properties of Poly(1-hexyl-3,4-dimethyl-2,5-pyrrolylene)

  摘要：

  本文介绍了一种通过1-烷基-3,4-氧化偶联反应制备可溶性新型共轭有机导电聚合物聚(1-己基-3,4-二甲基-2,5-吡咯基)的合成方法。二甲基吡咯衍生自顺式1,4-二溴-2,3-二甲基-2-丁烯和己胺。

  DOI：

  10.1246/cl.2001.564

文献信息

• [EN] ION-SELECTIVE SOLID CONTACT MICROELECTRODE AND ITS PRODUCTION METHOD<br/>[FR] MICROÉLECTRODE À CONTACT SOLIDE SÉLECTIVE À L'ÉGARD DES IONS ET SON PROCÉDÉ DE PRODUCTION
  申请人：UNIV AVEIRO

  公开号：WO2010076717A1

  公开（公告）日：2010-07-08

  The presented invention relates to a needle-shaped ion-selective solid contact microelectrode with the length of the measuring point preferably but not limited to equal or less than 10 micron, particularly 0.5 - 10 micron, a method for producing such an electrode and use of an ion-selective solid contact microelectrode as a working electrode in different scanning measuring systems, such as SECM, SIET, MIFE and others, for measuring activity (concentration) of different ions in the modes of three-dimensional gradient scanning, plane two-dimensional scanning, vertical or horizontal profiling, one point measurements or any other point by point measurements over an active surface. For example, the present invention aims to substitute the glass-capillary microelectrodes used in localized measurements. The microelectrode of presented invention differs in its principles of construction and production opposed to that of solid-contact ion-selective electrodes. The invention describes a needle-shaped rigid electrically-conductive substrate (1); an insulation layer (4), except in the tip of said substrate (3); an electrically-conductive layer (6); and a layer of ion-selective membrane (7).
• Synthesis, Characterization and Properties of Poly(1-hexyl-3,4-dimethyl-2,5-pyrrolylene)
  作者：In Tae Kim、Sang Woo Lee、Tae Hyoung Kwak、Jung Youl Lee、Hyang Suk Park、Ronald L. Elsenbaumer

  DOI：10.1246/cl.2001.564

  日期：2001.6

  This paper describes a synthetic approach for the preparation of a soluble new conjugated organic conducting polymer, poly(1-hexyl-3,4-dimethyl-2,5-pyrrolylene) obtained by oxidative coupling reaction of 1-alkyl-3,4-dimethylpyrrole derived from cis-1,4-dibromo-2,3-dimethyl-2-butene and hexylamine.

  本文介绍了一种通过1-烷基-3,4-氧化偶联反应制备可溶性新型共轭有机导电聚合物聚(1-己基-3,4-二甲基-2,5-吡咯基)的合成方法。二甲基吡咯衍生自顺式1,4-二溴-2,3-二甲基-2-丁烯和己胺。