acetone-diphenylacetal | 100975-82-4

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯酚醚
• 英文名称: acetone-diphenylacetal
• 英文别名: Aceton-diphenylacetal；2,2-Diphenoxy-propan；Acetone diphenylacetal；2-phenoxypropan-2-yloxybenzene
• CAS: 100975-82-4
• 化学式: C₁₅H₁₆O₂
• 分子量: 228.291
• InChiKey: QIQSRDSFZFNZTJ-UHFFFAOYSA-N

物化性质

• 沸点：
  154-155 °C(Press: 12 Torr)
• 密度：
  1.0702 g/cm3

计算性质

• 辛醇/水分配系数(LogP)：
  4.3
• 重原子数：
  17
• 可旋转键数：
  4
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.2
• 拓扑面积：
  18.5
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  2-phenoxypropene 、 苯酚 在 盐酸 作用下， 生成 acetone-diphenylacetal
  参考文献：
  名称：

  Schostakowskii et al., Zhurnal Obshchei Khimii, 1958, vol. 28, p. 2341; engl. Ausg. S. 2379

  摘要：

  DOI：

文献信息

• Processes for producing carbonic ester and producing polycarbonate
  申请人：Okamoto Masaya

  公开号：US20050234259A1

  公开（公告）日：2005-10-20

  A process for producing a carbonic ester, characterized in that an aromatic monohydroxy compound or an aliphatic monohydroxy compound is subjected to oxidative carbonylation with carbon monoxide and oxygen in the presence of a palladium catalyst using a compound having a carbonate bond as a reaction solvent. A process for producing a polycarbonate, characterized in that an aromatic dihydroxy compound or an aliphatic dihydroxy compound is subjected to oxidative carbonylation with carbon monoxide and oxygen in the presence of a palladium catalyst using a compound having a carbonate bond as a reaction solvent is also described. The carbonic ester can be produced with a higher yield and at a higher reaction rate and, also, a polycarbonate having a higher molecular weight as compared with the conventional method can be produced with a higher yield and at a higher reaction rate.

  一种生产碳酸酯的方法，其特征在于在存在钯催化剂的情况下，使用含有碳酸酯键的化合物作为反应溶剂，将芳香单羟基化合物或脂肪单羟基化合物与一氧化碳和氧气进行氧化羰基化反应。还描述了一种生产聚碳酸酯的方法，其特征在于在存在钯催化剂的情况下，使用含有碳酸酯键的化合物作为反应溶剂，将芳香二羟基化合物或脂肪二羟基化合物与一氧化碳和氧气进行氧化羰基化反应。与传统方法相比，可以以更高的产率和更快的反应速率生产碳酸酯，并且可以以更高的产率和更快的反应速率生产具有更高分子量的聚碳酸酯。
• Textile finishes
  申请人：SWS Silicones Corporation

  公开号：EP0105464A2

  公开（公告）日：1984-04-18

  A textile finishing composition comprising a silylated polyether, a compound selected from aldehydes, acetals and mixtures thereof and a diluent. The textile finishing composition is applied to textile materials to impart improved dimensional stability, improved wetting properties and a durable softness.

  一种纺织品整理组合物，由硅烷化聚醚、一种选自醛、乙缩醛及其混合物的化合物和一种稀释剂组成。纺织品整理组合物用于纺织材料，可提高尺寸稳定性，改善润湿性能和持久柔软性。
• Process for production of ultrafine polymer latex
  申请人：LION CORPORATION

  公开号：EP0228879A2

  公开（公告）日：1987-07-15

  A ultrafine crosslinked polymer latex having a three-dimensional network structure is produced from the emulsion polymerization of (i) an ethylenically unsaturated monomer and an unsaturated monomer having a reactive functional group in the presence of a betaine ester emulsifier or (ii) an ethylenically unsaturated monomer and, optionally, an unsaturated monomer having a reactive functional group in the presence of a polyoxyalkylene ethylenically unsaturated carboxylic acid polyester emulsifier and, optionally, a betaine ester emulsifier.

  一种具有三维网状结构的超细交联聚合物胶乳是由以下两种物质乳液聚合而成：(i) 一种乙烯基不饱和单体和一种具有活性官能团的不饱和单体，在甜菜碱酯乳化剂存在下；或 (ii) 一种乙烯基不饱和单体和一种具有活性官能团的不饱和单体（可选），在聚氧亚烷基乙烯基不饱和羧酸聚酯乳化剂和甜菜碱酯乳化剂存在下。
• Catalyst for olefin polymerization
  申请人：MITSUBISHI PETROCHEMICAL CO., LTD.

  公开号：EP0261961A2

  公开（公告）日：1988-03-30

  A catalyst for olefin polymerization which comprises a combination of: Component which is a solid catalyst component A obtained by contacting a component (i) which is a solid component comprising titanium, magnesium and halogen as essential elements with a component (ii), which is a silicon compound represented by formula: R¹R²3-n Si(OR³)n where R¹ stands for a branched hydrocarbon residue, R² stands for a hydrocarbon residue which is the same as or different from R¹ and n stands for a number satisfying an equation: 1≦n≦3; Component B which is an organoaluminum compound; and Component C which is a compound represented by a formula M(OR⁴)xR⁵yXz in which M stands for an element selected from the group consisting of B, Al, C, Si, Sn, P, S, Cl, Br, I, Fe, Ti, V, Zr, Mg, Ca and Zn, R⁴ and R⁵ each stand for a hydrocarbon residue having 1 to 20 carbon atoms which are the same as or different from each other and X stands for halogen atom, each of x, y and z is a number which is equal to zero or is equal to or less than the valency of the element M and the sum of x, y and z is equal to the valency of the element M.

  一种用于烯烃聚合的催化剂，由以下组分组合而成： 一种固体催化剂组分 A，由组分(i)与组分(ii)接触而得，组分(ii)为硅化合物，其基本元素为钛、镁和卤素：R¹R²3-n Si(OR³)n 其中 R¹ 代表支链烃残基，R² 代表与 R¹ 相同或不同的烃残基，n 代表满足等式的数字：1≦n≦3; 成分 B 是一种有机铝化合物；以及 成分 C 是由式 M(OR⁴)xR⁵yXz 代表的化合物，其中 M 代表选自 B、Al、C、Si、Sn、P、S、Cl、Br、I、Fe、Ti、V、Zr、Mg、Ca 和 Zn 组成的组中的元素、R⁴和 R⁵各自代表具有 1 至 20 个碳原子的烃残基，它们彼此相同或不同，X 代表卤素原子，x、y 和 z 中的每一个都是等于零或等于或小于元素 M 的化合价的数字，且 x、y 和 z 的总和等于元素 M 的化合价。
• MAGNESIUM HALIDE ADDUCT, OLEFINS POLYMERIZATION CATALYST COMPONENT AND CATALYST MADE THEREFROM
  申请人：China Petroleum & Chemical Corporation

  公开号：EP2036928A1

  公开（公告）日：2009-03-18

  The invention provides a magnesium halide complex, having a composition represented by the formula (I): MgX2·mROH·nE·pH2O (I), wherein X is chloride, bromide, or a C1-C14 alkoxy or aryloxy; R is C1-C12 alkyl, C3-C10 cycloalkyl or C6-C10 aryl; E is a gem-dihydrocarbyloxy hydrocarbon represented by the formula (II): wherein the R1 and R2, which are identical or different, are hydrogen or C1-C10 linear or branched alkyl, C3-C10 cycloalkyl, C6-C10 aryl, C7-C10 alkylaryl or arylalkyl, said aryl, alkylaryl and arylalkyl being optionally substituted by one or more halogen atoms on aromatic ring; the R1 and R2 are optionally bonded to each other to form a ring or a fused ring system; the R3 and R4 have the same meanings as defined for the R1 and R2 other than hydrogen; m is in a range of from 1 to 5; n is in a range of from 0.005 to 1.0; and p is in a range of from 0 to 0.8. The invention further relates to a spherical catalyst component and a catalyst prepared from the spherical magnesium halide complex, and to use of the catalyst in the polymerization of α-olefin CH2=CHR or a mixture thereof, in which R is H, or alkyl or aryl having 1 to 12 carbon atoms.

  本发明提供了一种卤化镁络合物，其成分由式(I)表示：MgX2-mROH-nE-pH2O (I)、 其中，X 是氯化物、溴化物或 C1-C14 烷氧基或芳基氧基；R 是 C1-C12 烷基、C3-C10 环烷基或 C6-C10 芳基；E 是由式 (II) 所代表的锗二烃比氧基烃： 其中 R1 和 R2（相同或不同）为氢或 C1-C10 直链或支链烷基、C3-C10 环烷基、C6-C10 芳基、C7-C10 烷芳基或芳烷基，所述芳基、烷芳基和芳烷基可选择在芳香环上被一个或多个卤原子取代；R1 和 R2 可选择相互键合以形成一个环或一个融合环系统；R3 和 R4 除氢外，具有与 R1 和 R2 所定义的相同含义；m 的范围为 1 至 5；n 的范围为 0.005至1.0的范围内；p在0至0.8的范围内。本发明还涉及一种球形催化剂组分和由球形卤化镁络合物制备的催化剂，以及该催化剂在 α-烯烃 CH2=CHR 或其混合物聚合中的用途，其中 R 是 H，或具有 1 至 12 个碳原子的烷基或芳基。