3,6,9,12-tetrathiatetradecane | 40195-99-1

• 分子结构分类: 有机化合物 - 有机硫化合物 - 硫醚类
• 英文名称: 3,6,9,12-tetrathiatetradecane
• 英文别名: 1,2-bis-(2-ethylsulfanyl-ethylsulfanyl)-ethane；1,2-Bis-(2-aethylmercapto-aethylmercapto)-aethan；1-Ethylsulfanyl-2-[2-(2-ethylsulfanylethylsulfanyl)ethylsulfanyl]ethane
• CAS: 40195-99-1
• 化学式: C₁₀H₂₂S₄
• 分子量: 270.549
• InChiKey: YLAZLRIUONOQJD-UHFFFAOYSA-N

物化性质

• 沸点：
  409.1±25.0 °C(Predicted)
• 密度：
  1.084±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  3.6
• 重原子数：
  14
• 可旋转键数：
  11
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  101
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  potassium pertechnetate 、 3,6,9,12-tetrathiatetradecane 、 苯硫酚 在 SnCl₂ 、 KPF₆ 作用下， 以 盐酸 为溶剂， 以47%的产率得到bis(benzenethiolato)(3,6,9,12-tetrathiatetradecane)technetium(III)hexafluorophosphate
  参考文献：
  名称：

  Technetium complexes with thioether ligands—I. Cationic technetium(III) complexes containing tetradentate thioether/monothiole ligands; X-ray structure analysis of bis(benzenethiolato)(5,8,11,14-tetrathiaoctadecane)technetium(III)hexafluorophosphate

  摘要：

  Cationic technetium(III) complexes containing both tetradentate thioether and monothioles, [Tc(''S4'')(SR)2]PF6 (''S4'': 3,6,9,12-tetrathiatetradecane, 5,8,11,14-tetrathiaoctadecane; SR : monodentate thiolates), were prepared starting from TcO4- and characterized by elemental analysis and spectroscopic methods. Bis(benzenethiolato)(5,8,11,14-tetrathiaoctadecane)technetium(III)hexafluorophosphate was characterized by single-crystal X-ray structural analysis (R = 0.084). In the complex the technetium is centred in a heavily distorted octahedron. The benzenethiolate ligands are coordinated in the cis-configuration.

  DOI：

  10.1016/s0277-5387(00)83716-x
• 作为产物：
  描述：

  1-chloro-3,6-dithiaoctane 、 alkaline earth salt of/the/ methylsulfuric acid 在 甲醇 作用下， 生成 3,6,9,12-tetrathiatetradecane
  参考文献：
  名称：

  Feher; Vogelbruch, Chemische Berichte, 1958, vol. 91, p. 996,1001

  摘要：

  DOI：

文献信息

• Resin composition for laser engraving, image forming material, relief printing plate precursor for laser engraving. relief printing plate, and method of producing relief printing plate
  申请人：FUJIFILM Corporation

  公开号：EP2145765A1

  公开（公告）日：2010-01-20

  A resin composition for laser engraving, including: a binder polymer; and a metal compound containing a metal selected from the group consisting of metals in Group 1 to Group 15 in the periodic table.

  一种用于激光雕刻的树脂组合物，包括：一种粘合剂聚合物；以及一种金属化合物，其中含有一种选自元素周期表中第 1 族至第 15 族金属的金属。
• Myokardgängige Technetium-Komplexverbindungen und Verfahren zu deren Herstellung
  申请人：Forschungszentrum Rossendorf e.V.

  公开号：EP0439871B1

  公开（公告）日：1995-05-31
• RESIN COMPOSITION FOR LASER ENGRAVING, IMAGE FORMING MATERIAL, RELIEF PRINTING PLATE PRECURSOR FOR LASER ENGRAVING, RELIEF PRINTING PLATE, AND METHOD OF MANUFACTURING RELIEF PRINTING PLATE
  申请人：KAWASHIMA Takashi

  公开号：US20090246469A1

  公开（公告）日：2009-10-01

  The invention provides a resin composition for laser engraving, containing at least (A) a polymerizable compound having two or more ethylenic unsaturated bonds, a carbon-sulfur bond being contained at the site where two among the two or more ethylenic unsaturated bonds are connected and (B) a binder polymer. The invention further provides an image forming material containing the resin composition, a relief printing plate precursor having a relief forming layer which contains the resin composition, a relief printing plate precursor having a relief forming layer which contains a product formed by subjecting the resin composition to cross-linking, a method for manufacturing a relief printing plate including subjecting the relief printing plate precursor having the relief forming layer which contains the resin composition to cross-linking, and a relief printing plate manufactured by the manufacturing method.
• RESIN COMPOSITION FOR LASER ENGRAVING, IMAGE FORMING MATERIAL, RELIEF PRINTING PLATE PRECURSOR FOR LASER ENGRAVING, RELIEF PRINTING PLATE, AND METHOD OF PRODUCING RELIEF PRINTING PLATE
  申请人：KAWASHIMA Takashi

  公开号：US20100015416A1

  公开（公告）日：2010-01-21

  A resin composition for laser engraving, including: a binder polymer; and a metal compound containing a metal selected from the group consisting of metals in Group 1 to Group 15 in the periodic table.
• US8278387B2
  申请人：——

  公开号：US8278387B2

  公开（公告）日：2012-10-02