(E,E)-bis(4-(2-(4-N,N-dibutylaminophenyl)ethenyl)phenyl)amine | 862420-04-0

• 分子结构分类: 有机化合物 - 苯丙烷和聚酮 - 二苯乙烯类
• 英文名称: (E,E)-bis(4-(2-(4-N,N-dibutylaminophenyl)ethenyl)phenyl)amine
• 英文别名: 4-[(E)-2-[4-(dibutylamino)phenyl]ethenyl]-N-[4-[(E)-2-[4-(dibutylamino)phenyl]ethenyl]phenyl]aniline
• CAS: 862420-04-0
• 化学式: C₄₄H₅₇N₃
• 分子量: 627.957
• InChiKey: VEMPKUHSYRSOLC-WXUKJITCSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  13.3
• 重原子数：
  47
• 可旋转键数：
  20
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.36
• 拓扑面积：
  18.5
• 氢给体数：
  1
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  (E,E)-bis(4-(2-(4-N,N-dibutylaminophenyl)ethenyl)phenyl)amine 、 三(4-溴苯基)胺 在 palladium diacetate 三叔丁基膦 、 sodium t-butanolate 作用下， 以 甲苯 为溶剂， 反应 48.0h， 生成 4-N,4-N-bis[4-[4-[(E)-2-[4-(dibutylamino)phenyl]ethenyl]-N-[4-[(E)-2-[4-(dibutylamino)phenyl]ethenyl]phenyl]anilino]phenyl]-1-N,1-N-bis[4-[(E)-2-[4-(dibutylamino)phenyl]ethenyl]phenyl]benzene-1,4-diamine
  参考文献：
  名称：

  Synthesis of Triphenylamine-Cored Dendritic Two-Photon Absorbing Chromophores

  摘要：

  A new series of dendritic two-photon absorbing chromophores containing triphenylamine moiety as a core or branching points have been synthesized through a convergent synthetic strategy. One-photon and two-photon optical properties of these molecules were characterized. In the nanosecond time domain, these molecules exhibited large two-photon absorption (TPA) cross sections up to 7.56-12.2 X 10(-44) S cm(4) at 800 nm, indicating that these molecular structures were viable candidates for various two-photon related applications.

  DOI：

  10.1021/ol050905n
• 作为产物：
  描述：

  N,N-bis-(4-bromophenyl)benzamide 在 palladium diacetate 氢氧化钾 、 三乙胺 、 三(邻甲基苯基)磷 作用下， 以 四氢呋喃 、 甲醇 、 水 、 N,N-二甲基甲酰胺 为溶剂， 反应 84.0h， 生成 (E,E)-bis(4-(2-(4-N,N-dibutylaminophenyl)ethenyl)phenyl)amine
  参考文献：
  名称：

  Synthesis of Triphenylamine-Cored Dendritic Two-Photon Absorbing Chromophores

  摘要：

  A new series of dendritic two-photon absorbing chromophores containing triphenylamine moiety as a core or branching points have been synthesized through a convergent synthetic strategy. One-photon and two-photon optical properties of these molecules were characterized. In the nanosecond time domain, these molecules exhibited large two-photon absorption (TPA) cross sections up to 7.56-12.2 X 10(-44) S cm(4) at 800 nm, indicating that these molecular structures were viable candidates for various two-photon related applications.

  DOI：

  10.1021/ol050905n

文献信息

• Synthesis of Triphenylamine-Cored Dendritic Two-Photon Absorbing Chromophores
  作者：Peng Wei、Xiangdong Bi、Zhe Wu、Zhi Xu

  DOI：10.1021/ol050905n

  日期：2005.7.1

  A new series of dendritic two-photon absorbing chromophores containing triphenylamine moiety as a core or branching points have been synthesized through a convergent synthetic strategy. One-photon and two-photon optical properties of these molecules were characterized. In the nanosecond time domain, these molecules exhibited large two-photon absorption (TPA) cross sections up to 7.56-12.2 X 10(-44) S cm(4) at 800 nm, indicating that these molecular structures were viable candidates for various two-photon related applications.