6-[9-(6-Aminohexyl)-2,7-bis(9,9-dihexylfluoren-2-yl)fluoren-9-yl]hexan-1-amine | 1171117-61-5

• 分子结构分类: 有机化合物 - 苯类化合物 - 芴
• 英文名称: 6-[9-(6-Aminohexyl)-2,7-bis(9,9-dihexylfluoren-2-yl)fluoren-9-yl]hexan-1-amine
• 英文别名: 6-[9-(6-aminohexyl)-2,7-bis(9,9-dihexylfluoren-2-yl)fluoren-9-yl]hexan-1-amine
• CAS: 1171117-61-5
• 化学式: C₇₅H₁₀₀N₂
• 分子量: 1029.63
• InChiKey: DTCLFGSUCYHASB-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  25.2
• 重原子数：
  77
• 可旋转键数：
  34
• 环数：
  9.0
• sp3杂化的碳原子比例：
  0.52
• 拓扑面积：
  52
• 氢给体数：
  2
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  氢化铕 、 二亚乙基三胺五乙酸二酐 、 6-[9-(6-Aminohexyl)-2,7-bis(9,9-dihexylfluoren-2-yl)fluoren-9-yl]hexan-1-amine 以 二甲基亚砜 为溶剂， 生成
  参考文献：
  名称：

  Mono- and Terfluorene Oligomers as Versatile Sensitizers for the Luminescent Eu³⁺ Cation

  摘要：

  We present the design, synthesis, and physical and photophysical characterization of Eu3+ and Gd3+ complexes formed with two ligands bearing either one or three fluorene sensitizer units. As a novel sensitizing approach, the oligomer length is used to control the energies of the triplet states of the sensitizer and to mediate the sensitizer to lanthanide energy transfer.

  DOI：

  10.1021/ic9002324

文献信息

• Mono- and Terfluorene Oligomers as Versatile Sensitizers for the Luminescent Eu³⁺ Cation
  作者：D. Samuel Oxley、Robert W. Walters、James E. Copenhafer、Tara Y. Meyer、Stéphane Petoud、Harry M. Edenborn

  DOI：10.1021/ic9002324

  日期：2009.7.20

  We present the design, synthesis, and physical and photophysical characterization of Eu3+ and Gd3+ complexes formed with two ligands bearing either one or three fluorene sensitizer units. As a novel sensitizing approach, the oligomer length is used to control the energies of the triplet states of the sensitizer and to mediate the sensitizer to lanthanide energy transfer.