(CyNH-o-C6H4)2O | 245093-30-5

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: (CyNH-o-C6H4)2O
• 英文别名: N-cyclohexyl-2-[2-(cyclohexylamino)phenoxy]aniline
• CAS: 245093-30-5
• 化学式: C₂₄H₃₂N₂O
• 分子量: 364.531
• InChiKey: YMKUNQVKWOOQRM-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  7
• 重原子数：
  27
• 可旋转键数：
  6
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.5
• 拓扑面积：
  33.3
• 氢给体数：
  2
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  (CyNH-o-C6H4)2O 以 甲苯 为溶剂， 生成
  参考文献：
  名称：

  含有三齿二氨基配体的钛和锆配合物 [(i-PrN-o-C6H4)2O]2-([i-PrNON]2-) 和 [(C6H11N-o-C6H4)2O]2-([CyNON] 2-)

  摘要：

  已经制备了多种含有[(i-PrN-o-C6H4)2O]2-([i-PrNON]2-)配体的五配位和六配位钛和锆二烷基配合物，其中[i- PrNON]Ti(CH2CHMe2)2、[i-PrNON]Ti(CH2CMe3)2、[i-PrNON]Zr(CH2CH3)2 和 [i-PrNON]Zr(CH2CHMe2)2。这些物质作为复合物的来源，例如 {[i-PrNON]Ti(PMe3)2}2(μ-N2)、[i-PrNON]Ti(CHCMe3)(PMe3)2、[i-PrNON]Zr(CH2CHMe2) )2(PMe3) 和 [i-PrNON]Zr(H2CCMe2)(PMe3)2。[i-PrNON]Ti(CH2CMe3)2 和 Me2PCH2CH2PMe2 在不存在二氮的情况下反应生成 (i-PrNC6H4)(i-PrNC6H4O)Ti(dmpe)，一种假八面体物质，其中一个芳基-氧键已被裂解。在[i

  DOI：

  10.1021/ja983549v
• 作为产物：
  描述：

  2-氨基苯基醚 、 环己酮 在 溶剂黄146 、 锌 作用下， 生成 (CyNH-o-C6H4)2O
  参考文献：
  名称：

  NON型二酰胺基醚三齿配体支持的定义明确的阴离子型烷氧基铝铝配合物的合成，结构表征及其在丙交酯的受控ROP中的用途†

  摘要：

  三齿配体（RNH- o -C 6 H 4）2 O（1a，R = C 5 H 9 ; 1b，R =半胱氨酸）被发现容易地与反应的LiAlH 4，得到相应的锂铝dihydrido盐物质[η 2 - Ñ，ñ - {（RN- ö -C 6 ħ 4）2 ö}的AlH（μ-H）的Li（THF） ] 2（2a，R = C 5 H 9 ; 2b，R =半胱氨酸）分别以50％和42％的收率。配合物2a和2b的固态结构通过X射线晶体学研究确定。化合物2a和2b容易与一当量的苯甲醛 负担相应的费用 一苄氧基物种η 2 - Ñ，ñ - {RN- ö -C 6 ħ 4）2 ö}的Al（H）（μ -OCH 2 PH）的Li（THF）2（图4a，R = C 4 H ^ 9 ;图4b，R =半胱氨酸），如4b的X射线研究所证实。以类似的方式，当化合物2a和2b与两当量的苯甲醛反应时，双苄氧基衍生物图5a和图5b η 3 -

  DOI：

  10.1039/b911802k

文献信息

• Synthesis and Structural Characterization of Various N,O,N-Chelated Aluminum and Gallium Complexes for the Efficient ROP of Cyclic Esters and Carbonates: How Do Aluminum and Gallium Derivatives Compare ?
  作者：Frédéric Hild、Nirvana Neehaul、Frédéric Bier、Morgane Wirsum、Christophe Gourlaouen、Samuel Dagorne

  DOI：10.1021/om3011068

  日期：2013.1.28

  novel Al and Ga coordination compounds 4, 5, 7, and 8 of the type (NON)AlX (NON2– = RNC6H4}2O2–; 4, R = Cy, X = Me; 5, R = C5H9, X = OCH2Ph; 7, R = C6F5, X = Me) and (NON)GaX (NON2– = R2NHC6H4}2O2–; 8, R = C6F5, X = Me) have been synthesized via, in the case of 4, 7, and 8, a methane elimination reaction between the corresponding protio ligands (NON)H2 and MMe3 precursors (M = Al, Ga). The Al alkoxide

  新颖的Al和Ga配位化合物4，5，7，和8的类型的（NON）ALX（NON 2- = RNC 6 ħ 4 } 2 ö 2- ; 4，R = CY，X =甲基; 5， R = C 5 H 9，X = OCH 2 Ph；7，R = C 6 F 5，X = Me）和（NON）GaX（NON 2– = R 2 NHC 6 H 4 } 2 O 2– ; 8，R = C6 ˚F 5，X = Me）的已通过被合成，在的情况下4，7，和8，相应的protio配体之间的甲烷消除反应（NON）H 2和MME 3个前体（M =铝，镓）。所述Al烷氧化物衍生物5经醇解反应制得之间κ 3 - ñ，ö，Ñ （C - 5 ħ 9）NC 6 H ^ 4 } 2 ö} 2 AlNMe 2和物理信道2哦。四配位的Al-THF加合物κ 2 - Ñ，N' - （C 5 H ^ 9）NC 6 H ^ 4 } 2 ö} 2的
• Novel N,O,N-Supported Tetracoordinate Aluminum Complexes for the Highly Controlled and Immortal ROP of Trimethylene Carbonate (TMC) under Mild Conditions: Access to Narrowly Disperse poly-TMC and Derived Copolymers
  作者：Frédéric Hild、Lydia Brelot、Samuel Dagorne

  DOI：10.1021/om200703d

  日期：2011.10.24

  The novel N,O,N-supported tetracoordinate amidoaluminum complexes eta(3)(N,O,N}-(C5H9)N-C6H4}(2)O-AlNMe2 (2a, R = C5H9; 2b, R = C6H(11)) have been synthesized and structurally characterized. In the solid state, as determined from X-ray crystallographic studies, complex 2a consists of a four-coordinate Al species in which the Al center adopts a distorted-trigonal-monopyramidal (tmp) geometry with the nitrogens of the three amido groups (defining the pyramidal base) being nearly coplanar with Al. Such Al species, when combined with an alcohol source such as benzyl alcohol, effectively polymerize trimethylene carbonate (TMC) at room temperature in a highly controlled manner to yield narrowly disperse poly(trimethylene carbonate), as deduced from polymer characterizations with various kinetic studies. The high degree of molecular chain length control of the present system was further exploited to access narrowly dispersed PEG-functionalized amphiphilic copolymers. The attractive features of the system lie in the combination of an excellent activity, a high level of chain length control, and mild reaction conditions.
• Titanium and Zirconium Complexes That Contain the Tridentate Diamido Ligands [(<i>i</i>-PrN-<i>o</i>-C₆H₄)₂O]²^- ([<i>i</i>-PrNON]²^-) and [(C₆H₁₁N-<i>o</i>-C₆H₄)₂O]²^- ([CyNON]²^-)
  作者：Robert Baumann、Rüdiger Stumpf、William M. Davis、Lan-Chang Liang、Richard R. Schrock

  DOI：10.1021/ja983549v

  日期：1999.9.1

  five- and six-coordinate titanium and zirconium dialkyl complexes that contain the [(i-PrN-o-C6H4)2O]2- ([i-PrNON]2-) ligand have been prepared, among them [i-PrNON]Ti(CH2CHMe2)2, [i-PrNON]Ti(CH2CMe3)2, [i-PrNON]Zr(CH2CH3)2, and [i-PrNON]Zr(CH2CHMe2)2. These species serve as sources of complexes such as [i-PrNON]Ti(PMe3)2}2(μ-N2), [i-PrNON]Ti(CHCMe3)(PMe3)2, [i-PrNON]Zr(CH2CHMe2)2(PMe3), and [i-PrNON]Zr(H2CCMe2)(PMe3)2

  已经制备了多种含有[(i-PrN-o-C6H4)2O]2-([i-PrNON]2-)配体的五配位和六配位钛和锆二烷基配合物，其中[i- PrNON]Ti(CH2CHMe2)2、[i-PrNON]Ti(CH2CMe3)2、[i-PrNON]Zr(CH2CH3)2 和 [i-PrNON]Zr(CH2CHMe2)2。这些物质作为复合物的来源，例如 [i-PrNON]Ti(PMe3)2}2(μ-N2)、[i-PrNON]Ti(CHCMe3)(PMe3)2、[i-PrNON]Zr(CH2CHMe2) )2(PMe3) 和 [i-PrNON]Zr(H2CCMe2)(PMe3)2。[i-PrNON]Ti(CH2CMe3)2 和 Me2PCH2CH2PMe2 在不存在二氮的情况下反应生成 (i-PrNC6H4)(i-PrNC6H4O)Ti(dmpe)，一种假八面体物质，其中一个芳基-氧键已被裂解。在[i
• Synthesis and structural characterization of well-defined anionic aluminium alkoxide complexes supported by NON-type diamido ether tridentate ligands and their use for the controlled ROP of lactide
  作者：Frédéric Hild、Pierre Haquette、Lydia Brelot、Samuel Dagorne

  DOI：10.1039/b911802k

  日期：——

  be prepared. While the lithium Al mono-alkoxide species 4a–b are inactive in the ring-opening polymerization (ROP) of lactide, their bis-alkoxide Al analogues 5a–b polymerize rac-lactide and (S)-lactide at room temperature, which is rather uncommon for Al-based alkoxide systems. Kinetic studies of the lactide ROP initiated by compound 5a suggest a strong preference for racemic enchainment during the

  三齿配体（RNH- o -C 6 H 4）2 O（1a，R = C 5 H 9 ; 1b，R =半胱氨酸）被发现容易地与反应的LiAlH 4，得到相应的锂铝dihydrido盐物质[η 2 - Ñ，ñ - （RN- ö -C 6 ħ 4）2 ö}的AlH（μ-H）的Li（THF） ] 2（2a，R = C 5 H 9 ; 2b，R =半胱氨酸）分别以50％和42％的收率。配合物2a和2b的固态结构通过X射线晶体学研究确定。化合物2a和2b容易与一当量的苯甲醛 负担相应的费用 一苄氧基物种η 2 - Ñ，ñ - RN- ö -C 6 ħ 4）2 ö}的Al（H）（μ -OCH 2 PH）的Li（THF）2（图4a，R = C 4 H ^ 9 ;图4b，R =半胱氨酸），如4b的X射线研究所证实。以类似的方式，当化合物2a和2b与两当量的苯甲醛反应时，双苄氧基衍生物图5a和图5b η 3 -