6-(hydroxy(phenyl)methyl)dibenzo[c,e][1,2]oxaphosphinine 6-oxide | 130444-41-6

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 6-(hydroxy(phenyl)methyl)dibenzo[c,e][1,2]oxaphosphinine 6-oxide
• 英文别名: (10-Oxo-10H-9-oxa-10λ⁵-phospha-phenanthren-10-yl)-phenyl-methanol；(6-Oxobenzo[c][2,1]benzoxaphosphinin-6-yl)-phenylmethanol
• CAS: 130444-41-6
• 化学式: C₁₉H₁₅O₃P
• 分子量: 322.3
• InChiKey: VNOYOYXFAQEXQY-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.4
• 重原子数：
  23
• 可旋转键数：
  2
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.05
• 拓扑面积：
  46.5
• 氢给体数：
  1
• 氢受体数：
  3

反应信息

• 作为产物：
  描述：

  邻苯基苯酚 在 水 、 zinc(II) chloride 、 三氯化磷 作用下， 以 甲醇 为溶剂， 反应 9.5h， 生成 6-(hydroxy(phenyl)methyl)dibenzo[c,e][1,2]oxaphosphinine 6-oxide
  参考文献：
  名称：

  Yamada, Yoichi; Yasuda, Heinosuke; Saito, Toranosuke, Journal of Heterocyclic Chemistry, 1990, vol. 27, # 4, p. 845 - 850

  摘要：

  DOI：

文献信息

• 一种DOPO-邻苯二甲酰亚胺类衍生物、制备 方法及应用
  申请人：中国科学院宁波材料技术与工程研究所

  公开号：CN108640949B

  公开（公告）日：2020-08-04

  本发明提供一种DOPO‑邻苯二甲酰亚胺类衍生物，具有式Ⅰ所示结构；本发明还提供所述DOPO‑邻苯二甲酰亚胺类衍生物的制备方法，包括：(1)DOPO衍生物与醛类化合物，进行亲核加成反应制备DOPO‑醇类化合物；(2)DOPO‑醇类化合物与磺酰氯反应制备DOPO‑磺酸酯类化合物；(3)DOPO‑磺酸酯类化合物与邻苯二甲酰亚胺金属盐进行亲核取代反应得到DOPO‑邻苯二甲酰亚胺衍生物。本发明还提供了上述DOPO‑邻苯酰亚胺类衍生物作为阻燃剂改性高分子树脂的应用。阻燃改性后的高分子树脂垂直燃烧测试通过V‑0级别；同时可使阻燃制品保持良好的热性能、力学性能及物理表观。
• Visible-Light-Induced Carbene Insertion into P–H Bonds between Acylsilanes and <i>H</i>-Phosphorus Oxides
  作者：Xiaoyu Mo、Yuexiang Xie、Linli Wei、Xiu Gu、Min Zhang、Xinzhi Zhang、Jun Jiang

  DOI：10.1021/acs.orglett.3c00722

  日期：——

  has been established for the P–H insertion reaction between acylsilanes and H-phosphorus oxides that, upon a subsequent acidic process, deliver a wide variety of α-hydroxyphosphorus oxides in good yields (up to 93% yield). The metal-free protocol represents a unique example of P–H insertion for C–P bond formation through in situ generation of siloxycarbenes. This methodology features the advantages of

  已经为酰基硅烷和H-氧化磷之间的 P-H 插入反应建立了一种有趣的可见光诱导策略，在随后的酸性过程中，以良好的产率（高达 93%）提供各种 α-羟基氧化磷屈服）。无金属方案代表了通过原位生成甲硅氧卡宾形成 C-P 键的 P-H 插入的独特示例。该方法具有操作简单、条件温和、底物适用范围广、克级合成无柱等优点。
• YAMADA, YOICHI;YASUDA, HEINOSUKE;SAITO, TORANOSUKE, J. HETEROCYCL. CHEM., 27,(1990) N, C. 845-850
  作者：YAMADA, YOICHI、YASUDA, HEINOSUKE、SAITO, TORANOSUKE

  DOI：——

  日期：——
• METHOD FOR PRODUCING PHOSPHORUS-CONTAINING PHENOLIC COMPOUND, NOVEL PHOSPHORUS-CONTAINING PHENOL, CURABLE RESIN COMPOSITION, CURED PRODUCT OF THE SAME, PRINTED WIRING BOARD, AND SEMICONDUCTOR SEALING MATERIAL
  申请人：Hayashi Koji

  公开号：US20120095156A1

  公开（公告）日：2012-04-19

  Provided are a method for producing a phosphorus-containing phenolic compound in which reactivity is considerably excellent in the reaction between a phosphorus-containing compound and an aromatic nucleus of a phenol; in the case of using a polyhydric phenol or a phenolic resin as the phenol, a novel phosphorus-containing phenolic compound that serves as a curing agent for an epoxy resin and imparts excellent heat resistance to a cured product; a curable resin composition containing the novel phosphorus-containing phenolic compound; a cured product of the curable resin composition; a printed wiring board; and a semiconductor sealing material. An aromatic aldehyde (a1) having an alkoxy group as a substituent on an aromatic nucleus is allowed to react with an organic phosphorus compound (a2) intramolecularly having a P—H group or a P—OH group. The resultant reaction product is then allowed to react with a phenol (a3).
• ACTIVE ESTER RESIN, THERMOSETTING RESIN COMPOSITION, CURED PRODUCT OF SAME, SEMICONDUCTOR ENCAPSULATION MATERIAL, PREPREG, CIRCUIT BOARD, AND BUILD-UP FILM
  申请人：DIC Corporation

  公开号：US20150118499A1

  公开（公告）日：2015-04-30

  A cured product exhibits good heat resistance and flame retardancy as well as low dielectric constant and low loss tangent. A phosphorus-containing compound (i) obtained by a reaction between an aromatic aldehyde (a1) having an alkoxy group as a substituent on a nucleus and an organic phosphorus compound (a2) having a P—H group or a P—OH group in a molecular structure is reacted with a phenolic substance (a3) to obtain a phosphorus-containing phenolic substance (A1). Then the phosphorus-containing phenolic substance (A1) is reacted with an aromatic dicarboxylic acid or an anhydride or dihalide of an aromatic dicarboxylic acid or a C2-6 saturated dicarboxylic acid or an anhydride or dihalide of a C2-6 saturated dicarboxylic acid (A2) so that all or some of hydroxyl groups of the phenolic substance (A1) form ester bonds.