O,O'-di(adamant-1-yl) thiophosphoric acid | 202820-24-4

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 有机硫代磷酸及其衍生物
• 英文名称: O,O'-di(adamant-1-yl) thiophosphoric acid
• 英文别名: Diadamantylthiophosphoric acid；bis(1-adamantyloxy)-hydroxy-sulfanylidene-λ5-phosphane
• CAS: 202820-24-4
• 化学式: C₂₀H₃₁O₃PS
• 分子量: 382.504
• InChiKey: BPSDLOFTDULYPG-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6.1
• 重原子数：
  25
• 可旋转键数：
  4
• 环数：
  8.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  70.8
• 氢给体数：
  1
• 氢受体数：
  4

反应信息

• 作为产物：
  描述：

  O,O'-di(adamant-1-yl) triethylammonio thiophosphate 在 盐酸 作用下， 以 水 为溶剂， 反应 1.0h， 以98%的产率得到O,O'-di(adamant-1-yl) thiophosphoric acid
  参考文献：
  名称：

  Di(adamant-1-yl)- and di(adamant-2-yl)thiophosphoric acids and their triethylammonium salts in alkylation reactions

  摘要：

  By reaction of di(adamant-1-yl) and di(adamant-2-yl) phosphites with sulfur in the presence of triethylamine diadamantylthiophosphoric acid triethylammonium salts were obtained. The latter by the action of hydrochloric acid were converted into free thiophosphoric acids and by the reaction of alkylation into the respective triesters which have thionic structure. Applicability in such reactions also of triethylammonium salts of diadamantyldithiophosphoric acids was demonstrated.

  DOI：

  10.1134/s1070363209080076

文献信息

• Di(adamant-1-yl)- and di(adamant-2-yl)thiophosphoric acids and their triethylammonium salts in alkylation reactions
  作者：R. I. Yurchenko、Yu. M. Klimko、A. A. Esipenko、E. D. Butova、A. G. Yurchenko

  DOI：10.1134/s1070363209080076

  日期：2009.8

  By reaction of di(adamant-1-yl) and di(adamant-2-yl) phosphites with sulfur in the presence of triethylamine diadamantylthiophosphoric acid triethylammonium salts were obtained. The latter by the action of hydrochloric acid were converted into free thiophosphoric acids and by the reaction of alkylation into the respective triesters which have thionic structure. Applicability in such reactions also of triethylammonium salts of diadamantyldithiophosphoric acids was demonstrated.