2-乙基-6-苯基苯酚 | 374936-02-4

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 中文名称: 2-乙基-6-苯基苯酚
• 英文名称: 3-ethyl[1,1'-biphenyl]-2-ol
• 英文别名: 2-ethyl-6-phenylphenol
• CAS: 374936-02-4
• 化学式: C₁₄H₁₄O
• 分子量: 198.265
• InChiKey: ADHVILAGEGKWDE-UHFFFAOYSA-N

物化性质

• 沸点：
  155-160 °C(Press: 8 Torr)
• 密度：
  1.066±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  4
• 重原子数：
  15
• 可旋转键数：
  2
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.14
• 拓扑面积：
  20.2
• 氢给体数：
  1
• 氢受体数：
  1

反应信息

• 作为产物：
  描述：

  碘苯 在 chloro(1,5-cyclooctadiene)rhodium(I) dimer 、 间氯过氧苯甲酸 、 lithium tert-butoxide 、 三(二甲胺基)膦 作用下， 以 二氯甲烷 、 乙腈 为溶剂， 反应 14.0h， 生成 2-乙基-6-苯基苯酚
  参考文献：
  名称：

  P(NMe2)3-promoted ortho-selective arylation of phenols with diaryliodonium triflates via rhodium catalysis

  摘要：

  Rh-catalyzed ortho-selective arylation of free phenol with diaryliodonium triflates to widely existed phenol-containing biaryls have been developed. The use of P(NMe2)(3), (BuOLi)-Bu-t and CH3CN proved to be critical for the ortho-selectivity of this reaction. (C) 2017 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tet.2017.03.055

文献信息

• BISPHENOL COMPOUND AND AROMATIC POLYCARBONATE
  申请人：Honshu Chemical Industry Co., Ltd.

  公开号：US20190047954A1

  公开（公告）日：2019-02-14

  The present invention addresses the problem of providing; a novel bisphenol compound having an indoline skeleton; and a novel aromatic polycarbonate which uses this bisphenol compound as a starting material dihydroxy compound. The above-described problem is able to be solved by an aromatic polycarbonate that contains a repeating unit represented by general formula (2).

  本发明解决了提供具有吲哚骨架的新型双酚化合物和使用该双酚化合物作为起始材料二羟基化合物的新型芳香族聚碳酸酯的问题。上述问题可以通过含有通式（2）所表示的重复单元的芳香族聚碳酸酯来解决。
• Method for producing water soluble resols and use therefor
  申请人：GENERAL ELECTRIC COMPANY

  公开号：EP0113037A2

  公开（公告）日：1984-07-11

  The effluent stream from a process for producing phenolic compounds is reacted with an aldehyde in the presence of a base to form a water soluble resol which is useful in enhanced oil recovery.

  酚类化合物生产过程中产生的废液在有碱存在的情况下与醛发生反应，生成一种水溶性溶胶，这种溶胶可用于提高石油采收率。
• 2-, 3- And 4-biphenyloxyaminoalkanes and related compounds, their preparation and uses, and pharmaceutical compositions containing them
  申请人：SYNTEX (U.S.A.) INC.

  公开号：EP0157652A1

  公开（公告）日：1985-10-09

  Compounds useful for treating inflammation, swelling and associated pain, and psoriasis, represented by the formula: and the pharmaceutically acceptable acid addition salts thereof, wherein: a is an integer of 0-3; b is an integer of 0-2; n is an integer of 3-12; each X and each Y are independently-halo, -R1, -alkoxy, or-phenyl; and B is selected from: and in which R' and R2 are independently H, alkyl or cycloalkyl; R3 is H, alkyl or -CH2CH2OH; and m is an integer of 3-8. Novel compounds are those wherein n is at least 6 if both a and b are 0.

  用于治疗炎症、肿胀及相关疼痛和牛皮癣的化合物，由式：及其药学上可接受的酸加成盐表示，其中：a 是 0-3 的整数；b 是 0-2 的整数；n 是 3-12 的整数；每个 X 和每个 Y 独立地是卤素、-R1、-烷氧基或苯基；B 选自：且其中 R' 和 R2 独立地是 H、烷基或环烷基；R3 是 H、烷基或-CH2CH2OH；且 m 是 3-8 的整数。 新型化合物是指如果 a 和 b 均为 0，则 n 至少为 6 的化合物。
• POLY(ARYLENE ETHER) COPOLYMER, METHOD TO PREPARE THE SAME, AND ARTICLE DERIVED THEREFROM
  申请人：SHPP Global Technologies B.V.

  公开号：EP3919544A1

  公开（公告）日：2021-12-08

  A capped poly(arylene ether) copolymer includes a reactive end group, wherein the capped poly(arylene ether) copolymer is derived from an alkyl, aryl-phenol.

  一种封端聚（芳基醚）共聚物包括一个活性端基，其中封端聚（芳基醚）共聚物由烷基、芳基-苯酚衍生而来。
• CURABLE THERMOSETTING COMPOSITION INCLUDING POLY(ARYLENE ETHER) COPOLYMER
  申请人：SHPP Global Technologies B.V.

  公开号：EP3919545A1

  公开（公告）日：2021-12-08

  A curable thermosetting composition, comprising a capped poly(arylene ether) copolymer comprising a reactive end group, wherein the capped poly(arylene ether) copolymer is derived from an alkyl, aryl-phenol.

  一种可固化的热固性组合物，包含一种由活性末端基团组成的封端的聚（芳基醚）共聚物，其中封端的聚（芳基醚）共聚物由烷基、芳基-苯酚衍生而来。