divinyl cyclohexane-1,4-dicarboxylate | 937802-15-8

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• 英文名称: divinyl cyclohexane-1,4-dicarboxylate
• 英文别名: Bis(ethenyl) cyclohexane-1,4-dicarboxylate
• CAS: 937802-15-8
• 化学式: C₁₂H₁₆O₄
• 分子量: 224.257
• InChiKey: GNBYZSBFWHSNOG-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.1
• 重原子数：
  16
• 可旋转键数：
  6
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.5
• 拓扑面积：
  52.6
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为产物：
  描述：

  1,4-环己烷二甲酸 、 乙炔 在 十羰基二铼 作用下， 以 1,4-二氧六环 为溶剂， 160.0 ℃ 、2.0 MPa 条件下， 反应 5.0h， 生成 divinyl cyclohexane-1,4-dicarboxylate
  参考文献：
  名称：

  Process for Preparing Vinyl Carboxylates

  摘要：

  本发明涉及一种制备乙烯羧酸酯的方法，其中在选择自钨、钼、铬、铁和铼的羰基配合物、卤化物和氧化物作为催化剂的情况下，将羧酸与炔烃化合物在温度≦300°C下反应。该过程以高产率给出所需的乙烯酯。

  公开号：

  US20080308765A1

文献信息

• Copolymerizable methine and anthraquinone compounds and articles containing them
  申请人：Pearson Clay Jason

  公开号：US20060115516A1

  公开（公告）日：2006-06-01

  This invention relates to polymerizable ultraviolet light absorbers and yellow colorants and their use in ophthalmic lenses. In particular, this invention relates to polymerizable ultraviolet light absorbing methine compounds and yellow compounds of the methine and anthraquinone classes that block ultraviolet light and/or violet-blue light transmission through ophthalmic lenses.

  这项发明涉及可聚合的紫外光吸收剂和黄色染料，以及它们在眼镜镜片中的应用。具体而言，这项发明涉及可聚合的紫外光吸收亚甲基化合物和亚甲基和蒽醌类化合物，这些化合物通过眼镜镜片阻挡紫外光和/或紫蓝光的透射。
• Copolymerizable azo compounds and articles containing them
  申请人：Pearson Clay Jason

  公开号：US20060110430A1

  公开（公告）日：2006-05-25

  Polymerizable light absorbing azo dyes are disclosed useful as monomers in the formation of devices such as, but not limited to ocular lenses. Specifically, intraocular lenses (IOL) are disclosed wherein one or more of the light absorbing dye is covalently bonded to other structural polymers though ethylene unsaturated groups. The resulting IOLs possess light absorbing properties without significant amounts of free (un-bound) azo dye molecules present in the final structural polymer matrix.

  可聚合的吸光偶氮染料被披露为在形成设备时作为单体有用，这些设备包括但不限于眼镜片。具体地，披露了一种人工晶状体（IOL），其中一个或多个吸光染料通过乙烯不饱和基与其他结构聚合物共价结合。由此产生的IOL具有吸光性能，而最终结构聚合物基质中几乎没有自由（未结合）偶氮染料分子。
• Ethylenically-unsaturated blue anthraquinone dyes
  申请人：Pearson Clay Jason

  公开号：US20050044644A1

  公开（公告）日：2005-03-03

  This invention pertains to certain novel colorant compounds containing one or more ethylenically-unsaturated, photopolymerizable radicals that may be copolymerized (or cured) with ethylenically-unsaturated monomers to produce colored compositions such as colored acrylic polymers. Suitable compositions having the present colorants copolymerized therein include, e.g., polymers produced from acrylate and methacrylate esters, colored polystyrenes, and similar colored polymeric materials derived from other ethylenically-unsaturated monomers. The present invention also pertains to processes for preparing the photopolymerizable colorant compounds. The ethylenically unsaturated colorant compounds may be suitable for use in coatings that are applied to wood, glass, metal, thermoplastics and the like.

  本发明涉及某些新颖的着色剂化合物，其中含有一个或多个乙烯基不饱和的光聚合基团，可以与乙烯基不饱和单体共聚合（或固化），以产生着色组合物，例如着色丙烯酸聚合物。在其中共聚合了现有着色剂的适当组合物包括，例如，由丙烯酸酯和甲基丙烯酸酯制成的聚合物，着色聚苯乙烯以及从其他乙烯基不饱和单体衍生的类似着色聚合材料。本发明还涉及制备光聚合着色剂化合物的过程。乙烯基不饱和着色剂化合物可以适用于涂覆于木材，玻璃，金属，热塑性塑料等表面的涂层中。
• Ethylenically-unsaturated red anthraquinone dyes
  申请人：Pearson Clay Jason

  公开号：US20050049425A1

  公开（公告）日：2005-03-03

  This invention pertains to certain novel red anthraquinone colorant compounds containing one or more ethylenically-unsaturated (e.g., vinyl), photopolymerizable radicals that may be copolymerized (or cured) with ethylenically-unsaturated monomers to produce colored compositions such as colored acrylic polymers. Suitable compositions having the present colorants copolymerized therein include, e.g., polymers produced from acrylate and methacrylate esters, colored polystyrenes, and similar colored polymeric materials derived from other ethylenically-unsaturated monomers. The novel colorants possess good fastness (stability) to ultraviolet (UV) light, good solubility in vinyl monomers and good color strength. The present invention also pertains to processes for preparing the photopolymerizable colorant compounds. The ethylenically unsaturated colorant compounds may be suitable for use in coatings that are applied to wood, glass, paper, metal, thermoplastics and the like.

  本发明涉及某些新颖的红色蒽醌着色剂化合物，其中包含一种或多种乙烯基不饱和（例如乙烯基）的光聚合基团，这些基团可以与乙烯基不饱和单体共聚合（或固化），以产生彩色组合物，例如彩色丙烯酸聚合物。适当的组合物中包括聚丙烯酸酯和甲基丙烯酸酯制成的聚合物，彩色聚苯乙烯以及从其他乙烯基不饱和单体中衍生的类似彩色聚合物材料。新颖的着色剂具有良好的紫外光（UV）稳定性，良好的乙烯基单体溶解性和良好的色彩强度。本发明还涉及制备光聚合色素化合物的方法。乙烯基不饱和着色剂化合物可适用于涂层，该涂层应用于木材、玻璃、纸张、金属、热塑性塑料等材料上。
• Azo compounds and coating compositions containing the azo compounds
  申请人：Pearson Clay Jason

  公开号：US20070207331A1

  公开（公告）日：2007-09-06

  Disclosed are azo colorant compounds containing one or more ethylenically-unsaturated groups polymerizable or copolymerizable with ethylenically-unsaturated compositions typically used in coating compositions. The azo colorantcompounds are polymerizable by photopolymerization or free radical polymerization techniques with ethylenically-unsaturated monomers. The copolymerized colorants produce colored compositions such as colored acrylic polymers, e.g., polymers produced from acrylate and methacrylate esters, colored polystyrenes, and similar colored polymeric materials derived from other ethylenically-unsaturated monomers. The ethylenically-unsaturated colorant compounds may be used in coatings that are applied to wood, glass, metal, thermoplastics and the like.

  本发明涉及一种偶氮染料化合物，其含有一个或多个乙烯基不饱和基团，可与通常用于涂料组成中的乙烯基不饱和物聚合或共聚。这些偶氮染料化合物可通过光聚合或自由基聚合技术与乙烯基不饱和单体聚合。共聚染料可产生彩色组成物，例如彩色丙烯酸聚合物，例如由丙烯酸酯和甲基丙烯酸酯制成的聚合物，彩色聚苯乙烯和类似的彩色聚合物材料，这些材料源自其他乙烯基不饱和单体。乙烯基不饱和染料化合物可用于应用于木材、玻璃、金属、热塑性材料等的涂层中。