(3-fluorobut-1-en-2-yl)benzene | 1144522-18-8

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: (3-fluorobut-1-en-2-yl)benzene
• 英文别名: 3-Fluorobut-1-en-2-ylbenzene；3-fluorobut-1-en-2-ylbenzene
• CAS: 1144522-18-8
• 化学式: C₁₀H₁₁F
• 分子量: 150.196
• InChiKey: WKRVWGQUUMJCBC-UHFFFAOYSA-N

物化性质

• 沸点：
  207.7±19.0 °C(predicted)
• 密度：
  0.953±0.06 g/cm3(Temp: 20 °C; Press: 760 Torr)(predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  3.5
• 重原子数：
  11
• 可旋转键数：
  2
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.2
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为产物：
  描述：

  2-苯-2-丁烯 在 Selectfluor 作用下， 以 N,N-二甲基甲酰胺 为溶剂， 反应 4.0h， 以67%的产率得到(3-fluorobut-1-en-2-yl)benzene
  参考文献：
  名称：

  Synthesis of aryl allylic fluorides by direct electrophilic fluorination of alkenes

  摘要：

  Aryl allylic fluorides were synthesized in 47-83% yields by using Selectfluor as the electrophilic reagent in DMF. The outcome of this reaction may be explained by electronic effects while the reactivity was controlled by the stabilization effect of the aryl group on the benzylic cationic intermediates. (C) 2009 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tetlet.2009.01.052

文献信息

• Synthesis of aryl allylic fluorides by direct electrophilic fluorination of alkenes
  作者：Hai-Qing Luo、Teck-Peng Loh

  DOI：10.1016/j.tetlet.2009.01.052

  日期：2009.4

  Aryl allylic fluorides were synthesized in 47-83% yields by using Selectfluor as the electrophilic reagent in DMF. The outcome of this reaction may be explained by electronic effects while the reactivity was controlled by the stabilization effect of the aryl group on the benzylic cationic intermediates. (C) 2009 Elsevier Ltd. All rights reserved.