di(2-ethylhexyl)malonate | 19824-16-9

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• 英文名称: di(2-ethylhexyl)malonate
• 英文别名: malonic acid bis-(2-ethyl-hexyl ester)；Malonsaeure-bis-(2-aethyl-hexylester)；propanedioic acid, bis(2-ethylhexyl) ester；di-(2-ethylhexyl) malonate；di(2-ethylhexyl) malonate；di-2-ethylhexyl malonate；bis(2-ethylhexyl) propanedioate
• CAS: 19824-16-9
• 化学式: C₁₉H₃₆O₄
• 分子量: 328.492
• InChiKey: YSRBRMMHTQOUDW-UHFFFAOYSA-N

物化性质

• 保留指数：
  2025

计算性质

• 辛醇/水分配系数(LogP)：
  6.4
• 重原子数：
  23
• 可旋转键数：
  16
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.89
• 拓扑面积：
  52.6
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  di(2-ethylhexyl)malonate 生成 sodium docusate
  参考文献：
  名称：

  KAJL, MARIEN;SZELEJEWSKI, WIESLAW;CYBULSKI, ANDRZEJ;CHRZCZONOWICE, SLAWOM+

  摘要：

  DOI：

文献信息

• Naphthalenemethylenemalonic diesters, and UV absorbers and cosmetic
  申请人：Kao Corporation

  公开号：US05508025A1

  公开（公告）日：1996-04-16

  The invention relates to UV absorbers and cosmetic compositions containing a naphthalenemethylenemalonic diester represented by the following formula (1): ##STR1## wherein NAP represents a naphthalene group which may optionally have a substituent, and R.sup.1 and R.sup.2 each independently represent a hydrocarbon group, an alkoxyalkyl group, or an alkoxyalkylenoxyalkyl group. The UV absorbers and the cosmetic compositions of the invention exhibit excellent ultraviolet ray absorbing action, and are stable to light.

  该发明涉及紫外线吸收剂和含有以下式（1）所代表的萘甲基丙二酸二酯的化妆品组合物：其中NAP代表一个可能具有取代基的萘基，R.sup.1和R.sup.2各自独立地代表一个碳氢基团，一个烷氧基烷基团或一个烷氧基烷氧基烷基团。该发明的紫外线吸收剂和化妆品组合物表现出优异的紫外线吸收作用，并且对光线稳定。
• New liposoluble unsaturated benzalmalonate derivatives and their use as
  申请人：L'Oreal

  公开号：US05175340A1

  公开（公告）日：1992-12-29

  The invention relates to an unsaturated benzalmalonate derivative of formula: ##STR1## in which: R.sub.1 and R.sub.2 denote a hydrogen atom, a hydroxyl, a trimethylsiloxy, a C.sub.1 -C.sub.6 straight or branched chain alkyl, C.sub.1 -C.sub.6 straight or branched chain alkoxy or a --(CH.sub.2).sub.p --C(R.sub.4).dbd.CH.sub.2 radical, where p is an integer between 1 and 10 and preferably between 1 and 4 and R.sub.4 denotes a hydrogen atom or a C.sub.1 -C.sub.4 straight or branched chain alkyl radical, one of the two radicals R.sub.1 or R.sub.2 denoting a residue --(CH.sub.2).sub.p --C(R.sub.4).dbd.CH.sub.2, R.sub.3 denotes a hydrogen atom, a C.sub.1 -C.sub.6 straight or branched chain alkyl radical or a C.sub.1 -C.sub.6 straight or branched chain alkoxy radical, R.sub.5 and R.sub.6, which are identical or different, denote a C.sub.1 -C.sub.8 straight or branched chain alkyl radical. Use as a sunscreen in cosmetic compositions.

  该发明涉及一种公式为：##STR1##的不饱和苯甲基马隆酸酯衍生物，其中：R.sub.1和R.sub.2表示氢原子、羟基、三甲基硅氧基、C.sub.1-C.sub.6直链或支链烷基、C.sub.1-C.sub.6直链或支链烷氧基或--(CH.sub.2).sub.p--C(R.sub.4).dbd.CH.sub.2基团，其中p是介于1和10之间的整数，优选在1和4之间，R.sub.4表示氢原子或C.sub.1-C.sub.4直链或支链烷基基团，R.sub.1或R.sub.2中的一个基团表示残基--(CH.sub.2).sub.p--C(R.sub.4).dbd.CH.sub.2，R.sub.3表示氢原子、C.sub.1-C.sub.6直链或支链烷基基团或C.sub.1-C.sub.6直链或支链烷氧基基团，R.sub.5和R.sub.6，相同或不同，表示C.sub.1-C.sub.8直链或支链烷基基团。用作化妆品组合物中的防晒剂。
• [EN] PHOTOPROTECTIVE COMPOSITIONS BASED ON METHYLTRIALKYLSILANES CONTAINING A CINNAMATE, CINNAMAMIDE, BENZALMALONAMIDE OR BENZALMALONATE FUNCTION<br/>[FR] COMPOSITIONS PHOTOPROTECTRICES A BASE DE METHYLTRIALKYLSILANES POSSEDANT UNE FONCTION CINNAMATE, CINNAMAMIDE, BENZALMALONAMIDE OU BENZALMALONATE
  申请人：OREAL

  公开号：WO2004067539A1

  公开（公告）日：2004-08-12

  The invention relates to photoprotective compositions comprising methyltrialkylsilanes containing a cinnamate, cinnamamide, benzalmalonamide or benzalmalonate function, as sunscreens that are active in the field of UV radiation. The invention also relates to novel methyltrialkylsilanes containing a cinnamate, cinnamamide, benzalmalonamide or benzalmalonate function and to uses thereof.

  这项发明涉及含有肉豆蔻酸酯、肉桂酰胺、苯甲基马隆酰胺或苯甲基马隆酸酯功能的甲基三烷基硅烷作为活性紫外线防晒剂的光保护组合物。该发明还涉及新型的含有肉豆蔻酸酯、肉桂酰胺、苯甲基马隆酰胺或苯甲基马隆酸酯功能的甲基三烷基硅烷以及其用途。
• Photo stable organic sunscreen compositions
  申请人：EMD CHEMICALS, INC.

  公开号：US20040247536A1

  公开（公告）日：2004-12-09

  Photostable broad-spectrum organic sunscreen compositions comprising a UV-A sunscreen, such as Avobenzone, a photostabilizer, a UV-B liquid organic sunscreen, and a solubilizer and further enhancing the photostability by encapsulation using a sol-gel process.

  具有光稳定性的广谱有机防晒霜组合物包括UV-A防晒霜，如阿伏苯宗，光稳定剂，UV-B液体有机防晒霜，溶解剂，并通过溶胶-凝胶过程进行封装以进一步增强光稳定性。
• Bis(4-hydroxy-3,5-dialkylbenzyl)cyano-carboxylic acid esters
  申请人：Ciba-Geigy Corporation

  公开号：US03950382A1

  公开（公告）日：1976-04-13

  The reaction of one mole of a Mannich base corresponding to the formula ##SPC1## And one mole of a Mannich base corresponding to the formula ##SPC2## Wherein R.sub.1, R.sub.2, R.sub.4 and R.sub.5 are independently selected from alkyl groups having 1 to 6 carbon atoms and R is alkyl, preferably lower alkyl, with 1 mole of a carboxylic acid ester corresponding to the formula R.sub.3 CH.sub.2 COOR.sub.4 wherein R.sub.3 is --H, --CN or --COOR.sub.4 and R.sub.4 is an alkyl, thioether, oxyether or aralkyl group having up to 20 carbons in the presence of a catalytically effective amount of an alkaline catalyst is useful for preparing compounds corresponding to the formula ##SPC3## The compounds represented by the above formula are useful as stabilizers for synthetic resins, particularly polyolefins. Compounds of the above formula, when R.sub.3 is --CN are novel and may also be prepared by reacting 1 mole of ##SPC4## And 1 mole of ##SPC5## Wherein X is halogen with 1 mole of NCCH.sub.2 COOR.sub.4 in the presence of an alkali metal and an anhydrous inert organic solvent.

  将一个摩尔的Mannich碱反应，其化学式为##SPC1##，和一个摩尔的Mannich碱反应，其化学式为##SPC2##，其中R.sub.1，R.sub.2，R.sub.4和R.sub.5分别为1至6个碳原子的烷基，而R是烷基，优选为低烷基，与一个摩尔的羧酸酯反应，其化学式为R.sub.3 CH.sub.2 COOR.sub.4，其中R.sub.3为--H，--CN或--COOR.sub.4，而R.sub.4为具有多达20个碳的烷基，硫醚，氧醚或芳基烷基，在碱性催化剂的存在下是制备符合以下化学式的化合物的有用方法##SPC3##上述化学式所代表的化合物可用作合成树脂的稳定剂，特别是聚烯烃。当R.sub.3为--CN时，上述化学式的化合物是新颖的，并且也可以通过在碱金属和无水惰性有机溶剂的存在下，将1摩尔的##SPC4##和1摩尔的##SPC5##反应，其中X为卤素，与1摩尔的NCCH.sub.2 COOR.sub.4反应来制备。