1,3,5-tris[(9-anthrylmethoxy)methyl]benzene | 287917-03-7

• 分子结构分类: 有机化合物 - 苯类化合物 - 蒽
• 英文名称: 1,3,5-tris[(9-anthrylmethoxy)methyl]benzene
• 英文别名: 9-[[3,5-Bis(anthracen-9-ylmethoxymethyl)phenyl]methoxymethyl]anthracene
• CAS: 287917-03-7
• 化学式: C₅₄H₄₂O₃
• 分子量: 738.926
• InChiKey: WKYLCARTDQZHGY-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  12.9
• 重原子数：
  57
• 可旋转键数：
  12
• 环数：
  10.0
• sp3杂化的碳原子比例：
  0.11
• 拓扑面积：
  27.7
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  马来酰亚胺 、 1,3,5-tris[(9-anthrylmethoxy)methyl]benzene 以 甲苯 为溶剂， 以94%的产率得到1-[[3,5-Bis[(16,18-dioxo-17-azapentacyclo[6.6.5.02,7.09,14.015,19]nonadeca-2,4,6,9,11,13-hexaen-1-yl)methoxymethyl]phenyl]methoxymethyl]-17-azapentacyclo[6.6.5.02,7.09,14.015,19]nonadeca-2,4,6,9,11,13-hexaene-16,18-dione
  参考文献：
  名称：

  High-Yield Formation of Giant Bis(bicyclic) and Crypt-tris(bicyclic) Molecules under Normal Reaction Conditions

  摘要：

  We report the unexpected result of the reaction of 1,3-bis[(9-anthrylmethoxy)methyl]benzene (1a) or 1,3,5 -tris [(9-anthrylmethoxy)methyl]benzene (1b) with tris(2-maleimidoethyl)amine (2) in homogeneous solution leading to giant bis(bicyclic) and crypt-tris(bicyclic) molecules. The anticipated, intractable solids are obtained in a condensed state reaction using an oscillating mill.

  DOI：

  10.1021/jo991783d
• 作为产物：
  描述：

  1,3,5-三(溴甲基)苯 、 9-蒽醇 在 sodium hydride 作用下， 以 N,N-二甲基甲酰胺 为溶剂， 以48%的产率得到1,3,5-tris[(9-anthrylmethoxy)methyl]benzene
  参考文献：
  名称：

  High-Yield Formation of Giant Bis(bicyclic) and Crypt-tris(bicyclic) Molecules under Normal Reaction Conditions

  摘要：

  We report the unexpected result of the reaction of 1,3-bis[(9-anthrylmethoxy)methyl]benzene (1a) or 1,3,5 -tris [(9-anthrylmethoxy)methyl]benzene (1b) with tris(2-maleimidoethyl)amine (2) in homogeneous solution leading to giant bis(bicyclic) and crypt-tris(bicyclic) molecules. The anticipated, intractable solids are obtained in a condensed state reaction using an oscillating mill.

  DOI：

  10.1021/jo991783d

文献信息

• High-Yield Formation of Giant Bis(bicyclic) and Crypt-tris(bicyclic) Molecules under Normal Reaction Conditions
  作者：Matheus Adrianus Dam、Amir Weitz、Roger Helgeson、Bin Ma、Fred Wudl

  DOI：10.1021/jo991783d

  日期：2000.6.1

  We report the unexpected result of the reaction of 1,3-bis[(9-anthrylmethoxy)methyl]benzene (1a) or 1,3,5 -tris [(9-anthrylmethoxy)methyl]benzene (1b) with tris(2-maleimidoethyl)amine (2) in homogeneous solution leading to giant bis(bicyclic) and crypt-tris(bicyclic) molecules. The anticipated, intractable solids are obtained in a condensed state reaction using an oscillating mill.