dodec-2c-enedioic acid | 6556-35-0

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 脂肪酰基
• 英文名称: dodec-2c-enedioic acid
• 英文别名: Dodec-2c-endisaeure；cis-Traumatinsaeure；(Z)-2-dodecenedioic acid；cis-2-Dodecen-1,12-disaeure；Traumatic acid, (2Z)-；(Z)-dodec-2-enedioic acid
• CAS: 6556-35-0
• 化学式: C₁₂H₂₀O₄
• 分子量: 228.288
• InChiKey: MAZWDMBCPDUFDJ-CLFYSBASSA-N

物化性质

• 熔点：
  67-68 °C
• 沸点：
  376.4±15.0 °C(Predicted)
• 密度：
  1.089±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  3
• 重原子数：
  16
• 可旋转键数：
  10
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.67
• 拓扑面积：
  74.6
• 氢给体数：
  2
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  dodec-2c-enedioic acid 生成 dodec-2c-enedioic acid bis-(4-phenyl-phenacyl ester)
  参考文献：
  名称：

  Lauer; Gensler, Journal of the American Chemical Society, 1945, vol. 67, p. 1174

  摘要：

  DOI：
• 作为产物：
  描述：

  10-烯酸甲酯 在 氢氧化钾 、 过氧化苯甲酰 作用下， 生成 dodec-2c-enedioic acid
  参考文献：
  名称：

  Dolezal,S., Collection of Czechoslovak Chemical Communications, 1966, vol. 31, p. 3765 - 3774

  摘要：

  DOI：

文献信息

• Composition suitable for making plastic articles, method for making said composition and cured articles thereof
  申请人：PHILLIPS PETROLEUM COMPANY

  公开号：EP0004369A2

  公开（公告）日：1979-10-03

  mixture of a carboxylic acid and an alkali metal carboxylate group-containing rubber in a vinyl monomer is provided. The resulting composition has a relatively low viscosity and is particularly adapted for preparing a thermosettable composition suitable for preparing reinforced plastic articles by combining an unsaturated polyester, the alkali metal carboxylate-containing rubber solution containing the carboxylic acid, a catalyst, and a reinforcing agent. The resulting composition when cured exhibits high impact strength and good surface finish.

  提供了一种羧酸和含碱金属羧酸基橡胶在乙烯基单体中的混合物。所得组合物的粘度相对较低，特别适用于通过将不饱和聚酯、含羧酸的碱金属羧酸基橡胶溶液、催化剂和补强剂组合在一起，制备适用于制备补强塑料制品的热固性组合物。固化后的组合物具有很高的冲击强度和良好的表面光洁度。
• PROCÉDÉS DE SYNTHÈSE DE DIACIDES GRAS PAR MÉTATHÈSE DE DIACIDES INSATURÉS OBTENUS PAR FERMENTATION D'ACIDES GRAS NATURELS
  申请人：ARKEMA FRANCE

  公开号：EP2191003B1

  公开（公告）日：2015-06-03
• METHODS FOR THE SYNTHESIS OF FATTY DIACIDS BY THE METATHESIS OF UNSATURATED DIACIDS OBTAINED BY FERMENTATION OF NATURAL FATTY ACIDS
  申请人：Dubois Jean-Luc

  公开号：US20100196973A1

  公开（公告）日：2010-08-05

  The invention relates to a method for the synthesis of diacids of general formula ROOC—(CH 2 ) n —(CH═CH) n —(CH 2 ) m COOR 1 in which n and m are identical or different and each represent an integer such that their sum is between 6 and 15, a is an index of 0 or 1, and R and R 1 are H or an alkyl radical with 1 to 4 carbon atoms, from long-chain mono-unsaturated natural fatty acids or esters having at least 10 adjacent carbon atoms per molecule of the general formula CH 3 —(CH 2 ) p —CH═CH—(CH 2 ) q —COOR, p and q, being identical or different and representing indices between 2 and 11, wherein said method comprises the first step of oxidizing by fermentation said natural fatty acid or ester, using a microorganism, such as a bacterium, a yeast, or a fungus, into at least one unsaturated dicarboxylic acid or dicarboxylate, the second step of submitting the product from the first step to a metathesis crossed with a compound of formula R 2 OOC—(CH 2 ) x —CH═CH—R 3 , in which R 2 is H or an alkyl radical with 1 to 4 carbon atoms, x is 0 or 1 or 2, and R 3 is H, CH 3 or COOR 2 , in order to obtain the unsaturated compound of formula ROOC—(CH 2 ) q —CH═CH—(CH 2 ) x —COOR 2 , and the third optional step of converting the unsaturated compound into a saturated compound by hydrogenation of the double bond,.
• US4020036A
  申请人：——

  公开号：US4020036A

  公开（公告）日：1977-04-26
• US4158654A
  申请人：——

  公开号：US4158654A

  公开（公告）日：1979-06-19