2-吡啶三溴甲砜 | 59626-33-4

• 物质功能分类: 医药中间体 - 杂环化合物 - 吡啶类化合物
• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡啶及其衍生物
• 中文名称: 2-吡啶三溴甲砜
• 中文别名: 2-吡啶基三溴甲基砜；2-甲基磺酰三溴吡啶；2-(三溴甲磺酰基)吡啶；2-三溴甲磺酰基吡啶
• 英文名称: tribromomethylsulfonylpyridine
• 英文别名: 2-Pyridyl Tribromomethyl Sulfone；2-(tribromomethylsulfonyl)pyridine
• CAS: 59626-33-4
• 化学式: C₆H₄Br₃NO₂S
• 分子量: 393.881
• InChiKey: FRCQMXHPNJVPJC-UHFFFAOYSA-N

物化性质

• 熔点：
  159-162°C
• 稳定性/保质期：
  避免接触水

计算性质

• 辛醇/水分配系数(LogP)：
  2.9
• 重原子数：
  13
• 可旋转键数：
  1
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.17
• 拓扑面积：
  55.4
• 氢给体数：
  0
• 氢受体数：
  3

安全信息

• WGK Germany：
  1
• 海关编码：
  2933399090
• 安全说明：
  S26,S36
• 危险类别码：
  R36/37/38
• 危险性防范说明：
  P280,P305+P351+P338
• 危险性描述：
  H317,H319

反应信息

• 作为产物：
  描述：

  2-甲硫基吡啶 在 sodium hydroxide 、 sodium hypobromide 作用下， 以99%的产率得到2-吡啶三溴甲砜
  参考文献：
  名称：

  Process for preparing tribromomethylsulfonylpyridine

  摘要：

  本发明提供了一种制备三溴甲磺酰吡啶的方法，包括在异相系统中，在碱和水的存在下，使甲硫基吡啶和次溴酸盐反应。根据本发明，可以工业上有利地、高产率、高纯度地制备三溴甲磺酰吡啶。

  公开号：

  US06420564B1

文献信息

• Method for producing grains of aliphatic acid silver salt and thermally processed image recording material
  申请人：——

  公开号：US20010018170A1

  公开（公告）日：2001-08-30

  A method for producing grains of aliphatic acid silver salt by mixing a solution containing silver ions and a solution of aliphatic acid alkali metal salt to attain reaction of them, wherein (1) 95-100% of the total molar number to be added of the aliphatic acid alkali metal salt is added under a condition that dilution factor of the solution of aliphatic acid alkali metal salt becomes 10-fold or higher at 1 second after the addition, (2) 95-100% of the total amount to be added of silver in the solution containing silver ions is added under a condition that dilution factor of the solution containing silver ions becomes 20-fold or higher at 1 second after the addition, and (3) 50-100% of the total amount to be added of the solution of aliphatic acid alkali metal salt is added simultaneously with the solution containing silver ions. According to the present invention, there is provided a method for producing grains of aliphatic acid silver salt, which show excellent fog prevention ability, in addition, excellent fog prevention ability even after time lapse, when used in a thermally processed image recording material.

  本发明提供了一种制备脂肪族酸银盐颗粒的方法，包括将含有银离子的溶液和脂肪族酸碱金属盐的溶液混合以使它们反应，其中（1）脂肪族酸碱金属盐的总摩尔数的95-100％在加入后1秒钟时，脂肪族酸碱金属盐的稀释因子变为10倍或更高，（2）所含银离子的溶液中总添加量的95-100％在加入后1秒钟时，银离子溶液的稀释因子变为20倍或更高，（3）脂肪族酸碱金属盐溶液的总添加量的50-100％同时与含银离子的溶液一起加入。该发明提供了一种制备脂肪族酸银盐颗粒的方法，该颗粒具有出色的防雾能力，并且即使在时间流逝后，当用于热处理的图像记录材料时，仍具有出色的防雾能力。
• Photocurable composition
  申请人：NIPPON PAINT CO., LTD.

  公开号：EP0382209A2

  公开（公告）日：1990-08-16

  The present invention provides a photocurable composition which is rapidly cured. The composition comprises a polymerizable compound having an ethylenically unsaturated double bond and a photopolymerization initiator wherein the photopolymerization initiator comprises; (a) a compound having the following formula [I]; [wherein X represents a sulfur atom or -CO-, R¹, R², R³ and R⁴ respectively represent a hydrogen atom, an alkyl group, a substituted alkyl group, an aryl group, an alkoxy group, -CH₂COOH, a nitro group, a sulfonyl group, a phosphonyl group, a cyano group, a hydroxyl group and a halogen atom.], or an alpha-diketone compound having the formula [II]; R⁵---R⁶      [II] [wherein R⁵ and R⁶ respectively represent an alkyl group, an alkoxy group or an aryl group, provided that neither R⁵ nor R⁶ is an alkoxy group.] (b) carbon tetrachloride or a compound having tribromomethylsulfonyl, and (c) an amine having carbon atoms directly bonded to a nitrogen atom, at least one of which is methylene group.

  本发明提供了一种可快速固化的光固化组合物。该组合物包括具有乙烯不饱和双键的可聚合化合物和光聚合引发剂，其中光聚合引发剂包括： (a) 具有下式[I]的化合物； [其中 X 代表硫原子或-CO-，R¹、R²、R³ 和 R⁴ 分别代表氢原子、烷基、取代烷基、芳基、烷氧基、-CH₂COOH、硝基、磺酰基、膦酰基、氰基、羟基和卤素原子]，或具有式[II]的α-二酮化合物； R⁵---R⁶ [II] 式中 [其中 R⁵ 和 R⁶ 分别代表烷基、烷氧基或芳基，但 R⁵ 和 R⁶ 均非烷氧基。］ (b) 四氯化碳或具有三溴甲基磺酰基的化合物，以及 (c) 具有与氮原子直接键合的碳原子的胺，其中至少一个为亚甲基。
• PROCESS FOR PREPARING TRIBROMOMETHYLSULFONYLPYRIDINE
  申请人：SUMITOMO SEIKA CHEMICALS CO., LTD.

  公开号：EP1184375A1

  公开（公告）日：2002-03-06

  The present invention provides a process for preparing a tribromomethylsulfonylpyridine, which comprises reacting a methylthiopyridine and a hypobromite in the presence of a base and water in a heterogeneous system. According to the present invention, it is possible to prepare a tribromomethylsulfonylpyridine industrially advantageously, and with high yield and high purity.

  本发明提供了一种制备三溴甲基磺酰基吡啶的工艺，该工艺包括在碱和水的存在下，使甲硫基吡啶和次溴酸盐在异构体系中反应。 根据本发明，可以在工业上制备三溴甲基磺酰基吡啶，且产量高、纯度高。
• PHOTOSENSITIVE RESIN COMPOSITION, PHOTOSENSITIVE ELEMENT COMPRISING THE SAME, METHOD FOR PRODUCING RESIST PATTERN, AND METHOD FOR PRODUCING PRINTED WIRING BOARD
  申请人：Hitachi Chemical Company, Ltd.

  公开号：EP1282010A1

  公开（公告）日：2003-02-05

  The present invention provides a photosensitive resin composition for laser scanning exposure, which satisfies the following formula (1):-25≦ E1-E0E0 × 100 ≦ 25 wherein E0 represents an exposure amount in mJ/cm2 at which the photosensitive resin composition is cured at the 21st step of the density 1.00 of a 41-step step tablet having a density range from 0.00 to 2.00, a density step of 0.05, a tablet size of 20 mm × 187 mm and a step size of 3 mm × 12 mm, by irradiation with a full wavelength active light of a high pressure mercury lamp and E1 represents an exposure amount in mJ/cm2 at which the photosensitive resin composition after being left for 2 hours under 40 W non-ultraviolet white lamp is cured at the 21st step of the 41-step step tablet by irradiation with a full wavelength active light from a high pressure mercury lamp.

  本发明提供了一种用于激光扫描曝光的光敏树脂组合物，它满足下式(1)：-25≦ E1-E0E0 × 100 ≦ 25 其中，E0表示光敏树脂组合物在密度范围为0.00至2.00、密度步长为0.E1 表示光敏树脂组合物在 40 W 非紫外线白光灯下放置 2 小时后，通过高压汞灯的全波长有效光照射，在 41 步片剂的第 21 步固化时的曝光量，单位为 mJ/cm2。
• Process for preparing methylthiopyridine
  申请人：SUMITOMO SEIKA CHEMICALS CO., LTD.

  公开号：EP1361214A1

  公开（公告）日：2003-11-12

  The present invention provides a process for preparing a methylthiopyridine, which comprises reacting a halogenated pyridine and an alkali metal salt of methanethiol in the presence of a base and water in a heterogeneous system.

  本发明提供了一种制备甲硫基吡啶的工艺，该工艺包括在碱和水的存在下，使卤代吡啶和甲硫醇的碱金属盐在异构体系中反应。

表征谱图