2-(2-((bis(pyridin-2-ylmethyl)amino)methyl)phenoxy)-N,N-diphenylacetamide | 1408320-36-4

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 2-(2-((bis(pyridin-2-ylmethyl)amino)methyl)phenoxy)-N,N-diphenylacetamide
• 英文别名: 2-[2-[[bis(pyridin-2-ylmethyl)amino]methyl]phenoxy]-N,N-diphenylacetamide
• CAS: 1408320-36-4
• 化学式: C₃₃H₃₀N₄O₂
• 分子量: 514.627
• InChiKey: WMXRERWYHSGVSG-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.3
• 重原子数：
  39
• 可旋转键数：
  11
• 环数：
  5.0
• sp3杂化的碳原子比例：
  0.12
• 拓扑面积：
  58.6
• 氢给体数：
  0
• 氢受体数：
  5

反应信息

• 作为反应物：
  描述：

  europium(III) nitrate hexahydrate 、 2-(2-((bis(pyridin-2-ylmethyl)amino)methyl)phenoxy)-N,N-diphenylacetamide 以 乙腈 为溶剂， 反应 1.0h， 生成
  参考文献：
  名称：

  Luminescent behavior and energy transfer in homometallic Eu and ion associating Eu–Zn complexes with a pentadentate ligand

  摘要：

  A pentadentate ligand L (2-(2-((bis(pyridin-2-ylmethyl)amino)methyl)phenoxy) -N,N-diphenylacetamide) was self-assembled with Eu (NO3)(3) or Zn (NO3)(2)/Eu (NO3)(3) to give homometallic complex ([EuL(NO3)(3)], 1) or ion associating complex ([ZnL(NO3)](2)center dot[Eu(NO3)(5)]center dot CH3CN, 2). respectively. The photoluminescent behavior and energy transfer process were studied in the two complexes by excitation in different ways, in which 2 shows Forster energy transfer mechanism. (C) 2012 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.inoche.2012.09.010
• 作为产物：
  描述：

  2-氯-N,N-二苯基乙酰胺 、 N-(2-hydroxybenzyl)-N,N-bis(2-pyridylmethyl)amine 在 potassium carbonate 、 potassium iodide 作用下， 以 N,N-二甲基甲酰胺 为溶剂， 生成 2-(2-((bis(pyridin-2-ylmethyl)amino)methyl)phenoxy)-N,N-diphenylacetamide
  参考文献：
  名称：

  Luminescent behavior and energy transfer in homometallic Eu and ion associating Eu–Zn complexes with a pentadentate ligand

  摘要：

  A pentadentate ligand L (2-(2-((bis(pyridin-2-ylmethyl)amino)methyl)phenoxy) -N,N-diphenylacetamide) was self-assembled with Eu (NO3)(3) or Zn (NO3)(2)/Eu (NO3)(3) to give homometallic complex ([EuL(NO3)(3)], 1) or ion associating complex ([ZnL(NO3)](2)center dot[Eu(NO3)(5)]center dot CH3CN, 2). respectively. The photoluminescent behavior and energy transfer process were studied in the two complexes by excitation in different ways, in which 2 shows Forster energy transfer mechanism. (C) 2012 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.inoche.2012.09.010

文献信息

• Luminescent behavior and energy transfer in homometallic Eu and ion associating Eu–Zn complexes with a pentadentate ligand
  作者：Hai-Ping Wang、Shi-Chao Wei、Mei Pan、Kang Li、Zi Wang、Cheng Yan、Cheng-Yong Su

  DOI：10.1016/j.inoche.2012.09.010

  日期：2012.11

  A pentadentate ligand L (2-(2-((bis(pyridin-2-ylmethyl)amino)methyl)phenoxy) -N,N-diphenylacetamide) was self-assembled with Eu (NO3)(3) or Zn (NO3)(2)/Eu (NO3)(3) to give homometallic complex ([EuL(NO3)(3)], 1) or ion associating complex ([ZnL(NO3)](2)center dot[Eu(NO3)(5)]center dot CH3CN, 2). respectively. The photoluminescent behavior and energy transfer process were studied in the two complexes by excitation in different ways, in which 2 shows Forster energy transfer mechanism. (C) 2012 Elsevier B.V. All rights reserved.