2-丙烯酸丁酯与2-丙烯酸乙酯的聚合物 | 26353-42-4

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• 中文名称: 2-丙烯酸丁酯与2-丙烯酸乙酯的聚合物
• 英文名称: Butyl prop-2-enoate;ethyl prop-2-enoate
• CAS: 26353-42-4
• 化学式: C12H20O4
• 分子量: 228.28
• InChiKey: BUMBHRYBYOQTFV-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.25
• 重原子数：
  16
• 可旋转键数：
  8
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.5
• 拓扑面积：
  52.6
• 氢给体数：
  0
• 氢受体数：
  4

文献信息

• Filler particles coated with reactive liquid polymers in a matrix resin
  申请人：The B.F. GOODRICH Company

  公开号：EP0045949A1

  公开（公告）日：1982-02-17

  A composite comprising filler particles having a thin film of a reactive liquid polymer embedded in a polymeric matrix made by the method which includes the steps of mixing said reactive liquid polymer and said filler in order to provide a thin film of said reactive liquid polymer on said filler particles, mixing said coated filler particles with a polymeric matrix, and forming said composite.

  一种复合材料，包含有嵌入聚合物基质中的活性液体聚合物薄膜的填料颗粒，其制造方法包括以下步骤：混合所述活性液体聚合物和所述填料，以便在所述填料颗粒上形成所述活性液体聚合物薄膜；将所述涂覆的填料颗粒与聚合物基质混合；以及形成所述复合材料。
• Suspension polymerization of vinyl monomers
  申请人：The B.F. GOODRICH Company

  公开号：EP0062285A1

  公开（公告）日：1982-10-13

  This invention relates to a suspension polymerization process for polymerizing vinyl monomers in a reaction vessel equipped with an external cooling means, such as a reflux condenser, as well as a cooling jacket, wherein polymer buildup in said external cooling means can be substantially eliminated. This is accomplished by continuously or intermittently adding to the reaction mixture nonionic surface active or wetting agents having a hydrophile-lipophile balance (HLB) in the range of from about 9 to about 16 thus resulting in reducing charge expansion and attendant reduction in foaming of the charge.

  本发明涉及一种悬浮聚合工艺，用于在装有外部冷却装置（如回流冷凝器）和冷却夹套的反应容器中聚合乙烯基单体，其中所述外部冷却装置中的聚合物积聚现象可基本消除。 实现这一目的的方法是连续或间歇地向反应混合物中添加非离子表面活性或润湿剂，这些表面活性或润湿剂的亲水-亲油平衡（HLB）范围在约 9 到约 16 之间，从而减少了电荷膨胀，并随之减少了电荷起泡。
• Dimensionally heat-recoverable articles
  申请人：BICC Public Limited Company

  公开号：EP0118164A1

  公开（公告）日：1984-09-12

  Polymer compositions used in the manufacture of heat-shrink products for high-voltage electrical applications and which can be white or coloured comprise (i) a polymeric base comprising at least one polymer having a main chain comprising carbon atoms and optionally oxygen and/or nitrogen atoms but no other hetero-atoms crosslinked to a condition in which it is dimensionally heat-recoverable and has a recovery temperature not less than 80°C and, per hundred parts of the base (by weight); (ii) 40 to 120 parts of mineral filler of which (a) at least half, subject to a minimum of 30 parts, is calcium carbonate with a number average particle size in the range 0.01 to 50 micro metre and containing substantially no particles with a dimension in excess of 100 micrometre; (b) up to 20 parts may be an inert mineral filler, and; (c) the balance, if any, is an active flame-retardant filler. They may include also one or more pigment; one or more antioxidant and/or ultra-violet stabiliser; one or more acid acceptor; and one or more processing aid.

  用于制造高压电气应用热缩产品的聚合物成分，可以是白色或彩色的，包括 (i) 聚合物基料，包括至少一种聚合物，其主链由碳原子和可选的氧原子 和/或氮原子组成，但不含其他杂原子，交联后可进行尺寸热复原，且 复原温度不低于 80°C，每百份基料（按重量计）含以下成分 (ii) 40 至 120 份矿物填料，其中(a)至少一半（最少 30 份）为碳酸钙，其平均粒径在 0.01 至 50 微米之间，且基本上不含尺寸超过 100 微米的颗粒；(b)最多 20 份可为惰性矿物填料，及；(c)其余（如有）为活性阻燃填料。 它们还可包括一种或多种颜料；一种或多种抗氧化剂和/或紫外线稳定剂；一种或多种酸接受剂；以及一种或多种加工助剂。
• Polycarbonate-polyether block copolymers, polymer blends containing same and intermediates for the production thereof
  申请人：GENERAL ELECTRIC COMPANY

  公开号：EP0213465A2

  公开（公告）日：1987-03-11

  Block copolymers of the general formula ( polycarbonate G ( polyether glycol ) wherein G is an ester aromatic carbonate and/or an ester-ester linkage, substantially free of aliphatic ether linkages are thermally stable in comparison with prior art block copolymers. They form compatible blends with a number of other thermoplastic resins to produce molded articles with improved resiliency. The block copolymers are produced from novel terminally functional end capped polyalkylene glycols.

  通式为 ( 聚碳酸酯 G ( 聚醚乙二醇 ) ，其中 G 是芳香族碳酸酯和/或酯-酯连接，基本上不含脂肪族醚连接，与现有技术的嵌段共聚物相比具有热稳定性。它们可以与许多其他热塑性树脂形成兼容的混合物，生产出具有更好弹性的模制产品。这种嵌段共聚物是由新型末端官能团封端的聚亚烷基二醇制成的。
• Polymerisation process
  申请人：IMPERIAL CHEMICAL INDUSTRIES PLC

  公开号：EP0278668A2

  公开（公告）日：1988-08-17

  A polymerisation process which comprises contacting at least one polar acrylic type or maleimide monomer under polymerisation conditions with (i) a tetracoordinate organosilicon, organotin or organogermanium initiator having at least one initiating site, (ii) a co-catalyst which is a source of fluoride, bifluoride, cyanide or azide ions or a Lewis acid, and (iii) from 0.1 to 10% by weight, based on the weight of monomer, of acetonitrile.

  一种聚合工艺，包括在聚合条件下，将至少一种极性丙烯酸类或马来酰亚胺类单体与(i)具有至少一个引发位点的四价有机硅、有机锡或有机锗引发剂，(ii)作为氟化物、双氟化物、氰化物或叠氮离子或路易斯酸来源的助催化剂，以及(iii)按单体重量计从 0.1%到 10%的乙腈接触。