Cyclobutan-1,1,2-tricarbonsaeure | 2144-31-2

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• 英文名称: Cyclobutan-1,1,2-tricarbonsaeure
• 英文别名: Cyclobutan-tricarbonsaeure-(1,1,2)；cyclobutane-1,1,2-tricarboxylic acid；1,1,2-Cyclobutanetricarboxylicacid
• CAS: 2144-31-2
• 化学式: C₇H₈O₆
• mdl: MFCD20638730
• 分子量: 188.137
• InChiKey: CMLOVBIZVAKNJA-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  -0.6
• 重原子数：
  13
• 可旋转键数：
  3
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.571
• 拓扑面积：
  112
• 氢给体数：
  3
• 氢受体数：
  6

反应信息

• 作为反应物：
  描述：

  Cyclobutan-1,1,2-tricarbonsaeure 180.0 ℃ 、2.67 kPa 条件下， 生成 cis-1,2-cyclobutane dicarboxylic anhydride
  参考文献：
  名称：

  Cyclobutane Derivatives. I.¹ The Degradation of cis- and trans-1,2-Cyclobutane-dicarboxylic Acids to the Corresponding Diamines

  摘要：

  DOI：

  10.1021/ja01263a048
• 作为产物：
  描述：

  dimethyl 1-cyanocyclobutane-1,2-dicarboxylate 在 盐酸 作用下， 反应 12.0h， 生成 Cyclobutan-1,1,2-tricarbonsaeure
  参考文献：
  名称：

  The synthesis and use in asymmetric epoxidation of metal salen complexes derived from enantiopure trans-cyclopentane- and cyclobutane-1,2-diamine

  摘要：

  A complete synthesis of enantiopure trans-cyclopentane-1,2-diamine and trans-cyclobutane-1,2-diamine is described. These diamines have been used as components of novel chiral salen ligands whose chromium and manganese complexes were then evaluated as oxygen transfer agents in the asymmetric epoxidation of alkenes. (C) 2003 Elsevier Science Ltd. All rights reserved.

  DOI：

  10.1016/s0957-4166(02)00757-7

文献信息

• Interfacially synthesized reverse osmosis membranes and processes for preparing the same
  申请人：HYDRANAUTICS

  公开号：EP0527348A1

  公开（公告）日：1993-02-17

  Water permeable reverse osmosis membranes are prepared by interfacially polymerizing on a microporous support an essentially monomeric polyamine reactant having at least two amine functional groups per reactant molecule, and an essentially monomeric amine-reactive polyfunctional single ring cycloaliphatic acyl halide having fewer than six carbon atoms per ring and having on the average at least about 2.2 acyl halide groups per reactant molecule. The polymerization is preferably carried out in the presence of a monomeric amine salt, which increases the flux rate of the resulting membrane. In addition, an aromatic polyfunctional acyl halide may be used in conjunction with the cycloaliphatic acyl halide in order to increase salt rejection rates. Preferred cycloaliphatic acyl halides are 1-cis, 2-trans, 3-cis, 4-trans-cyclopentane tetracarboxylic acid chloride, 1-cis, 2-trans, 3-cis, 4-trans-cyclobutane tetracarboxylic acid chloride and 1-cis, 2-trans, 4-cis-cyclopentane tricarboxylic acid chloride. The preparation of novel alternating cis/trans isomers of cycloaliphatic polycarboxylic acid halides is carried out using metal salts of the all-cis polycarboxylic acids.

  透水反渗透膜的制备方法是在微孔支撑体上界面聚合基本上是单体的多胺反应物（每个反应物分子至少有两个胺官能团）和基本上是单体的胺反应性多官能团单环脂族酰卤，每个环的碳原子数少于六个，每个反应物分子平均至少有大约 2.2 个酰卤基团。聚合反应最好在有单体胺盐存在的情况下进行，这样可以提高所得膜的通量。此外，芳香族多官能酰卤可与环脂族酰卤一起使用，以提高盐排斥率。优选的环脂族酰卤有 1-顺式、2-反式、3-顺式、4-反式环戊烷四羧酰氯，1-顺式、2-反式、3-顺式、4-反式环丁烷四羧酰氯和 1-顺式、2-反式、4-顺式环戊烷三羧酰氯。利用全顺式多羧酸的金属盐，可以制备新型环脂族多羧酸卤化物的顺式/反式交替异构体。
• Interfacially polymerized, bipiperidine-polyamide membranes for reverse osmosis and/or nanofiltration and process for making the same
  申请人：HYDRANAUTICS

  公开号：EP1060785A1

  公开（公告）日：2000-12-20

  Selective, water-permeable membranes for reverse osmosis and nanofiltration are prepared by interfacially polymerizing on a microporous support an essentially monomeric bipiperidine reactant, and an essentially monomeric amine-reactive polyfunctional aromatic or cycloaliphatic acyl halide having on the average at least about 2 acyl halide groups per reactant molecule. The polymerization is optionally carried out in the presence of a monomeric amine salt, which can increase the flux rate of the resulting membrane.

  用于反渗透和纳滤的选择性透水膜的制备方法是在微孔载体上将基本上是单体的双哌啶反应物和基本上是单体的胺反应性多官能团芳香族或环脂族酰基卤进行界面聚合，每个反应物分子平均至少具有约 2 个酰基卤基团。聚合可选择在有单体胺盐存在的情况下进行，这样可以提高所得膜的通量。
• NUCLEIC ACID DETECTION METHOD
  申请人：Toray Industries, Inc.

  公开号：EP3546590A1

  公开（公告）日：2019-10-02

  A method of detecting a nucleic acid, comprising the following steps of: a) mixing a solution containing a carboxylic acid and/or a salt thereof, a cerium oxide support and a sample containing a nucleic acid to adsorb the nucleic acid to the cerium oxide support, b) separating the cerium oxide support on which the nucleic acid was adsorbed from the mixture obtained in the step a), c) collecting the nucleic acid by adding an eluent to the cerium oxide support on which the nucleic acid was adsorbed and which was separated in the step b), and d) detecting the nucleic acid collected in the step c) by a hybridization reaction or a nucleic acid amplification reaction.

  一种检测核酸的方法，包括以下步骤： a) 将含有羧酸和/或羧酸盐的溶液、氧化铈载体和含有核酸的样品混合，使核酸吸附在氧化铈载体上、 b) 从步骤 a) 中得到的混合物中分离出吸附了核酸的氧化铈载体、 c) 向步骤 b) 中分离的吸附了核酸的氧化铈载体上添加洗脱液，收集核酸，以及 d) 通过杂交反应或核酸扩增反应检测步骤 c) 中收集的核酸。
• RESIN COMPOSITION, RESIN SHEET, MULTILAYER PRINTED WIRING BOARD, AND SEMICONDUCTOR DEVICE
  申请人：MITSUBISHI GAS CHEMICAL COMPANY, INC.

  公开号：EP3916025A1

  公开（公告）日：2021-12-01

  The resin composition of the present invention is a resin composition containing: a bismaleimide compound (A) containing a constituent unit represented by the following formula (1) and maleimide groups at both ends of the molecular chain; a compound (B) containing one or more carboxy groups; and a photo initiator (C). In the formula (1), R1 represents a linear or branched alkylene group having 1 to 16 carbon atoms, or a linear or branched alkenylene group having 2 to 16 carbon atoms. R2 represents a linear or branched alkylene group having 1 to 16 carbon atoms, or a linear or branched alkenylene group having 2 to 16 carbon atoms. Each R3 independently represents a hydrogen atom, a linear or branched alkyl group having 1 to 16 carbon atoms, or a linear or branched alkenyl group having 2 to 16 carbon atoms. Each n independently represents an integer of 1 to 10.

  本发明的树脂组合物是一种含有以下成分的树脂组合物：双马来酰亚胺化合物（A），其组成单元由下式（1）表示，分子链两端含有马来酰亚胺基团；化合物（B），含有一个或多个羧基；以及光引发剂（C）。 在式 (1) 中，R1 代表具有 1 至 16 个碳原子的直链或支链亚烷基，或具有 2 至 16 个碳原子的直链或支链烯基。R2 代表具有 1 至 16 个碳原子的直链或支链亚烷基，或具有 2 至 16 个碳原子的直链或支链烯基。每个 R3 独立地代表氢原子、具有 1 至 16 个碳原子的直链或支链烷基或具有 2 至 16 个碳原子的直链或支链烯基。每个 n 独立地代表 1 至 10 的整数。
• Binder composition for secondary battery
  申请人：NEC Corporation

  公开号：US11018342B2

  公开（公告）日：2021-05-25

  A purpose of the present invention is to provide a binder composition for a secondary battery which improves the charge and discharge efficiency and the cycle characteristics of a battery. The binder composition for a secondary battery of the present invention is characterized by comprising a polyamide-imide comprising a repeating unit represented by chemical formula (1) or a precursor thereof, wherein A is a trivalent group obtained by removing carboxyl groups from a tricarboxylic acid, B is a divalent group obtained by removing amino groups from a diamine, and at least one of A and B is an aliphatic group.

  本发明的目的是提供一种用于二次电池的粘结剂组合物，它能提高电池的充放电效率和循环特性。本发明的二次电池粘结剂组合物的特点是由聚酰胺-酰亚胺组成，该聚酰胺-酰亚胺包括由化学式（1）表示的重复单元或其前体、 其中 A 是通过去除三羧酸中的羧基而得到的三价基团，B 是通过去除二胺中的氨基而得到的二价基团，A 和 B 中至少有一个是脂肪族基团。